Chapter 23: Problem 63
Why is the \(+2\) oxidation state common among the transition metals? Why do so many transition metals exhibit a variety of oxidation states?
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Chapter 23: Problem 63
Why is the \(+2\) oxidation state common among the transition metals? Why do so many transition metals exhibit a variety of oxidation states?
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A sample containing \(\mathrm{PbSO}_{4}\) is to be refined to \(\mathrm{Pb}\) metal via calcination, followed by roasting. (a) What volatile product would you expect to be produced by calcination? (b) Propose an appropriate atmosphere to accompany the roasting. (c) Write balanced chemical equations for the two steps.
Describe how electrometallurgy could be employed to. purify crude cobalt metal. Describe the compositions of the electrodes and electrolyte, and write out all electrode reactions.
In an electrolytic process nickel sulfide is oxidized in ? two-step reaction: $$ \begin{array}{r} \mathrm{Ni}_{3} \mathrm{~S}_{2}(s) \longrightarrow \mathrm{Ni}^{2+}(a q)+2 \mathrm{NiS}(s)+2 \mathrm{e}^{-} \\ \mathrm{NiS}(s) \longrightarrow \mathrm{Ni}^{2+}(a q)+\mathrm{S}(s)+2 \mathrm{e}^{-} \end{array} $$ What mass of \(\mathrm{Ni}^{2+}\) is produced in solution by passing a current of 67 A for a period of \(11.0 \mathrm{hr}\), assuming the cell is \(90 \%\) efficient?
What is meant by the following terms: (a) calcination, (b) leaching, (c) smelting, (d) slag?
What is meant by the term lanthanide contraction? What properties of the transition elements are affected by the lanthanide contraction?
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