Chapter 20: Problem 105
If you were going to apply a small potential to a steel ship resting in the water as a means of inhibiting corrosion, would you apply a negative or a positive charge? Explain.
/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none}
Learning Materials
Features
Discover
Chapter 20: Problem 105
If you were going to apply a small potential to a steel ship resting in the water as a means of inhibiting corrosion, would you apply a negative or a positive charge? Explain.
All the tools & learning materials you need for study success - in one app.
Get started for free
A voltaic cell is constructed with two silver-silver chloride electrodes, each of which is based on the following half-reaction: $$ \mathrm{AgCl}(s)+\mathrm{e}^{-}--\rightarrow \mathrm{Ag}(s)+\mathrm{Cl}^{-}(a q) $$ The two cell compartments have \(\left[\mathrm{Cl}^{-} \mathrm{J}=0.0150 \mathrm{M}\right.\) and \(\left[\mathrm{Cl}^{-}\right]=2.55 M\), respectively. (a) Which electrode is the cathode of the cell? (b) What is the standard emf of the cell? (c) What is the cell emf for the concentrations given? (d) For each electrode, predict whether [Cl \(^{-}\) ] will increase, decrease, or stay the same as the cell operates.
A voltaic cell is based on \(\mathrm{Ag}^{+}(a q) / \mathrm{Ag}(\mathrm{s})\) and \(\mathrm{Fe}^{3+}(a q) / \mathrm{Fe}^{2+}(a q)\) half-cells. (a) What is the standard emf of the cell? (b) Which reaction occurs at the cathode, and which at the anode of the cell? (c) Use \(S^{\circ}\) values in Appendix \(C\) and the relationship between cell potential and free-energy change to predict whether the standard cell potential increases or decreases when the temperature is raised above \(25^{\circ} \mathrm{C}\).
A student designs an ammeter (a device that measures electrical current) that is based on the electrolysis of water into hydrogen and oxygen gases. When electrical current of unknown magnitude is run through the device for \(2.00 \mathrm{~min}, 12.3 \mathrm{~mL}\) of water-saturated \(\mathrm{H}_{2}(\mathrm{~g})\) is collected. The temperature of the system is \(25.5^{\circ} \mathrm{C}\), and the atmospheric pressure is 768 torr. What is the magnitude of the current in amperes?
(a) Write the half-reaction that occurs at a hydrogen electrode in acidic aqueous solution when it serves as the cathode of a voltaic cell. (b) What is standard about the standard hydrogen electrode? (c) What is the role of the platinum foil in a standard hydrogen electrode?
An iron object is plated with a coating of cobalt to protect against corrosion. Does the cobalt protect iron by cathodic protection? Explain.
What do you think about this solution?
We value your feedback to improve our textbook solutions.