Chapter 13: Problem 28
Write the expression of the reaction quotient for the ionization of HOCN in water.
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Chapter 13: Problem 28
Write the expression of the reaction quotient for the ionization of HOCN in water.
These are the key concepts you need to understand to accurately answer the question.
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Write the mathematical expression for the reaction quotient, \(Q_{c}\), for each of the following reactions: (a) \(\mathrm{N}_{2}(g)+3 \mathrm{H}_{2}(g) \rightleftharpoons 2 \mathrm{NH}_{3}(g)\) (b) \(4 \mathrm{NH}_{3}(g)+5 \mathrm{O}_{2}(g) \rightleftharpoons 4 \mathrm{NO}(g)+6 \mathrm{H}_{2} \mathrm{O}(g)\) (c) \(\mathrm{N}_{2} \mathrm{O}_{4}(g)=2 \mathrm{NO}_{2}(g)\) (d) \(\mathrm{CO}_{2}(g)+\mathrm{H}_{2}(g) \rightleftharpoons \mathrm{CO}(g)+\mathrm{H}_{2} \mathrm{O}(g)\) (e) \(\mathrm{NH}_{4} \mathrm{Cl}(s)=\mathrm{NH}_{3}(g)+\mathrm{HCl}(g)\) (f) \(2 \mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}(s) \rightleftharpoons 2 \mathrm{PbO}(s)+4 \mathrm{NO}_{2}(g)+\mathrm{O}_{2}(g)\) (g) \(2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g)=2 \mathrm{H}_{2} \mathrm{O}(l)\) (h) \(S_{8}(g) \rightleftharpoons 8 S(g)\)
Suggest four ways in which the concentration of hydrazine, \(\mathrm{N}_{2} \mathrm{H}_{4}\), could be increased in an equilibrium described by the following equation: \(\mathrm{N}_{2}(g)+2 \mathrm{H}_{2}(g) \rightleftharpoons \mathrm{N}_{2} \mathrm{H}_{4}(g) \quad \Delta H=95 \mathrm{kJ}\)
How will an increase in temperature affect each of the following equilibria? How will a decrease in the volume of the reaction vessel affect each? (a) \(2 \mathrm{H}_{2} \mathrm{O}(g) \rightleftharpoons 2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) \quad \Delta H=484 \mathrm{kJ}\) (b) \(\mathrm{N}_{2}(g)+3 \mathrm{H}_{2}(g) \rightleftharpoons 2 \mathrm{NH}_{3}(g) \quad \Delta H=-92.2 \mathrm{kJ}\) (c) \(2 \operatorname{Br}(g) \rightleftharpoons \operatorname{Br}_{2}(g) \quad \Delta H=-224 \mathrm{kJ}\) (d) \(\mathrm{H}_{2}(g)+\mathrm{I}_{2}(s) \rightleftharpoons 2 \mathrm{HI}(g) \quad \Delta H=53 \mathrm{kJ}\)
Show that the complete chemical equation, the total ionic equation, and the net ionic equation for the reaction represented by the equation \(\mathrm{KI}(a q)+\mathrm{I}_{2}(a q) \rightleftharpoons \mathrm{KI}_{3}(a q)\) give the same expression for the reaction quotient. \(\mathrm{KI}_{3}\) is composed of the ions \(K^{+}\) and \(I_{3}^{-}\)
What property of a reaction can we use to predict the effect of a change in temperature on the value of an equilibrium constant?
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