Chapter 5: Problem 17
(a) What is meant by the term system in thermodynamics? (b) What is a closed system?
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Chapter 5: Problem 17
(a) What is meant by the term system in thermodynamics? (b) What is a closed system?
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A watt is a measure of power (the rate of energy change) equal to \(1 \mathrm{~J} / \mathrm{s}\). (a) Calculate the number of joules in a kilowatt-hour. (b) An adult person radiates heat to the surroundings at about the same rate as a 100 -watt electric incandescent lightbulb. What is the total amount of energy in kcal radiated to the surroundings by an adult in 24 hours?
From the enthalpies of reaction \(\begin{aligned} 2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) & \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(g) & \Delta H &=-483.6 \mathrm{~kJ} \\ 3 \mathrm{O}_{2}(g) & \cdots &-\cdots & 2 \mathrm{O}_{3}(g) & \Delta H &=+284.6 \mathrm{~kJ} \end{aligned}\) calculate the heat of the reaction $$ 3 \mathrm{H}_{2}(\mathrm{~g})+\mathrm{O}_{3}(\mathrm{~g}) \longrightarrow 3 \mathrm{H}_{2} \mathrm{O}(\mathrm{g}) $$
Two solid objects, \(\mathrm{A}\) and \(\mathrm{B}\), are placed in boiling water and allowed to come to temperature there. Each is then lifted out and placed in separate beakers containing \(1000 \mathrm{~g}\) water at \(10.0{ }^{\circ} \mathrm{C}\). Object \(\mathrm{A}\) increases the water temperature by \(3.50^{\circ} \mathrm{C} ; \mathrm{B}\) increases the water temperature by \(2.60^{\circ} \mathrm{C}\). (a) Which object has the larger heat capacity? (b) What can you say about the specific heats of A and B?
The standard enthalpies of formation of gaseous propyne \(\left(\mathrm{C}_{3} \mathrm{H}_{4}\right)\), propylene \(\left(\mathrm{C}_{3} \mathrm{H}_{6}\right)\), and propane \(\left(\mathrm{C}_{3} \mathrm{H}_{8}\right)\) are \(+185.4,+20.4\), and \(-103.8 \mathrm{~kJ} / \mathrm{mol}\), respectively. (a) Calculate the heat evolved per mole on combustion of each substance to yield \(\mathrm{CO}_{2}(g)\) and \(\mathrm{H}_{2} \mathrm{O}(g) .\) (b) Calculate the heat evolved on combustion of \(1 \mathrm{~kg}\) of each substance.
The heat of combustion of ethanol, \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(l)\), is \(-1367 \mathrm{~kJ} / \mathrm{mol}\). A batch of Sauvignon Blanc wine contains \(10.6 \%\) ethanol by mass. Assuming the density of the wine to be \(1.0 \mathrm{~g} / \mathrm{mL}\), what caloric content does the alcohol (ethanol) in a 6-oz glass of wine (177 mL) have?
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