Chapter 16: Problem 110
Calculate the \(\mathrm{pH}\) of a solution made by adding \(2.50 \mathrm{~g}\) of lithium oxide \(\left(\mathrm{Li}_{2} \mathrm{O}\right)\) to enough water to make \(1.500 \mathrm{~L}\) of solution.
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Chapter 16: Problem 110
Calculate the \(\mathrm{pH}\) of a solution made by adding \(2.50 \mathrm{~g}\) of lithium oxide \(\left(\mathrm{Li}_{2} \mathrm{O}\right)\) to enough water to make \(1.500 \mathrm{~L}\) of solution.
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Which of the following solutions has the higher pH? (a) a \(0.1 \mathrm{M}\) solution of a strong acid or a \(0.1 \mathrm{M}\) solution of a weak acid, (b) a \(0.1 \mathrm{M}\) solution of an acid with \(K_{a}=2 \times 10^{-3}\) or one with \(K_{a}=8 \times 10^{-6}\), (c) a 0.1 M solution of a base with \(\mathrm{pK}_{b}=4.5\) or one with \(\mathrm{pK}_{b}=6.5\).
Predict the products of the following acid-base reactions, and predict whether the equilibrium lies to the left or to the right of the equation: (a) \(\mathrm{O}^{2-}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons\) (b) \(\mathrm{CH}_{3} \mathrm{COOH}(a q)+\mathrm{HS}^{-}(a q) \rightleftharpoons\) (c) \(\mathrm{NO}_{2}^{-}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons\)
Ephedrine, a central nervous system stimulant, is used in nasal sprays as a decongestant. This compound is a weak organic base: \(\mathrm{C}_{10} \mathrm{H}_{15} \mathrm{ON}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{C}_{10} \mathrm{H}_{15} \mathrm{ONH}^{+}(a q)+\mathrm{OH}^{-}(a q)\) A \(0.035 \mathrm{M}\) solution of ephedrine has a pH of \(11.33 .\) (a) What are the equilibrium concentrations of \(\mathrm{C}_{10} \mathrm{H}_{15} \mathrm{ON}, \mathrm{C}_{10} \mathrm{H}_{15} \mathrm{ONH}^{+}\), and \(\mathrm{OH}^{-} ?\) (b) Calculate \(K_{b}\) for ephedrine.
If a substance is a Lewis acid, is it necessarily a Brønsted-Lowry acid? Is it necessarily an Arrhenius acid? Explain.
Deuterium oxide \(\left(\mathrm{D}_{2} \mathrm{O}\right.\), where \(\mathrm{D}\) is deuterium, the hydrogen- 2 isotope) has an ion-product constant, \(K_{\mathrm{uu}}\) of \(8.9 \times 10^{-16}\) at \(20^{\circ} \mathrm{C}\) Calculate \(\left[\mathrm{D}^{+}\right]\) and \(\left[\mathrm{OD}^{-}\right]\) for pure(neutral) \(\mathrm{D}_{2} \mathrm{O}\) at this temperature.
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