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The chemistry of gallium: (a) Gallium hydroxide, like aluminum hydroxide, is amphoteric. Write a balanced equation to show how this hydroxide can dissolve in both HCl (aq) and \(\mathrm{NaOH}(\mathrm{aq})\) (b) Gallium ion in water, \(\mathrm{Ga}^{3+}(\mathrm{aq}),\) has a \(K_{\mathrm{a}}\) value of \(1.2 \times 10^{-3} .\) Is this ion a stronger or a weaker acid than \(\mathrm{Al}^{3+}(\mathrm{aq}) ?\)

Short Answer

Expert verified
(a) \( \text{Ga(OH)}_3 + 3\text{HCl} \rightarrow \text{GaCl}_3 + 3\text{H}_2\text{O} \) and \( \text{Ga(OH)}_3 + 3\text{NaOH} \rightarrow \text{Na}_3\text{GaO}_3 + 3\text{H}_2\text{O} \); (b) Ga\(^{3+}\) is a stronger acid than Al\(^{3+}\).

Step by step solution

01

Writing the Balanced Equation for Reaction with HCl

Gallium hydroxide \( \text{Ga(OH)}_3 \) reacts with hydrochloric acid \( \text{HCl (aq)} \) to form gallium chloride \( \text{GaCl}_3 \) and water. The balanced equation for this reaction is: \[ \text{Ga(OH)}_3 + 3\text{HCl} \rightarrow \text{GaCl}_3 + 3\text{H}_2\text{O} \] This shows the amphoteric nature of gallium hydroxide reacting as a base.
02

Writing the Balanced Equation for Reaction with NaOH

Gallium hydroxide \( \text{Ga(OH)}_3 \) can also react with sodium hydroxide \( \text{NaOH (aq)} \) to form sodium gallate \(\text{Na}_3\text{GaO}_3\) and water. The balanced equation is: \[ \text{Ga(OH)}_3 + 3\text{NaOH} \rightarrow \text{Na}_3\text{GaO}_3 + 3\text{H}_2\text{O} \] This reaction illustrates gallium hydroxide acting as an acid.
03

Comparing Acid Strengths

The strength of an acid is measured by its ionization constant \( K_a \). For \( \text{Ga}^{3+}(aq) \), the \( K_a \) is \( 1.2 \times 10^{-3} \). For \( \text{Al}^{3+}(aq) \), \( K_a \) is typically around \( 10^{-5} \). A larger \( K_a \) value indicates a stronger acid, thus \( \text{Ga}^{3+} \) is a stronger acid than \( \text{Al}^{3+} \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Amphoteric Compounds
Amphoteric compounds are fascinating in the chemistry world because they can react with both acids and bases. This ability comes from the presence of both acidic and basic properties within the same substance. A great example of an amphoteric compound is gallium hydroxide, \(\text{Ga(OH)}_3\), which behaves like aluminum hydroxide in this regard.
  • When reacting with an acid, such as hydrochloric acid \( \text{HCl} \(\mathrm{aq}\)\), gallium hydroxide acts as a base.
  • The reaction with HCl forms gallium chloride \( \text{GaCl}_3 \) and water. The balanced equation is: \\[ \text{Ga(OH)}_3 + 3\text{HCl} \rightarrow \text{GaCl}_3 + 3\text{H}_2\text{O} \]
  • Conversely, when it's treated with a strong base like sodium hydroxide \( \text{NaOH (aq)} \), it acts as an acid.
  • This forms sodium gallate \( \text{Na}_3\text{GaO}_3 \) and water, shown in this balanced equation: \\[ \text{Ga(OH)}_3 + 3\text{NaOH} \rightarrow \text{Na}_3\text{GaO}_3 + 3\text{H}_2\text{O} \]
This dual nature of being able to react with both acids and bases makes amphoterism an essential concept, revealing the versatile chemistry of these compounds.
Acid Strength Comparison
Understanding acid strength requires examining the ionization constant, or \( K_a\), which tells us how well an acid can give off hydrogen ions. The larger the \( K_a\), the stronger the acid.Gallium ions \( \text{Ga}^{3+}(\mathrm{aq})\) in solution have a \( K_a\) of \( 1.2 \times 10^{-3}\), which is significantly larger than that of aluminum ions, \( \text{Al}^{3+}(\mathrm{aq})\), with a \( K_a\) around \( 10^{-5}\). This means:
  • Gallium ions are stronger acids compared to aluminum ions.
  • This difference is due to the more significant tendency of gallium ions to release hydrogen ions in solution.
In simple terms, a stronger acid like \( \text{Ga}^{3+}\) will dissociate more in water, making it more reactive and suggesting a more substantial ability to interact with other substances through proton donation. This knowledge helps understand reactions in solutions, industrial processes, or biological systems where different acid strengths play a role.
Chemical Reaction Equations
Chemical reactions can be thoroughly understood through balanced equations, which show the reactants and products involved. For instance, as seen in amphoteric compounds, formulations of gallium hydroxide reactions highlight these crucial details:
  • Reaction with hydrochloric acid: This equation \ \[ \text{Ga(OH)}_3 + 3\text{HCl} \rightarrow \text{GaCl}_3 + 3\text{H}_2\text{O} \] is balanced, showing each atom's count is the same on both sides, maintaining the law of conservation of mass.
  • Reaction with sodium hydroxide: Similarly, the reaction \ \[ \text{Ga(OH)}_3 + 3\text{NaOH} \rightarrow \text{Na}_3\text{GaO}_3 + 3\text{H}_2\text{O} \] gives a full picture of the transformation occurring on a molecular level.
Balancing equations is essential, ensuring that chemical reactions reflect the reality of conservation laws. This skill is crucial for anyone studying chemistry, providing insights into not only qualitative but quantitative aspects of chemical reactions. Understanding this helps predict outcomes in labs, anticipate product formations, and maintain safety in chemical handling.

