A mixture of \(0.2000 \mathrm{~mol}\) of \(\mathrm{CO}_{2}, 0.1000 \mathrm{~mol}\)
of \(\mathrm{H}_{2}\), and \(0.1600 \mathrm{~mol}\) of \(\mathrm{H}_{2} \mathrm{O}\)
is placed in a 2.000-L vessel. The following equilibrium is established at
\(500 \mathrm{~K}\) :
$$
\mathrm{CO}_{2}(\mathrm{~g})+\mathrm{H}_{2}(\mathrm{~g}) \rightleftharpoons
\mathrm{CO}(\mathrm{g})+\mathrm{H}_{2} \mathrm{O}(\mathrm{g})
$$
(a) Calculate the initial partial pressures of \(\mathrm{CO}_{2},
\mathrm{H}_{2}\) and \(\mathrm{H}_{2} \mathrm{O} .\) (b) At equilibrium
\(P_{\mathrm{H}_{2} \mathrm{O}}=3.51 \mathrm{~atm}\). Calculate the equilibrium
partial pressures of \(\mathrm{CO}_{2}, \mathrm{H}_{2}\), and \(\mathrm{CO}\).
(c) Calculate \(K_{n}\) for the reaction.