Chapter 11: Problem 9
List the three states of matter in order of (a) increasing molecular disorder and (b) increasing intermolecular attractions. (c) Which state of matter is most easily compressed?
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Chapter 11: Problem 9
List the three states of matter in order of (a) increasing molecular disorder and (b) increasing intermolecular attractions. (c) Which state of matter is most easily compressed?
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Compounds like \(\mathrm{CCl}_{2} \mathrm{~F}_{2}\) are known as chlorofluorocarbons, or CFCs. These compounds were once widely used as refrigerants but are now being replaced by compounds that are believed to be less harmful to the environment. The heat of vaporization of \(\mathrm{CCl}_{2} \mathrm{~F}_{2}\) is \(289 \mathrm{~J} / \mathrm{g}\). What mass of this substance must evaporate to freeze \(200 \mathrm{~g}\) of water initially at \(15^{\circ} \mathrm{C} ?\) (The heat of fusion of water is \(334 \mathrm{~J} / \mathrm{g} ;\) the specific heat of water is \(4.18 \mathrm{~J} / \mathrm{g}-\mathrm{K}\).)
Explain the following observations: (a) The surface tension of \(\mathrm{CHBr}_{3}\) is greater than that of \(\mathrm{CHCl}_{3}\). (b) As temperature increases, oil flows faster through a narrow tube. (c) Raindrops that collect on a waxed automobile hood take on a nearly spherical shape. (d) Oil droplets that collect on a waxed automobile hood take on a flat shape.
The normal melting and boiling points of \(\mathrm{O}_{2}\) are \(-218{ }^{\circ} \mathrm{C}\) and \(-183{ }^{\circ} \mathrm{C}\) respectively. Its triple point is at \(-219^{\circ} \mathrm{C}\) and \(1.14\) torr, and its critical point is at \(-119^{\circ} \mathrm{C}\) and \(49.8\) atm. (a) Sketch the phase diagram for \(\mathrm{O}_{2}\), showing the four points given and indicating the area in which each phase is stable. (b) Will \(\mathrm{O}_{2}(s)\) float on \(\mathrm{O}_{2}(I)\) ? Explain. (c) As it is heated, will solid \(\mathrm{O}_{2}\) sublime or melt under a pressure of 1 atm?
Which type (or types) of crystalline solid is characterized by each of the following: (a) high mobility of electrons throughout the solid; (b) softness, relatively low melting point; (c) high melting point and poor electrical conductivity; (d) network of covalent bonds; (e) charged particles throughout the solid.
Look up and compare the normal boiling points and normal melting points of \(\mathrm{H}_{2} \mathrm{O}\) and \(\mathrm{H}_{2} \mathrm{~S}\). (a) Based on these physical properties, which substance has stronger intermolecular forces? What kind of intermolecular forces exist for each molecule? (b) Predict whether solid \(\mathrm{H}_{2} \mathrm{~S}\) is more or less dense than liquid \(\mathrm{H}_{2} \mathrm{~S}\). How does this compare to \(\mathrm{H}_{2} \mathrm{O}\) ? Explain. (c) Water has an unusually high specific heat. Is this related to its intermolecular forces? Explain.
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