Chapter 5: Problem 79
(a) What is meant by the term fuel value? (b) Which is a greater source of energy as food, \(5 \mathrm{~g}\) of fat or \(9 \mathrm{~g}\) of carbohydrate?
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Chapter 5: Problem 79
(a) What is meant by the term fuel value? (b) Which is a greater source of energy as food, \(5 \mathrm{~g}\) of fat or \(9 \mathrm{~g}\) of carbohydrate?
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In a thermodynamic study a scientist focuses on the properties of a solution in an apparatus as illustrated. A solu- tion is continuously flowing into the apparatus at the top and out at the bottom, such that the amount of solution in the apparatus is constant with time. (a) Is the solution in the apparatus a closed system, open system, or isolated system? Explain your choice. (b) If it is not a closed system, what could be done to make it a closed system?
Calcium carbide \(\left(\mathrm{CaC}_{2}\right)\) reacts with water to form acetylene \(\left(\mathrm{C}_{2} \mathrm{H}_{2}\right)\) and \(\mathrm{Ca}(\mathrm{OH})_{2}\). From the following enthalpy of reaction data and data in Appendix \(C\), calculate \(\Delta H_{f}^{\circ}\) for \(\mathrm{CaC}_{2}(s):\) \(\mathrm{CaC}_{2}(s)+2 \mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Ca}(\mathrm{OH})_{2}(s)+\mathrm{C}_{2} \mathrm{H}_{2}(g)\) \(\Delta H^{\circ}=-127.2 \mathrm{~kJ}\)
(a) Write an equation that expresses the first law of thermodynamics in terms of heat and work. (b) Under what conditions will the quantities \(q\) and \(w\) be negative numbers?
A \(1.800-g\) sample of phenol \(\left(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{OH}\right)\) was burned in a bomb calorimeter whose total heat capacity is \(11.66 \mathrm{~kJ} /{ }^{\circ} \mathrm{C}\). The temperature of the calorimeter plus contents increased from \(21.36^{\circ} \mathrm{C}\) to \(26.37^{\circ} \mathrm{C}\). (a) Write a balanced chemical equation for the bomb calorimeter reaction. (b) What is the heat of combustion per gram of phenol? Per mole of phenol?
Consider the decomposition of liquid benzene, \(\mathrm{C}_{6} \mathrm{H}_{6}(l)\), to gaseous acetylene, \(\mathrm{C}_{2} \mathrm{H}_{2}(\mathrm{~g})\) : $$ \mathrm{C}_{6} \mathrm{H}_{6}(l) \longrightarrow 3 \mathrm{C}_{2} \mathrm{H}_{2}(g) \quad \Delta H=+630 \mathrm{~kJ} $$ (a) What is the enthalpy change for the reverse reaction? (b) What is \(\Delta H\) for the formation of \(1 \mathrm{~mol}\) of acetylene? (c) Which is more likely to be thermodynamically favored, the forward reaction or the reverse reaction? (d) If \(C_{6} \mathrm{H}_{6}(g)\) were consumed instead of \(\mathrm{C}_{6} \mathrm{H}_{6}(l)\), would you expect the magnitude of \(\Delta H\) to increase, decrease, or stay the same? Explain.
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