Chapter 22: Problem 42
Draw the Lewis structure of ozone. Explain why the \(\mathrm{O}-\mathrm{O}\) bond \((1.28 \AA)\) is longer in ozone than in \(\mathrm{O}_{2}(1.21 \AA)\).
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Chapter 22: Problem 42
Draw the Lewis structure of ozone. Explain why the \(\mathrm{O}-\mathrm{O}\) bond \((1.28 \AA)\) is longer in ozone than in \(\mathrm{O}_{2}(1.21 \AA)\).
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Account for the following observations: (a) Phosphorus forms a pentachloride, but nitrogen does not. (b) \(\mathrm{H}_{3} \mathrm{PO}_{2}\) is a monoprotic acid. (c) Phosphonium salts, such as \(\mathrm{PH}_{4} \mathrm{Cl}\), can be formed under anhydrous conditions, but they can't be made in aqueous solution. (d) White phosphorus is extremely reactive.
Boron nitride has a graphite-like structure with \(\mathrm{B}-\mathrm{N}\) bond distances of \(1.45 \AA\) within sheets and a separation of \(3.30 \AA\) between sheets. At high temperatures the \(B N\) assumes a diamondlike form that is almost as hard as diamond. Rationalize the similarity between \(\mathrm{BN}\) and elemental carbon.
The atomic and ionic radii of the first three group \(6 \mathrm{~A}\) elements are (a) Explain why the atomic radius increases in moving downward in the group. (b) Explain why the ionic radii are larger than the atomic radii. (c) Which of the three anjons would you expect to be the strongest base in water? Explain.
The dissolved oxygen present in any highly pressurized, high-temperature steam boiler can be extremely corrosive to its metal parts. Hydrazine, which is completely miscible with water, can be added to remove oxygen by reacting with it to form nitrogen and water. (a) Write the balanced equation for the reaction between gaseous hydrazine and oxygen. (b) Calculate the enthalpy change accompanying this reaction. (c) Oxygen in air dissolves in water to the extent of \(9.1\) ppm at \(20^{\circ} \mathrm{C}\) at sea level. How many grams of hydrazine are required to react with all the oxygen in \(3.0 \times 10^{4} \mathrm{~L}\) (the volume of a small swimming pool) under these conditions?
(a) List three industrial uses of \(\mathrm{O}_{2} .\) (b) List two industrial uses of \(\mathrm{O}_{3}\)
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