Chapter 9: Problem 3
Explain the difference between heat capacity and specific heat of a substance.
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Chapter 9: Problem 3
Explain the difference between heat capacity and specific heat of a substance.
These are the key concepts you need to understand to accurately answer the question.
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When a 0.740-g sample of trinitrotoluene (TNT), \(\mathrm{C}_{7} \mathrm{H}_{5} \mathrm{N}_{2} \mathrm{O}_{6}\), is bumed in a bomb calorimeter, the temperature increases from \(23.4^{\circ} \mathrm{C}\) to \(26.9^{\circ} \mathrm{C}\). The heat capacity of the calorimeter is \(534 \mathrm{J} /^{\circ} \mathrm{C}\), and it contains \(675 \mathrm{mL}\) of water. How much heat was produced by the combustion of the TNT sample?
Explain why bonds occur at specific average bond distances instead of the atoms approaching each other infinitely close.
The oxidation of the sugar glucose, \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\), is described by the following equation: \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(s)+6 \mathrm{O}_{2}(g) \longrightarrow 6 \mathrm{CO}_{2}(g)+6 \mathrm{H}_{2} \mathrm{O}(l) \quad \Delta H=-2816 \mathrm{kJ}\) The metabolism of glucose gives the same products, although the glucose reacts with oxygen in a series of steps in the body. (a) How much heat in kilojoules can be produced by the metabolism of \(1.0 \mathrm{g}\) of glucose? (b) How many Calories can be produced by the metabolism of \(1.0 \mathrm{g}\) of glucose?
A 45-g aluminum spoon (specific heat 0.88 J/g ^ C) at 24 ^ C is placed in 180 mL (180 g) of coffee at 85 ^ C and the temperature of the two become equal. (a) What is the final temperature when the two become equal? Assume that coffee has the same specific heat as water. (b) The first time a student solved this problem she got an answer of \(88^{\circ} \mathrm{C}\). Explain why this is clearly an incorrect answer.
A 0.500-g sample of KCl is added to 50.0 g of water in a calorimeter (Figure 9.12). If the temperature decreases by \(1.05^{\circ} \mathrm{C},\) what is the approximate amount of heat involved in the dissolution of the \(\mathrm{KCl}\), assuming the specific heat of the resulting solution is \(4.18 \mathrm{J} / \mathrm{g}^{\circ} \mathrm{C}\) ? Is the reaction exothermic or endothermic?
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