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Problem 6

Which of the following oxoacids of sulphur contains \(S=S\) bond? (a) \(\mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{6}\) (b) \(\mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{3}\) (c) \(\mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{8}\) (d) \(\mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{4}\)

Problem 7

Any p-orbital can accommodate up to: (a) 4 electrons (b) 2 electrons with parallel spins (c) 6 electrons (d) 2 electrons with opposite spins

Problem 7

The shape of \(\mathrm{XeF}_{4}\) is (a) Tetrahedral (b) Square planar (c) Pyramidal (d) Nearly linear

Problem 8

In an atom two electrons are moving in orbits of radii \(r\) and \(9 r\). The ratio of time taken by them to complete one revolution is (a) \(1: 9\) (b) \(1: 3\) (c) \(1: 27\) (d) \(1: 6\)

Problem 9

The structure of \(\mathrm{XeO}_{2} \mathrm{~F}_{2}\) is (a) Plane triangular (b) Trigonal bipyramidal (c) Square planar (d) Tetrahedral

Problem 9

The number of electrons in the 3 d shell of the element with atomic number 26 is (a) 4 (b) 6 (c) 8 (d) 10

Problem 10

Principal, arimuthal and magnetic quantum numbers are respectively related to: (a) size, shape and orientation (b) shape, size and orientation (d) none of the above (c) sire, orientation and shape (d) none of the above

Problem 11

The bonding of \(\mathrm{S}\) in \(\mathrm{SCl}_{4}\) molecule involves (a) sp orbitals (b) \(\mathrm{sp}^{2}\) orbitals (c) \(sp^{3}\) orbitals (d) \(\mathrm{dsp}^{2}\) orbitals

Problem 12

The correct order of decreasing polarisable ions is (a) \(\mathrm{Cl}^{-}, \mathrm{Br}^{-}, \mathrm{F}, \mathrm{F}^{-}\) (b) \(\mathrm{F}^{-}, \mathrm{I}, \mathrm{Br}^{-}, \mathrm{Cl}^{-}\) (c) \(\mathrm{F}, \mathrm{Cl}^{-}, \mathrm{Br}^{-}, \mathrm{I}^{-}\) (d) \(\mathrm{I}^{-}, \mathrm{Br}^{-}, \mathrm{Cl}^{-}, \mathrm{F}^{-}\)

Problem 13

Among the following, the pair in which the two species are not isostructural is (a) \(\mathrm{IO}_{3}^{-}\)and \(\mathrm{XeO}_{3}\) (b) \(\mathrm{BH}_{4}^{-}\)and \(\mathrm{NH}_{4}^{+}\) (c) \(\mathrm{PF}_{6}^{-}\)and \(\mathrm{SF}_{6}\) (d) \(\mathrm{SiF}_{4}\) and \(\mathrm{SF}_{4}\)

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