Chapter 19: Problem 19
Consider a system consisting of an ice cube. (a) Under what conditions can the ice cube melt reversibly? (b) If the ice cube melts reversibly, is \(\Delta E\) zero for the process? Explain.
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Chapter 19: Problem 19
Consider a system consisting of an ice cube. (a) Under what conditions can the ice cube melt reversibly? (b) If the ice cube melts reversibly, is \(\Delta E\) zero for the process? Explain.
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(a) What is the meaning of the standard free-energy change, \(\Delta G^{\circ}\), as compared with \(\Delta G ?\) (b) For any process that occurs at constant temperature and pressure, what is the significance of \(\Delta G=0 ?(c)\) For a certain process, \(\Delta G\) is large and negative. Does this mean that the process necessarily occurs rapidly?
The value of \(K_{a}\) for nitrous acid \(\left(\mathrm{HNO}_{2}\right)\) at \(25^{\circ} \mathrm{C}\) is given in Appendix D. (a) Write the chemical equation for the equilibrium that corresponds to \(K_{a}\). (b) By using the value of \(K_{a}\) calculate \(\Delta G^{\circ}\) for the dissociation of nitrous acid in aqueous solution. (c) What is the value of \(\Delta G\) at equilibrium? (d) What is the value of \(\Delta G\) when \(\left[\mathrm{H}^{+}\right]=5.0 \times 10^{-2} \mathrm{M}\), \(\left[\mathrm{NO}_{2}^{-}\right]=6.0 \times 10^{-4} M\), and \(\left[\mathrm{HNO}_{2}\right]=0.20 \mathrm{M} ?\)
(a) Express the second law of thermodynamics as a mathematical equation. (b) In a particular spontaneous process the entropy of the system decreases. What can you conclude about the sign and magnitude of \(\Delta S_{\text {surr }}\) ? (c) During a certain reversible process, the surroundings undergo an entropy change, \(\Delta S_{\text {surr }}=-78 \mathrm{~J} / \mathrm{K} .\) What is the entropy change of the system for this process?
Consider the reaction \(2 \mathrm{NO}_{2}(g) \longrightarrow \mathrm{N}_{2} \mathrm{O}_{4}(g) .\) (a) Using data from Appendix \(C\), calculate \(\Delta G^{\circ}\) at \(298 \mathrm{~K}\). (b) Calculate \(\Delta G\) at \(298 \mathrm{~K}\) if the partial pressures of \(\mathrm{NO}_{2}\) and \(\mathrm{N}_{2} \mathrm{O}_{4}\) are \(0.40 \mathrm{~atm}\) and \(1.60 \mathrm{~atm}\), respectively.
Predict the sign of the entropy change of the system for each of the following reactions: (a) \(2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{SO}_{3}(g)\) (b) \(\mathrm{Ba}(\mathrm{OH})_{2}(s) \longrightarrow \mathrm{BaO}(s)+\mathrm{H}_{2} \mathrm{O}(g)\) (c) \(\mathrm{CO}(\mathrm{g})+2 \mathrm{H}_{2}(\mathrm{~g}) \longrightarrow \mathrm{CH}_{3} \mathrm{OH}(l)\) (d) \(\mathrm{FeCl}_{2}(s)+\mathrm{H}_{2}(g) \longrightarrow \mathrm{Fe}(s)+2 \mathrm{HCl}(g)\)
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