Chapter 5: Problem 91
An aluminum can of a soft drink is placed in a freezer. Later, you find that the can is split open and its contents frozen. Work was done on the can in splitting it open. Where did the energy for this work come from?
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Chapter 5: Problem 91
An aluminum can of a soft drink is placed in a freezer. Later, you find that the can is split open and its contents frozen. Work was done on the can in splitting it open. Where did the energy for this work come from?
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Consider the following hypothetical reactions: $$ \begin{array}{ll} \mathrm{A} \rightarrow \mathrm{B} & \Delta H=+30 \mathrm{~kJ} \\ \mathrm{~B} \longrightarrow \mathrm{C} & \Delta H=+60 \mathrm{~kJ} \end{array} $$ (a) Use Hess's law to calculate the enthalpy change for the reaction A - - - - C. (b) Construct an enthalpy diagram for substances \(\mathrm{A}, \mathrm{B}\), and \(\mathrm{C}\), and show how Hess's law applies.
Consider the twodiagramsbelow. (a) Based on \((t)\), write an equation showing how \(\Delta H_{\mathrm{A}}\) is related to \(\Delta H_{\mathrm{B}}\) and \(\Delta H_{\mathrm{C}}\). How do both diagram (i) and your equation relate to the fact that enthalpy is a state function? (b) Based on (ii), write an equation relating \(\Delta H_{Z}\) to the other enthalpy changes in the diagram. (c) How do these diagrams relate to Hess's law? [Section 5.6]
(a) Why are tables of standard enthalpies of formation so useful? (b) What is the value of the standard enthalpy of formation of an element in its most stable form? (c) Write the chemical equation for the reaction whose enthalpy change is the standard enthalpy of formation of glucose, \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(\mathrm{~s}), \Delta \mathrm{H}_{f}^{\circ}\left[\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\right]\).
(a) What is heat? (b) Under what conditions is heat transferred from one object to another?
(a) Why are fats well suited for energy storage in the human body? (b) A particular chip snack food is composed of \(12 \%\) protein, \(14 \%\) fat, and the rest carbohydrate. What percentage of the calorie content of this food is fat? (c) How many grams of protein provide the same fuel value as \(25 \mathrm{~g}\) of fat?
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