In some laboratory analyses, the preferred technique is to dissolve a sample
in an excess of acid or base and then "back-titrate" the excess with a
standard base or acid. This technique is used to assess the purity of a sample
of \(\left(\mathrm{NH}_{4}\right)_{2} \mathrm{SO}_{4}\). Suppose you dissolve
a 0.475 -g sample of impure \(\left(\mathrm{NH}_{4}\right)_{2} \mathrm{SO}_{4}\)
in aqueous \(\mathrm{KOH}\)
\(\left(\mathrm{NH}_{4}\right)_{2} \mathrm{SO}_{4}(\mathrm{aq})+2
\mathrm{KOH}(\mathrm{aq}) \rightarrow\)
$$
2 \mathrm{NH}_{3}(\mathrm{aq})+\mathrm{K}_{2} \mathrm{SO}_{4}(\mathrm{aq})+2
\mathrm{H}_{2} \mathrm{O}(\ell)
$$
The NH ated in the reaction is distilled from the solution into a flask
containing \(50.0 \mathrm{mL}\) of \(0.100 \mathrm{M}\) HCl. The ammonia reacts
with the acid to produce \(\mathrm{NH}_{4} \mathrm{Cl},\) but not all of the
\(\mathrm{HCl}\) is used in this reaction. The amount of excess acid is
determined by titrating the solution with standardized NaOH. This titration
consumes \(11.1 \mathrm{mL}\) of \(0.121 \mathrm{M} \mathrm{NaOH}\). What is the
weight percent of \(\left(\mathrm{NH}_{4}\right)_{2} \mathrm{SO}_{4}\) in the
\(0.475-\mathrm{g}\) sample?