Chapter 8: Problem 11
Write the Lewis symbol for atoms of each of the following elements: (a) \(\mathrm{Al}\), (b) \(\mathrm{Br}\), (c) \(\mathrm{Ar}\), (d) \(\mathrm{Sr}\).
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Chapter 8: Problem 11
Write the Lewis symbol for atoms of each of the following elements: (a) \(\mathrm{Al}\), (b) \(\mathrm{Br}\), (c) \(\mathrm{Ar}\), (d) \(\mathrm{Sr}\).
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Predict the chemical formula of the ionic compound formed between the following pairs of elements: (a) \(\mathrm{Al}\) and \(\mathrm{F},(\mathrm{b}) \mathrm{K}\) and \(\mathrm{S},(\mathrm{c}) \mathrm{Y}\) and \(\mathrm{O}\), (d) \(\mathrm{Mg}\) and \(\mathrm{N}\).
Acetylene \(\left(\mathrm{C}_{2} \mathrm{H}_{2}\right)\) and nitrogen \(\left(\mathrm{N}_{2}\right)\) both contain a triple bond, but they differ greatly in their chemical properties. (a) Write the Lewis structures for the two substances. (b) By referring to Appendix \(C\), look up the enthalpies of formation of acetylene and nitrogen and compare their reactivities. (c) Write balanced chemical equations for the complete oxidation of \(\mathrm{N}_{2}\) to form \(\mathrm{N}_{2} \mathrm{O}_{5}(g)\) and of acetylene to form \(\mathrm{CO}_{2}(g)\) and \(\mathrm{H}_{2} \mathrm{O}(g)\). (d) Calculate the enthalpy of oxidation per mole of \(\mathrm{N}_{2}\) and \(\mathrm{C}_{2} \mathrm{H}_{2}\) (the enthalpy of formation of \(\mathrm{N}_{2} \mathrm{O}_{5}(\mathrm{~g})\) is \(11.30 \mathrm{~kJ} / \mathrm{mol}\) ). How do these comparative values relate to your response to part (b)? Both \(\mathrm{N}_{2}\) and \(\mathrm{C}_{2} \mathrm{H}_{2}\) possess triple bonds with quite high bond enthalpies (Table 8.4). What aspect of chemical bonding in these molecules or
(a) When talking about atoms in a Lewis structure, what is meant by the term formal charge? (b) Does the formal charge of an atom represent the actual charge on that atom? Explain. (c) How does the formal charge of an atom in a Lewis structure differ from the oxidation number of the atom?
Based on data in Table \(8.2\), estimate (within \(30 \mathrm{~kJ} / \mathrm{mol}\) ) the lattice energy for (a) LiBr, (b) \(\mathrm{CsBr}\), (c) \(\mathrm{CaCl}_{2}\).
Would you expect AlN to have a lattice energy that is larger or smaller than ScN? Explain.
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