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(a) What is an electrolytic cell? (b) The negative terminal of a voltage source is connected to an electrode of an electrolytic cell. Is the electrode the anode or the cathode of the cell? Explain. (c) The electrolysis of water is often done with a small amount of sulfuric acid added to the water. What is the role of the sulfuric acid?

Short Answer

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(a) An electrolytic cell is a device that uses an electric current to drive chemical reactions, typically reduction-oxidation, at the electrodes through a process known as electrolysis. (b) The electrode connected to the negative terminal of a voltage source is the cathode of the electrolytic cell, where reduction occurs due to the gain of electrons. (c) Sulfuric acid, when added to water during electrolysis, serves as an electrolyte, enhancing the electrical conductivity of the solution and facilitating the flow of electric current for a more efficient process.

Step by step solution

01

(a) Definition of Electrolytic Cell

An electrolytic cell is a device in which an electric current is passed through a solution containing ions, causing a chemical reaction (typically reduction-oxidation) to occur at the electrodes. This process, known as electrolysis, can result in the deposition of a substance, the production of gases, or the dissociation of a solution.
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(b) Identification of the Anode or Cathode

Since the negative terminal of a voltage source is connected to the electrode, this electrode is the cathode of the electrolytic cell. In an electrolytic cell, the cathode is where reduction occurs, meaning a gain of electrons. Electrons flow from the negative terminal of the voltage source to the cathode, allowing for the reduction reaction to take place at this electrode.
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(c) Role of Sulfuric Acid in Water Electrolysis

The role of sulfuric acid in the electrolysis of water is to act as an electrolyte, or a substance that increases the electrical conductivity of the solution. This helps to facilitate the flow of electric current through the solution, making the electrolysis process more efficient. Since pure water has very low electrical conductivity, the addition of a small amount of sulfuric acid (Hâ‚‚SOâ‚„) significantly improves the rate of electrolysis by providing a greater number of ions to carry the electric current.

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Most popular questions from this chapter

A student designs an ammeter (a device that measures electrical current) that is based on the electrolysis of water into hydrogen and oxygen gases. When electrical current of unknown magnitude is run through the device for \(2.00 \mathrm{~min}, 12.3 \mathrm{~mL}\) of water-saturated \(\mathrm{H}_{2}(\mathrm{~g})\) is collected. The temperature of the system is \(25.5^{\circ} \mathrm{C}\), and the atmospheric pressure is 768 torr. What is the magnitude of the current in amperes?

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Derive an equation that directly relates the standard emf of a redox reaction to its equilibrium constant.

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