Chapter 17: Problem 28
An organic compound having molecular mass 60 is found to contain \(C=20 \%, H=6.67 \%\) and \(\mathrm{N}=46.67 \%\) while rest is oxygen. On heating it gives \(\mathrm{NH}_{3}\) along with a solid residue. The solid residue gives violet colour with alkaline copper sulphate solution. The compound is (a) \(\mathrm{CH}_{y} \mathrm{NCO}\) (b) \(\mathrm{CH}_{3} \mathrm{CONH}_{2}\) (c) \(\left(\mathrm{NH}_{4}\right)_{2} \mathrm{CO}\) (d) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CONH}_{2}\)
Short Answer
Step by step solution
Calculate Molar Contributions
Determine Empirical Formula
Identify Suitable Molecular Formula
Analyze Reaction Outcomes and Color Test
Correct Identification from Options
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Empirical Formula
- Carbon: \( \frac{12}{12} = 1 \) mole
- Hydrogen: \( \frac{4}{1} = 4 \) moles
- Nitrogen: \( \frac{28}{14} = 2 \) moles
- Oxygen: \( \frac{16}{16} = 1 \) mole
Molecular Mass Calculation
- Carbon: 12 g/mol
- Hydrogen: 4 x 1 g/mol = 4 g/mol
- Nitrogen: 2 x 14 g/mol = 28 g/mol
- Oxygen: 16 g/mol