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Specify what ions are present in solution upon dissolving each of the following substances in water: (a) \(\mathrm{ZnCl}_{2}\), (b) \(\mathrm{HNO}_{3}\) (c) \(\left(\mathrm{NH}_{4}\right)_{2} \mathrm{SO}_{4}\), (d) \(\mathrm{Ca}(\mathrm{OH})_{2}\).

Short Answer

Expert verified
Upon dissolving the given substances in water, the following ions are present in the solution: (a) \(\mathrm{Zn}^{2+}\) and \(\mathrm{Cl}^-\), (b) \(\mathrm{H}^{+}\) and \(\mathrm{NO}_{3}^-\), (c) \(\mathrm{NH}_{4}^+\) and \(\mathrm{SO}_{4}^{2-}\), and (d) \(\mathrm{Ca}^{2+}\) and \(\mathrm{OH}^-\).

Step by step solution

01

(a) Dissolving ZnCl2 in water

When \(\mathrm{ZnCl}_{2}\) is dissolved in water, it separates into its constituent ions: a zinc ion (\(\mathrm{Zn}^{2+}\)) and two chloride ions (\(2\times\mathrm{Cl}^-\)). Therefore, the ions present in the solution are \(\mathrm{Zn}^{2+}\) and \(\mathrm{Cl}^-\) ions.
02

(b) Dissolving HNO₃ in water

When \(\mathrm{HNO}_{3}\) is dissolved in water, it ionizes into hydrogen ions (\(\mathrm{H}^{+}\)) and nitrate ions (\(\mathrm{NO}_{3}^-\)). Therefore, the ions present in the solution are \(\mathrm{H}^{+}\) and \(\mathrm{NO}_{3}^-\) ions.
03

(c) Dissolving (NHâ‚„)â‚‚SOâ‚„ in water

When \(\left(\mathrm{NH}_{4}\right)_{2} \mathrm{SO}_{4}\) is dissolved in water, it separates into its constituent ions: two ammonium ions (\(2\times\mathrm{NH}_{4}^+\)) and one sulfate ion (\(\mathrm{SO}_{4}^{2-}\)). Therefore, the ions present in the solution are \(\mathrm{NH}_{4}^+\) and \(\mathrm{SO}_{4}^{2-}\) ions.
04

(d) Dissolving Ca(OH)â‚‚ in water

When \(\mathrm{Ca}(\mathrm{OH})_{2}\) is dissolved in water, it separates into its constituent ions: a calcium ion (\(\mathrm{Ca}^{2+}\)) and two hydroxide ions (\(2\times\mathrm{OH}^-\)). Therefore, the ions present in the solution are \(\mathrm{Ca}^{2+}\) and \(\mathrm{OH}^-\) ions.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Dissolution Process
The dissolution process involves the breaking apart of substances when they interact with a solvent, often water, to form a solution. In this context, let's focus on substances like
  • Zinc chloride (\( \mathrm{ZnCl}_2 \))
  • Nitric acid (\( \mathrm{HNO}_3 \))
  • Ammonium sulfate (\( \left(\mathrm{NH}_4\right)_{2} \mathrm{SO}_4 \))
  • Calcium hydroxide (\( \mathrm{Ca(OH)}_2 \))
As each of these substances interacts with water, they dissociate into individual ions. For instance, when zinc chloride dissolves in water, it separates into zinc ions and chloride ions. This process is crucial in determining the properties of the resulting solution, including its conductivity and reactivity.
Aqueous Solutions
An aqueous solution refers to a solution where water acts as the solvent. Water's unique ability to dissolve many substances makes it an excellent medium for chemical reactions. When substances like calcium hydroxide or nitric acid are dissolved in water, they form aqueous solutions. The ions within these solutions are surrounded by water molecules, a phenomenon known as hydration. This helps stabilize the ions and allows them to move freely, making the solution conductive. The dissolution of substances into ions is essential for many biological and chemical processes, including nutrient absorption and chemical synthesis.
Chemical Ionization
Chemical ionization occurs during the dissolution process when a molecule separates into its constituent ions. This can happen either through dissociation, as with zinc chloride, or through ionization, as with nitric acid. For example, when ammonium sulfate dissolves in water, it dissociates into ammonium ions and sulfate ions. Factors affecting ionization include:
  • Temperature: Increasing temperature usually increases ionization.
  • Concentration: The concentration of the dissolved substance can influence the extent of ionization.
  • Nature of the solvent: Water, being polar, is excellent at promoting ionization.
Understanding ionization is key to predicting how substances will behave in different chemical environments.
Inorganic Chemistry
Inorganic chemistry is the branch of chemistry dealing with inorganic compounds, often those without carbon-hydrogen bonds. This includes a diverse set of substances, such as salts like zinc chloride and acids like nitric acid. In inorganic chemistry, understanding the behavior of ions in solutions is crucial. - **Ions and Reactions:** Ions are the active participants in many reactions, forming products through recombination. - **Acids and Bases:** Many inorganic reactions involve acids or bases dissolving, followed by ionization. For instance, calcium hydroxide provides hydroxide ions, which can neutralize acids. The study of these ion interactions is foundational to discovering new compounds and reactions, making inorganic chemistry an essential field of study.

