Chapter 23: Problem 33
Define the term alloy. Distinguish among solution alloys, heterogeneous alloys, and intermetallic compounds.
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Chapter 23: Problem 33
Define the term alloy. Distinguish among solution alloys, heterogeneous alloys, and intermetallic compounds.
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The electrical conductivity of titanium is approximately 2500 times greater than that of silicon. Titanium has a hexagonal close-packed structure, and silicon has the diamond structure. Explain how the structures relate to the relative electrical conductivities of the elements.
Tin exists in two allotropic forms: Gray tin has a diamond structure, and white tin has a close-packed structure. One of these allotropic forms is a semiconductor with a small band gap while the other is a metal. Which one is which? Which form would you expect to have the longer Sn -Sn bond distance?
The reduction of metal oxides is often accomplished using carbon monoxide as a reducing agent. Carbon (coke) and carbon dioxide are usually present, leading to the following reaction: $$ \mathrm{C}(\mathrm{s})+\mathrm{CO}_{2}(g) \rightleftharpoons 2 \mathrm{CO}(g) $$ Using data from Appendix \(C\), calculate the equilibrium constant for this reaction at \(298 \mathrm{~K}\) and at \(2000 \mathrm{~K}\), assuming that the enthalpies and entropies of formation do not depend upon temperature.
Magnesium is obtained by electrolysis of molten \(\mathrm{MgCl}_{2}\). (a) Why isn't an aqueous solution of \(\mathrm{MgCl}_{2}\) used in the electrolysis? (b) Several cells are connected in parallel by very large copper buses that convey current to the cells. Assuming that the cells are \(96 \%\) efficient in producing the desired products in electrolysis, what mass of \(\mathrm{Mg}\) is formed by passing a current of \(97,000 \mathrm{~A}\) for a period of \(24 \mathrm{hr}\)?
Associated with every antiferromagnetic solid is a temperature known as its Néel temperature. When heated above its Néel temperature the magnetic behavior changes from antiferromagnetic to paramagnetic. In contrast diamagnetic substances do not generally become paramagnetic upon heating. How do you explain this difference in behavior?
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