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For each question below, set up an amounts table that lists the initial amount or amounts of reactants, the changes in amounts of reactants and products, and the amounts of reactants and products after reaction (see page 159 and Example \(4 . \overline{1}\) ). The metals industry was a major source of air pollution years ago. One common process involved "roasting" metal sulfides in the air: $$ 2 \mathrm{PbS}(\mathrm{s})+3 \mathrm{O}_{2}(\mathrm{g}) \rightarrow 2 \mathrm{PbO}(\mathrm{s})+2 \mathrm{SO}_{2}(\mathrm{g}) $$ If 2.50 mol of PbS is heated in air, what amount of \(\mathrm{O}_{2}\) is required for complete reaction? What amounts of PbO and \(\mathrm{SO}_{2}\) are expected?

Short Answer

Expert verified
3.75 moles of Oâ‚‚ are required; 2.50 moles of PbO and 2.50 moles of SOâ‚‚ are produced.

Step by step solution

01

Understand the Reaction

The balanced chemical equation is \(2 \text{PbS}(\text{s}) + 3 \text{O}_2(\text{g}) \rightarrow 2 \text{PbO}(\text{s}) + 2 \text{SO}_2(\text{g})\). This equation tells us the stoichiometric ratios of reactants to products.
02

Set Up the Initial Amounts Table

From the problem, we start with 2.50 moles of PbS. Initially, assume zero moles of PbO and SO_2, as they are products generated during the reaction. O_2 is in excess, but its initial amount is unknown.
03

Calculate Required Amounts of Oâ‚‚ for Reaction

The balanced reaction shows 2 moles of PbS react with 3 moles of Oâ‚‚. Thus, the ratio is \(\frac{3}{2}\) moles of Oâ‚‚ required per mole of PbS. Calculating for 2.50 moles of PbS: \(2.50 \text{ mol PbS} \times \frac{3 \text{ mol O}_2}{2 \text{ mol PbS}} = 3.75 \text{ mol O}_2\). So, 3.75 moles of Oâ‚‚ are required for complete reaction.
04

Calculate Amounts of PbO and SOâ‚‚ Formed

For the balanced equation \(2 \text{PbS} \rightarrow 2 \text{PbO}\), 1 mole of PbS produces 1 mole of PbO. Thus, 2.50 moles of PbS will produce 2.50 moles of PbO.Similarly, the equation shows \(2 \text{PbS} \rightarrow 2 \text{SO}_2\), so 2.50 moles of PbS will yield 2.50 moles of SOâ‚‚.
05

Summarize the Amounts After Reaction

After the complete reaction: - PbS: 0 moles (all consumed) - Oâ‚‚: Not completely consumed, excess is remaining - PbO: 2.50 moles - SOâ‚‚: 2.50 moles

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Equations
In chemical reactions, chemical equations are used to represent the transformation of reactants into products. A balanced chemical equation is essential because it provides the exact stoichiometric relationship between the different substances involved. This relationship tells us how many molecules or moles of each reactant and product are involved. For example, in the equation \(2 \text{PbS}(\text{s}) + 3 \text{O}_2(\text{g}) \rightarrow 2 \text{PbO}(\text{s}) + 2 \text{SO}_2(\text{g})\), the coefficients indicate that two moles of lead sulfide (PbS) react with three moles of oxygen (Oâ‚‚) to produce two moles of lead oxide (PbO) and two moles of sulfur dioxide (SOâ‚‚). This balanced equation helps us understand the proportionate consumption and production of each species during the reaction.
In practice, writing and balancing chemical equations involves making sure the number of atoms for each element is the same on both sides of the equation. This ensures mass is conserved in the reaction, as no atoms are lost or gained, just rearranged. Understanding chemical equations is crucial for performing further stoichiometric calculations, like determining the amounts of reactants needed or products formed.
Mole Calculations
Mole calculations are a fundamental part of stoichiometry, allowing chemists to quantify the amount of a substance involved in a chemical reaction. The mole is a unit in chemistry that measures the amount of a substance. One mole represents approximately \(6.022 \times 10^{23}\) particles (Avogadro's number), making it a bridge between the microscopic world of atoms and the macroscopic amounts of material we handle in the lab.
In the given reaction, we determine the moles of each substance using stoichiometric coefficients. For instance, starting with 2.50 moles of PbS, we used the coefficients from the balanced equation to find the needed moles of Oâ‚‚. The ratio, \(\frac{3}{2}\), means for every 2 moles of PbS, we need 3 moles of Oâ‚‚. Therefore, if we have 2.50 moles of PbS, we calculate the moles of Oâ‚‚ required as follows: \[2.50 \text{ mol PbS} \times \frac{3 \text{ mol O}_2}{2 \text{ mol PbS}} = 3.75 \text{ mol O}_2\]. These calculations are essential for not only predicting amounts but also for assessing reaction efficiencies and planning experiments accordingly.
Reaction Stoichiometry
Reaction stoichiometry involves the quantitative relationship between reactants and products in a chemical reaction. This concept helps us understand how much of each reactant is needed or how much product we can expect to form when a reaction goes to completion. By using the coefficients from a balanced chemical equation, we can determine these quantities.
In this exercise, reaction stoichiometry tells us that 2 moles of PbS transform into 2 moles of PbO and 2 moles of SOâ‚‚. Hence, starting with 2.50 moles of PbS, the stoichiometry directly informs us that 2.50 moles of PbO and 2.50 moles of SOâ‚‚ are produced. Any leftover oxygen is considered excess because our calculations are based solely on the limiting reactant, PbS in this case.
  • Stoichiometric ratios are derived from balancing chemical equations.
  • This ensures each element is accounted for according to its molecular composition before and after the reaction.
  • The stoichiometric method is essential for efficiently designing chemical processes reacting fully.
Recognizing and handling these relationships allow chemists to predictively control the results of reactions—an invaluable skill in both research and industrial applications.

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