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Most popular questions from this chapter

The newest U.S. standard for arsenate in drinking water, mandated by the Safe Drinking Water Act, required that by January 2006, public water supplies must contain no greater than 10 parts per billion (ppb) arsenic. If this arsenic is present as arsenate, \(\mathrm{AsO}_{4}{ }^{3-}\), what mass of sodium arsenate would be present in a 1.00-L sample of drinking water that just meets the standard?

A solution is made by mixing \(12.0 \mathrm{~g}\) of \(\mathrm{NaOH}\) and 75.0 \(\mathrm{mL}\) of \(0.200 \mathrm{M} \mathrm{HNO}_{3}\). (a) Write a balanced equation for the reaction that occurs between the solutes. (b) Calculate the concentration of each ion remaining in solution. (c) Is the resultant solution acidic or basic?

What is the difference between (a) a monoprotic acid and a diprotic acid, (b) a weak acid and a strong acid, (c) an acid and a base?

Because theoxide ion is basic, metal oxides react readily with acids. (a) Write the net ionic equation for the following reaction: $$ \mathrm{FeO}(s)+2 \mathrm{HClO}_{4}(a q) \longrightarrow \mathrm{Fe}\left(\mathrm{ClO}_{4}\right)_{2}(a q)+\mathrm{H}_{2} \mathrm{O}(l) $$ (b) Based on the equation in part (a), write the net ionic equation for the reaction that occurs between \(\mathrm{NiO}(s)\) and an aqueous solution of nitric acid.

Federal regulations set an upper limit of 50 parts per million ( \(\mathrm{ppm}\) ) of \(\mathrm{NH}_{3}\) in the air in a work environment [that is, 50 molecules of \(\mathrm{NH}_{3}(\mathrm{~g})\) for every million molecules in the air]. Air from a manufacturing operation was drawn through a solution containing \(1.00 \times 10^{2} \mathrm{~mL}\) of \(0.0105 \mathrm{M}\) HCl. The \(\mathrm{NH}_{3}\) reacts with \(\mathrm{HCl}\) as follows: $$ \mathrm{NH}_{3}(a q)+\mathrm{HCl}(a q) \longrightarrow \mathrm{NH}_{4} \mathrm{Cl}(a q) $$ After drawing air through the acid solution for \(10.0 \mathrm{~min}\) at a rate of \(10.0 \mathrm{~L} / \mathrm{min}\), the acid was titrated. The remaining acid needed \(13.1 \mathrm{~mL}\) of \(0.0588 \mathrm{M} \mathrm{NaOH}\) to reach the equivalence point. (a) How many grams of \(\mathrm{NH}_{3}\) were drawn into the acid solution? (b) How many ppm of \(\mathrm{NH}_{3}\) were in the air? (Air has a density of \(1.20 \mathrm{~g} / \mathrm{L}\) and an average molar mass of \(29.0 \mathrm{~g} / \mathrm{mol}\) under the conditions of the experiment.) (c) ls this manufacturer in compliance with regulations?

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