/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 47 (a) What factors determine wheth... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

(a) What factors determine whether a collision between two molecules will lead to a chemical reaction? (b) According to the collision model, why does temperature affect the value of the rate constant?

Short Answer

Expert verified
(a) A successful chemical reaction between two colliding molecules depends on two factors: 1) having enough activation energy (Ea) to overcome the energy barrier and break necessary bonds in reactant molecules, and 2) correct orientation during the collision, which allows the reactive parts of the molecules to come into direct contact (steric factor). (b) According to the collision model, temperature affects the rate constant by increasing both the kinetic energy of molecules and the collision frequency. This results in more molecules having the required activation energy and higher chances of collisions with the correct orientation, leading to an increased rate constant.

Step by step solution

01

Factors determining a successful chemical reaction from molecular collision

To have a successful chemical reaction following a collision between two molecules, the following two conditions must be met: 1. The molecules must have enough energy, called the activation energy (Ea), to overcome the energy barrier and react. Activation energy is the minimum amount of energy needed to break the required bonds in the reactant molecules. 2. The molecules must be oriented correctly when they collide, such that the reactive parts of the molecules come into direct contact. This is called the steric factor.
02

Collision Model

The collision model is a theory which states that a chemical reaction can occur only when reactant molecules come into direct contact with sufficient energy and the correct orientation. This theory primarily depends on two factors: collision frequency (how often the molecules collide) and the fraction of collisions possessing the minimum activation energy (Ea) and correct orientation.
03

Temperature effect on the value of the rate constant

According to the collision model, increasing the temperature leads to an increase in the rate constant because temperature has two main effects on the reaction: 1. Increased temperature leads to an increase in the kinetic energy of the molecules. This means that more molecules will possess the required activation energy (Ea) to overcome the energy barrier and successfully react. The higher the temperature, the greater the fraction of molecules with enough energy to react. 2. Increased temperature also increases the collision frequency between molecules. When molecules have higher energy, they move faster and collide more frequently. Hence, the chances of having successful collisions with the correct orientation increase. These two factors combine to make the overall rate of the reaction much faster, increasing the value of the rate constant at high temperatures.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

The reaction \(2 \mathrm{NO}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{NO}_{2}(g)\) is second order in \(\mathrm{NO}\) and first order in \(\mathrm{O}_{2}\). When \([\mathrm{NO}]=0.040 \mathrm{M}\) and \(\left[\mathrm{O}_{2}\right]=0.035 \mathrm{M}\), the observed rate of disappearance of \(\mathrm{NO}\) is \(9.3 \times 10^{-5} \mathrm{M} / \mathrm{s}\). (a) What is the rate of disappearance of \(\mathrm{O}_{2}\) at this moment? (b) What is the value of the rate constant? (c) What are the units of the rate constant? (d) What would happen to the rate if the concentration of NO were increased by a factor of \(1.8\) ?

In a hydrocarbon solution, the gold compound \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{AuPH}_{3}\) decomposes into ethane \(\left(\mathrm{C}_{2} \mathrm{H}_{6}\right)\) and a dif- ferent gold compound, \(\left(\mathrm{CH}_{3}\right) \mathrm{AuPH}_{3}\). The following mechanism has been proposed for the decomposition of \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{AuPH}_{3}:\) Step 1: \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{AuPH}_{3} \underset{k_{-1}}{\stackrel{k_{1}}{\rightleftharpoons}\left(\mathrm{CH}_{3}\right)_{3} \mathrm{Au}+\mathrm{PH}_{3} \quad \text { (fast) }}\) Step 2: \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{Au} \stackrel{\mathrm{k}_{2}}{\longrightarrow} \mathrm{C}_{2} \mathrm{H}_{6}+\left(\mathrm{CH}_{3}\right) \mathrm{Au} \quad\) (slow) Step 3: \(\left(\mathrm{CH}_{3}\right) \mathrm{Au}+\mathrm{PH}_{3} \stackrel{k_{2}}{\longrightarrow}\left(\mathrm{CH}_{3}\right) \mathrm{AuPH}_{3} \quad\) (fast) (a) What is the overall reaction? (b) What are the intermediates in the mechanism? (c) What is the molecularity of each of the elementary steps? (d) What is the ratedetermining step? (e) What is the rate law predicted by this mechanism? (f) What would be the effect on the reaction rate of adding \(\mathrm{PH}_{3}\) to the solution of \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{AuPH}_{3} ?\)

A certain first-order reaction has a rate constant of \(2.75 \times 10^{-2} \mathrm{~s}^{-1}\) at \(20^{\circ} \mathrm{C}\). What is the value of \(k\) at \(60^{\circ} \mathrm{C}\) if (a) \(E_{a}=75.5 \mathrm{~kJ} / \mathrm{mol} ;\) (b) \(E_{a}=125 \mathrm{~kJ} / \mathrm{mol}\) ?

The following mechanism has been proposed for the reaction of \(\mathrm{NO}\) with \(\mathrm{H}_{2}\) to form \(\mathrm{N}_{2} \mathrm{O}\) and \(\mathrm{H}_{2} \mathrm{O}\) : $$ \begin{aligned} &\mathrm{NO}(g)+\mathrm{NO}(g) \longrightarrow \mathrm{N}_{2} \mathrm{O}_{2}(g) \\ &\mathrm{N}_{2} \mathrm{O}_{2}(g)+\mathrm{H}_{2}(g) \longrightarrow \mathrm{N}_{2} \mathrm{O}(g)+\mathrm{H}_{2} \mathrm{O}(g) \end{aligned} $$ (a) Show that the elementary reactions of the proposed mechanism add to provide a balanced equation for the reaction. (b) Write a rate law for each elementary reaction in the mechanism. (c) Identify any intermediates in the mechanism. (d) The observed rate law is rate \(=k[\mathrm{NO}]^{2}\left[\mathrm{H}_{2}\right]\). If the proposed mechanism is correct, what can we conclude about the relative speeds of the first and second reactions?

Sucrose \(\left(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\right)\), which is commonly known as table sugar, reacts in dilute acid solutions to form two simpler sugars, glucose and fructose, both of which have the formula \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\) : At \(23^{\circ} \mathrm{C}\) and in \(0.5 \mathrm{M} \mathrm{HCl}\), the following data were obtained for the disappearance of sucrose: $$ \begin{array}{cl} \hline \text { Time }(\mathrm{min}) & \left.\mathrm{IC}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\right](M) \\ \hline 0 & 0.316 \\ 39 & 0.274 \\ 80 & 0.238 \\ 140 & 0.190 \\ 210 & 0.146 \end{array} $$ (a) Is the reaction first order or second order with respect to \(\left[\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\right] ?\) (b) What is the value of the rate constant?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.