Chapter 18: Problem 46
What properties make a substance a good coagulant for water purification?
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Chapter 18: Problem 46
What properties make a substance a good coagulant for water purification?
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Draw the Lewis structure for the chlorofluorocarbon CFC-11, CFCly. What chemical characteristics of this substance allow it to effectively deplete stratospheric ozone?
The hydroxyl radical, \(\mathrm{OH}\), is formed at low altitudes via the reaction of excited oxygen atoms with water: $$ \mathrm{O}^{4}(g)+\mathrm{H}_{2} \mathrm{O}(g) \longrightarrow 2 \mathrm{OH}(g) $$ (a) Write the Lewis structure for the hydroxyl radical (Hint: It has one unpaired electron.) Once produced, the hydroxyl radical is very reactive. Explain why each of the following series of reactions affects the pollution in the troposphere: (b) \(\mathrm{OH}+\mathrm{NO}_{2} \longrightarrow \mathrm{HNO}_{3}\) (c) \(\mathrm{OH}+\mathrm{CO}+\mathrm{O}_{2} \longrightarrow \mathrm{CO}_{2}+\mathrm{OOH}\) \(\mathrm{OOH}+\mathrm{NO} \longrightarrow \mathrm{OH}+\mathrm{NO}_{2}\) (d) \(\mathrm{OH}+\mathrm{CH}_{4} \longrightarrow \mathrm{H}_{2} \mathrm{O}+\mathrm{CH}_{3}\) \(\mathrm{CH}_{3}+\mathrm{O}_{2} \longrightarrow \mathrm{OOCH}_{3}\) \(\mathrm{OOCH}_{3}+\mathrm{NO} \longrightarrow \mathrm{OCH}_{3}+\mathrm{NO}_{2}\)
The precipitation of \(\mathrm{A} \mathrm{L}(\mathrm{OH})_{3}\left(K_{\text {sp }}=1.3 \times 10^{-33}\right.\) ) is sometimes used to purify water. (a) Estimate the \(\mathrm{pH}\) at wh?ch precipitation of \(\mathrm{Al}(\mathrm{OH})_{3}\) will begin if \(5.0 \mathrm{lb}\) of \(\mathrm{Al}_{2}\left(\mathrm{SO}_{4}\right)_{3}\) is added to \(2000 \mathrm{gal}\) of water. (b) Approximately how many pounds of \(\mathrm{CaO}\) must be added to the water to achieve this \(\mathrm{pH}\) ?
The Baeyer-Villiger reaction is a classic organic oxidation reaction for converting ketones to lactones, as in this reaction: The reaction is used in the manufacture of plastics and pharmaceuticals. The reactant 3 -chloroperbenzoic acid is somewhat shock sensitive, however, and prone to explode Also, 3 -chlorobenzoic acid is a waste product. An alternative process being developed uses hydrogen peroxide and a catalyst consisting of tin deposited within a solid support. The catalyst is readily recovered from the reaction mixture. (a) What would you expect to be the other product of oxidation of the ketone to lactone by hydrogen peroxide? (b) What principles of green chemistry are addressed by use of the proposed process?
Nitrogen dioxide \(\left(\mathrm{NO}_{2}\right)\) is the only important gaseous species in the lower atmosphere that absorbs visible light. (a) Write the Lewis structure(s) for \(\mathrm{NO}_{2}\). (b) How does this structure account for the fact that \(\mathrm{NO}_{2}\) dimerizes to form \(\mathrm{N}_{2} \mathrm{O}_{4}\) ? Based on what you can find about this dimerization reaction in the text, would you expect to find the \(\mathrm{NO}_{2}\) that forms in an urban environment to be in the form of dimer? Explain. (c) What would you expect as products, if any, for the reaction of \(\mathrm{NO}_{2}\) with CO? (d) Would you expect \(\mathrm{NO}_{2}\) generated in an urban environment to migrate to the stratosphere? Explain.
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