Chapter 7: Problem 5
Apply Write out the electron configuration for each atom. Then, predict the change that must occur in each to achieve a noble-gas configuration. a. nitrogen \(\quad\) b. sulfur \(\quad\) c. barium \(\quad\) d. lithium
Short Answer
Expert verified
Nitrogen gains 3 electrons, sulfur gains 2, barium loses 2, and lithium loses 1 to achieve noble-gas configurations.
Step by step solution
01
Understanding Electron Configuration
Electron configuration refers to the distribution of electrons in an atom's orbitals. Each element has a unique electron configuration that can be determined based on its atomic number.
02
Electron Configuration of Nitrogen
The atomic number of nitrogen is 7, which means it has 7 electrons. The electron configuration is 1s虏 2s虏 2p鲁. Nitrogen needs to gain 3 electrons to achieve the noble-gas configuration of neon (1s虏 2s虏 2p鈦).
03
Electron Configuration of Sulfur
Sulfur has an atomic number of 16, giving it 16 electrons. Its configuration is 1s虏 2s虏 2p鈦 3s虏 3p鈦. To achieve the noble gas configuration of argon (1s虏 2s虏 2p鈦 3s虏 3p鈦), it needs to gain 2 electrons.
04
Electron Configuration of Barium
Barium, with atomic number 56, has its electron configuration as 1s虏 2s虏 2p鈦 3s虏 3p鈦 3d鹿鈦 4s虏 4p鈦 4d鹿鈦 5s虏 5p鈦 6s虏. Barium needs to lose 2 electrons to reach the noble-gas configuration of xenon (1s虏 2s虏 2p鈦 3s虏 3p鈦 3d鹿鈦 4s虏 4p鈦 4d鹿鈦 5s虏 5p鈦).
05
Electron Configuration of Lithium
Lithium has 3 electrons and an electron configuration of 1s虏 2s鹿. To obtain the noble-gas configuration of helium (1s虏), lithium must lose one electron.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Noble-Gas Configuration
The noble-gas configuration is a state where an atom possesses a full set of valence electrons, mimicking the electron configuration of noble gases. Noble gases are elements in Group 18 of the periodic table, and they include helium, neon, argon, krypton, xenon, and radon. These gases are known for their stability and lack of reactivity due to their full valence shells.
When atoms achieve a noble-gas configuration, they have a complete outer electron shell, typically an octet (8 electrons), except for helium. This configuration makes the atom energetically stable. Other elements tend to gain, lose, or share electrons in order to attain this stable arrangement.
When atoms achieve a noble-gas configuration, they have a complete outer electron shell, typically an octet (8 electrons), except for helium. This configuration makes the atom energetically stable. Other elements tend to gain, lose, or share electrons in order to attain this stable arrangement.
- Helium: 1s虏
- Neon: 1s虏 2s虏 2p鈦
- Argon: 1s虏 2s虏 2p鈦 3s虏 3p鈦
- Others follow similar patterns, filling up electron orbitals.
Atomic Number
The atomic number is a crucial term in chemistry, as it represents the number of protons in the nucleus of an atom of an element. It determines the element's identity and is listed on the periodic table, usually above the element symbol.
For example:
For example:
- Nitrogen has an atomic number of 7, indicating it has 7 protons in its nucleus.
- Sulfur's atomic number is 16, signifying 16 protons.
- Barium, bearing the atomic number 56, has 56 protons.
- Lithium with atomic number 3, has 3 protons.
Electron Distribution
Electron distribution, also known as electron configuration, describes the arrangement of electrons around an atom's nucleus in electron shells or orbitals. Electrons fill these orbitals in a specific order dictated by the principle of increasing energy levels.
The distribution follows certain rules:
The distribution follows certain rules:
- The Aufbau Principle: Electrons occupy the lowest-energy orbitals first.
- Pauli Exclusion Principle: Each orbital can hold a maximum of two electrons with opposite spins.
- Hund's Rule: Electrons will fill an unoccupied orbital before they pair up in an occupied one within the same sublevel.
Electron Orbitals
Electron orbitals are regions around an atom's nucleus where electrons are likely to be found. These orbitals are part of larger energy levels, often referred to as electron shells. The concept of orbitals helps explain where and how electrons are distributed in atoms.
There are different types of orbitals:
There are different types of orbitals:
- s-orbitals: Spherical in shape and able to hold 2 electrons. Present in all energy levels.
- p-orbitals: Dumbbell-shaped and can hold up to 6 electrons in three axes (px, py, pz).
- d-orbitals: More complex shapes, occupying up to 10 electrons in five orientations.
- f-orbitals: Complicated structures, with room for 14 electrons in seven orientations.