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Most popular questions from this chapter

Select one of the alkali metals, and write a balanced chemical equation for its reaction with chlorine. Is the reaction likely to be exothermic or endothermic? Is the product ionic or molecular?

Halogens form polyhalide ions. Sketch Lewis electron dot structures and molecular structures for the following ions: (a) \(\mathrm{I}_{3}^{-}\) (b) \(\mathrm{BrCl}_{2}^{-}\) (c) \(\mathrm{ClF}_{2}^{+}\) (d) An iodide ion and two iodine molecules form the \(\mathrm{I}_{5}^{-}\) ion. Here, the ion has five I atoms in a row, but the ion is not linear. Draw the Lewis dot structure for the ion, and propose a structure for the ion.

One material needed to make silicones is dichlorodimethylsilane, \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{SiCl}_{2} .\) It is made by treating silicon powder at about \(300^{\circ} \mathrm{C}\) with \(\mathrm{CH}_{3} \mathrm{Cl}\) in the presence of a copper-containing catalyst. (a) Write a balanced equation for the reaction. (b) Assume you carry out the reaction on a small scale with \(2.65 \mathrm{g}\) of silicon. To measure the \(\mathrm{CH}_{3} \mathrm{Cl}\) gas, you fill a \(5.60-\mathrm{L}\) flask at \(24.5^{\circ} \mathrm{C} .\) What pressure of \(\mathrm{CH}_{3} \mathrm{Cl}\) gas must you have in the flask to have the stoichiometrically correct amount of the compound? (c) What mass of \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{SiCl}_{2}\) can be produced from \(2.65 \mathrm{g}\) of \(\mathrm{Si}\) and excess \(\mathrm{CH}_{3} \mathrm{Cl} ?\)

Select one of the alkaline earth metals and write a balanced chemical equation for its reaction with oxygen. Is the reaction likely to be exothermic or endothermic? Is the product ionic or molecular?

(a) Magnesium is obtained from sea water. If the concentration of \(\mathrm{Mg}^{2+}\) in sea water is \(0.050 \mathrm{M},\) what volume of sea water (in liters) must be treated to obtain \(1.00 \mathrm{kg}\) of magnesium metal? What mass of lime (CaO; in kilograms) must be used to precipitate the magnesium in this volume of sea water? (b) When \(1.2 \times 10^{3} \mathrm{kg}\) of molten \(\mathrm{MgCl}_{2}\) is electrolyzed to produce magnesium, what mass (in kilograms) of metal is produced at the cathode? What is produced at the anode? What is the mass of this product? What is the total number of Faradays of electricity used in the process? (c) One industrial process has an energy consumption of \(18.5 \mathrm{kWh} / \mathrm{kg}\) of \(\mathrm{Mg} .\) How many joules are required per mole ( \(1 \mathrm{kWh}=1\) kilowatt-hour \(=\) \(\left.3.6 \times 10^{6} \mathrm{J}\right) ?\) How does this energy compare with the energy of the following process? $$\mathrm{MgCl}_{2}(\mathrm{s}) \rightarrow \mathrm{Mg}(\mathrm{s})+\mathrm{Cl}_{2}(\mathrm{g})$$

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