Chapter 9: Problem 14
(a) How does one determine the number of electron domains in a molecule or ion? (b) What is the difference between a bonding electron domain and a nonbonding electron domain?
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Chapter 9: Problem 14
(a) How does one determine the number of electron domains in a molecule or ion? (b) What is the difference between a bonding electron domain and a nonbonding electron domain?
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How would you expect the extent of overlap of atomic orbitals to vary in the series IF, ICl, \(\mathrm{IBr}\), and \(\mathrm{I}_{2}\) ?
Draw sketches illustrating the overlap between the following orbitals on two atoms: (a) the 2 s orbital on each atom, (b) the \(2 p_{z}\) orbital on each atom (assume both atoms are on the z-axis), (c) the \(2 s\) orbital on one atom and the \(2 p_{z}\) orbital on the other atom.
Consider the molecule \(\mathrm{PF}_{4} \mathrm{Cl}\). (a) Draw a Lewis structure for the molecule, and predict its electron-domain geometry. (b) Which would you expect to take up more space, a. \(\mathrm{P}-\mathrm{F}\) bond or a \(\mathrm{P}-\mathrm{Cl}\) bond? Explain. (c) Predict the molecular geometry of \(\mathrm{PF}_{4} \mathrm{Cl}\). How did your answer for part (b) influence your answer here in part (c)? (d) Would you expect the molecule to distort from its ideal electron-domain geometry? If so, how would it distort?
The vertices of a tetrahedron correspond to four alternating corners of a cube. By using analytical geometry, demonstrate that the angle made by connecting two of the vertices to a point at the center of the cube is \(109.5^{\circ}\), the characteristic angle for tetrahedral molecules.
Why are there no \(s p^{4}\) or \(s p^{5}\) hybrid orbitals?
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