/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 33 A first-stage recovery of magnes... [FREE SOLUTION] | 91影视

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A first-stage recovery of magnesium from seawater is precipitation of \(\mathrm{Mg}(\mathrm{OH})_{2}\) with \(\mathrm{CaO}\) : \(\mathrm{Mg}^{2+}(a q)+\mathrm{CaO}(\mathrm{s})+\mathrm{H}_{2} \mathrm{O}(t) \longrightarrow \mathrm{Mg}(\mathrm{OH})_{2}(s)+\mathrm{Ca}^{2+}(a q)\) What mass of \(\mathrm{CaO}\), in grams, is needed to precipitate \(1000 \mathrm{lb}\) of \(\mathrm{Mg}(\mathrm{OH})_{2} ?\)

Short Answer

Expert verified
Approximately 435,914.19 grams of CaO are needed to precipitate 1000 lb of Mg(OH)鈧 from seawater.

Step by step solution

01

Convert the mass of Mg(OH)鈧 to moles

Given that we have 1000 lb of Mg(OH)鈧, we need to convert this mass to grams and then to moles using the molar mass of Mg(OH)鈧 (58.32 g/mol). 1000 lb 脳 (453.592 g / 1 lb) = 453,592 g Now, we can convert grams to moles: Moles of Mg(OH)鈧 = mass of Mg(OH)鈧 / molar mass of Mg(OH)鈧 Moles of Mg(OH)鈧 = 453,592 g / 58.32 g/mol 鈮 7775.86 mol
02

Use the stoichiometry to find moles of CaO required

Using the balanced equation Mg虏鈦(aq) + CaO(s) + H鈧侽(l) 鈫 Mg(OH)鈧(s) + Ca虏鈦(aq) We can see that the mole ratio between Mg(OH)鈧 and CaO is 1:1. So, moles of CaO required = moles of Mg(OH)鈧 鈮 7775.86 mol
03

Convert moles of CaO to grams

Now, we need to convert these moles of CaO to grams using its molar mass (56.08 g/mol). Mass of CaO = moles of CaO 脳 molar mass of CaO Mass of CaO 鈮 7775.86 mol 脳 56.08 g/mol 鈮 435,914.19 g So, approximately 435,914.19 grams of CaO are needed to precipitate 1000 lb of Mg(OH)鈧 from seawater.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Mole-Mass Calculations
Understanding mole-mass calculations is essential for students tackling stoichiometry in chemical reactions. The concept revolves around converting mass (usually in grams) to moles, a fundamental step in stoichiometry. This is carried out using the substance's molar mass as a conversion factor. For instance, if you're given a mass of a compound, you can determine the number of moles by dividing the mass by the compound's molar mass.
In the provided example, we start by converting the mass of magnesium hydroxide, Mg(OH)2, from pounds to grams. We do this because molar masses are given in grams per mole, enabling direct calculation of moles. Once the mass is in grams, the conversion to moles is straightforward. By doing these mole-mass calculations, we lay the foundation for further stoichiometric analyses, such as deducing the amounts of reactants or products participating in a chemical reaction.
Chemical Precipitation
Chemical precipitation is a process widely used in chemistry to separate a solid from a solution. When a reaction occurs that forms an insoluble solid鈥攌nown as a precipitate鈥攖he substance can then be filtered out from the remaining liquid. This method is often employed in water treatment, mineral recovery, and various analytical procedures.

In our example, chemical precipitation is utilized to recover magnesium from seawater. The reaction between seawater's dissolved Mg2+ ions and CaO, in the presence of water, results in magnesium hydroxide as a solid precipitate. This solid is then separated from the seawater, effectively extracting the magnesium. Precipitation reactions are valuable, especially in large-scale processes, because they allow for the cost-effective retrieval of specific components from mixtures.
Molar Mass
The molar mass is one of the most fundamental aspects of chemical calculations鈥攄efined as the mass of one mole of a substance. It is expressed typically in grams per mole (g/mol). The molar mass is crucial because it relates the mass of a substance to the number of particles or moles, which allows chemists to count molecules by weighing them.
When calculating the molar mass, we sum up the atomic masses of all the atoms in a molecule, as found on the periodic table. In the exercise, the molar mass is used as a conversion factor in mole-mass calculations. Knowing the molar mass of Mg(OH)2 and CaO is essential to solve the problem at hand. It not only helps determine how many moles of each substance are involved but also allows for the necessary conversions to answer the question about the mass of CaO required.
Balanced Chemical Equations
Balanced chemical equations are the backbone of stoichiometry. They ensure that the law of conservation of mass is obeyed, indicating that the same number of atoms for each element is present on both the reactant and product sides of the equation. This balance is fundamental because it provides the mole ratios needed to calculate the quantities of reactants and products involved in a chemical reaction.
Using the balanced equation, we can deduce that the mole ratio between magnesium hydroxide (Mg(OH)2) and calcium oxide (CaO) is 1:1. This ratio is the key to determining the precise amount of CaO needed to react with a given amount of Mg(OH)2. Without a balanced chemical equation, we would not be able to make the precise stoichiometric calculations as illustrated in the example provided.

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