Chapter 18: Problem 48
Discuss how catalysts can make processes more energy efficient.
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Chapter 18: Problem 48
Discuss how catalysts can make processes more energy efficient.
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Explain, using Le Châtelier's principle, why the equilibrium constant for the formation of NO from \(\mathrm{N}_{2}\) and \(\mathrm{O}_{2}\) increases with increasing temperature, whereas the equilibrium constant for the formation of \(\mathrm{NO}_{2}\) from NO and \(\mathrm{O}_{2}\) decreases with increasing temperature.
Ferrous sulfate \(\left(\mathrm{FeSO}_{4}\right)\) is often used as a coagulant in water purification. The iron(II) salt is dissolved in the water to be purified, then oxidized to the iron(III) state by dissolved oxygen, at which time gelatinous \(\mathrm{Fe}(\mathrm{OH})_{3}\) forms, assuming the \(\mathrm{pH}\) is above approximately 6. Write balanced chemical equations for the oxidation of \(\mathrm{Fe}^{2+}\) to \(\mathrm{Fe}^{3+}\) by dissolved oxygen, and for the formation of \(\mathrm{Fe}(\mathrm{OH})_{3}(\mathrm{~s})\) by reaction of \(\mathrm{Fe}^{3+}(a q)\) with \(\mathrm{HCO}_{3}^{-}(a q)\).
It is estimated that the lifetime for HFCs in the stratosphere is \(2-7\) years. If HFCs have such long lifetimes, why are they being used to replace CFCs?
The precipitation of \(\mathrm{A} \mathrm{L}(\mathrm{OH})_{3}\left(K_{\text {sp }}=1.3 \times 10^{-33}\right.\) ) is sometimes used to purify water. (a) Estimate the \(\mathrm{pH}\) at wh?ch precipitation of \(\mathrm{Al}(\mathrm{OH})_{3}\) will begin if \(5.0 \mathrm{lb}\) of \(\mathrm{Al}_{2}\left(\mathrm{SO}_{4}\right)_{3}\) is added to \(2000 \mathrm{gal}\) of water. (b) Approximately how many pounds of \(\mathrm{CaO}\) must be added to the water to achieve this \(\mathrm{pH}\) ?
(a) Distinguish between photodissociation and photoionization. (b) Use the energy requirements of these two processes to explain why photodissociation of oxygen is more important than photoionization of oxygen at altitudes below about \(90 \mathrm{~km}\).
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