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The decreasing order of strength of the following bases is: (a) \(\mathrm{Cl}, \mathrm{CH}_{3} \mathrm{COO}^{-}, \mathrm{NH}_{3}\) (b) \(\mathrm{CH}_{3} \mathrm{COO}^{-}, \mathrm{NH}_{3}, \mathrm{Cl}^{-}\) (c) \(\mathrm{CH}_{3} \mathrm{COO}^{-}, \mathrm{Cl}^{-}, \mathrm{NH}_{3}\) (d) \(\mathrm{NH}_{3}, \mathrm{CH}_{3} \mathrm{COO}^{-}, \mathrm{Cl}^{-}\)

Short Answer

Expert verified
The correct order is option (d): NH鈧, CH鈧僀OO鈦, Cl鈦.

Step by step solution

01

Identify Proton Acceptors

Bases are substances that can accept a proton (H+). Examine the given substances: Cl (a neutral atom and not a base), CH鈧僀OO鈦 (an ion), and NH鈧 (a molecule). CH鈧僀OO鈦 and NH鈧 are bases because they can accept protons, unlike Cl, which is typically a halide and doesn't function as a proton acceptor.
02

Review Basic Strengths in Terms of Conjugate Acids

The strength of a base is inversely related to the strength of its conjugate acid. The conjugate acid of CH鈧僀OO鈦 is acetic acid (CH鈧僀OOH), and the conjugate acid of NH鈧 is NH鈧勨伜. Acetic acid is stronger than NH鈧勨伜, hence, CH鈧僀OO鈦 is a weaker base compared to NH鈧.
03

Rank the Bases Based on Strength

Since NH鈧 can donate a lone pair of electrons and is a weakly basic molecule, it's stronger than CH鈧僀OO鈦, which is a weaker base. Cl鈦 has HCl as its conjugate acid, a strong acid, making Cl鈦 a very weak base. Therefore, the order from strongest to weakest base is: NH鈧, CH鈧僀OO鈦, Cl鈦.
04

Select the Correct Option

Based on the order established (NH鈧 > CH鈧僀OO鈦 > Cl鈦), compare with the options given: (a) Cl, CH鈧僀OO鈦, NH鈧; (b) CH鈧僀OO鈦, NH鈧, Cl鈦; (c) CH鈧僀OO鈦, Cl鈦, NH鈧; (d) NH鈧, CH鈧僀OO鈦, Cl鈦. The correct order NH鈧, CH鈧僀OO鈦, Cl鈦 corresponds to option (d).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Conjugate Acids and Bases
In acid-base chemistry, the concept of conjugate acids and bases is essential. A conjugate acid-base pair consists of two substances that transform into each other by the gain or loss of a proton (H+). Let's break this down.
- **Conjugate Acid:** A conjugate acid is formed when a base gains a proton. For example, when ammonia (NH3) accepts a proton, it becomes NH4+.
- **Conjugate Base:** Conversely, a conjugate base is what remains after an acid has donated a proton. For instance, acetic acid (CH3COOH) loses a proton to become acetate (CH3COO-).
Understanding the strengths of these acids and bases is important for predicting chemical reactions. The stronger an acid, the weaker its conjugate base, and vice versa. This relationship influences how substances behave in chemical environments.
Proton Acceptors
Bases are known as proton acceptors because they can accept hydrogen ions (H+). This ability varies between different bases, affecting their strength.
- **NH3 (Ammonia):** Ammonia is a common base that can accept a proton to form NH4+. It features a lone pair of electrons which facilitates the acceptance of a proton, making it a basic compound.
- **CH3COO- (Acetate Ion):** The acetate ion comes from acetic acid. It is less basic compared to ammonia because it's the conjugate base of a stronger acid (acetic acid).
- **Cl- (Chloride Ion):** As the conjugate base of hydrochloric acid (HCl), which is a very strong acid, chloride is a very weak proton acceptor. Chloride ions rarely hold onto protons once they are released, reflecting its weak basic nature.
Understanding these proton-accepting capabilities is essential for predicting the behavior of substances in chemical reactions.
Base Strength Comparison
In comparing the strength of bases, it's important to consider their ability to accept protons and the strength of their corresponding conjugate acids.
- **Ammonia vs. Acetate Ion:** Ammonia (NH3) is a stronger base than the acetate ion (CH3COO-). This is because its conjugate acid, NH4+, is weaker compared to acetic acid, the conjugate acid of CH3COO-. Thus, NH3 more easily accepts protons.
- **Acetate Ion vs. Chloride Ion:** The acetate ion is a stronger base than the chloride ion (Cl-) because the conjugate acid of Cl-, HCl, is a stronger acid than acetic acid.
From this, we can rank the given bases from strongest to weakest in their ability to accept protons: NH3 > CH3COO- > Cl-. Recognizing these comparative strengths helps in selecting the appropriate bases for various chemical reactions or processes.

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