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Explain with equations and calculations, when necessary, whether an aqueous solution of each of these salts is acidic, basic, or neutral: (a) KBr; (b)NH4I; (c) KCN

Short Answer

Expert verified

Answer

(a) Indifferent

(b) Acidic

(c) Fundamental

Step by step solution

01

Explanation of the concept

An acidic salt is an aqueous solution of a salt that contains the anion of the strong acid and the cation of the weak base. The anion of the weak base reacts with water to form the hydronium ion, causing the solution to become acidic. As an example, consider ammonium chloride. A basic salt is an aqueous solution of a salt that contains the cation of the strong base and the anion of the weak acid. The cation of the strong acid reacts with water, resulting in the formation of the hydroxide ion. As a result, the solution is simplified. As an example, consider sodium supplied. A neutral salt is an aqueous solution of a salt containing the cation.

02

Disintegration of salts into the water

(a)KBr

KBrwill disintegrate in water

KBrK-+Br-

K+is an ion of a strong base KOHandBr-is an ion of a powerful acid (HBr).

A salt containing both ions from strong acids and bases will produce a neutral solution.

03

Disintegration of salts into the water

(b)NH4I

NH4IWill disintegrate in water

NH4INH4++I-

NH4+is a weak base's ion (NH3)andI-is an ion of a powerful acid HIAn acidic solution is produced by combining salt with a cation of a weak base and an anion of a strong acid.

04

Disintegration of salts into the water

(c)KCN

KCNwill disintegrate in water

KCNK++CN-

K+is an ion derived from a strong base (KOH)andCH-is a weak acid's ion (HCN)A basic solution is produced by combining salt with a cation of a strong base and an anion of a weak acid.

As a result, all the 3 salts are

  1. Indifferent, (b) Acidic, (c) Fundamental.

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Most popular questions from this chapter

When Fe3 +salts are dissolved in water, the solution becomes acidic due to formation ofFe(H2O)5OH2 +andH3O+.The overall process involves both Lewis and Br酶nsted-Lowry acid-base reactions. Write the equations for the process.

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