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Classify each of the following as exothermic or endothermic: a. \(\mathrm{C}_{3} \mathrm{H}_{8}(g)+5 \mathrm{O}_{2}(g) \stackrel{\Delta}{\longrightarrow} 3 \mathrm{C} \mathrm{O}_{2}(g)+4 \mathrm{H}_{2} \mathrm{O}(g)+2220 \mathrm{~kJ}\) b. \(2 \mathrm{Na}(s)+\mathrm{Cl}_{2}(g) \longrightarrow 2 \mathrm{NaCl}(s)+819 \mathrm{~kJ}\) c. \(\mathrm{PCl}_{5}(g)+67 \mathrm{~kJ} \longrightarrow \mathrm{PCl}_{3}(g)+\mathrm{Cl}_{2}(g)\)

Short Answer

Expert verified
a. Exothermic, b. Exothermic, c. Endothermic

Step by step solution

01

Identify Heat Term in Reaction (a)

Observe the reaction \(\mathrm{C}_{3} \mathrm{H}_{8}(g)+5 \mathrm{O}_{2}(g) \stackrel{\Delta}{\longrightarrow} 3 \mathrm{C} \mathrm{O}_{2}(g)+4 \mathrm{H}_{2} \mathrm{O}(g)+2220 \mathrm{~kJ}\). The heat term (2220 kJ) is on the product side, meaning the reaction releases heat. Classify this reaction as exothermic.
02

Identify Heat Term in Reaction (b)

Observe the reaction \(2 \mathrm{Na}(s)+\mathrm{Cl}_{2}(g) \longrightarrow 2 \mathrm{NaCl}(s)+819 \mathrm{~kJ}\). The heat term (819 kJ) is on the product side, meaning the reaction releases heat. Classify this reaction as exothermic.
03

Identify Heat Term in Reaction (c)

Observe the reaction \(\mathrm{PCl}_{5}(g)+67 \mathrm{~kJ} \longrightarrow \mathrm{PCl}_{3}(g)+\mathrm{Cl}_{2}(g)\). The heat term (67 kJ) is on the reactant side, meaning the reaction absorbs heat. Classify this reaction as endothermic.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Exothermic Reactions
Exothermic reactions are reactions that release heat energy to their surroundings. You can identify an exothermic reaction by looking at its chemical equation and noting where the heat term is located. If the heat is listed among the products, then the reaction is exothermic.

For example, in the reaction:
\(\text{C}_{3} \text{H}_{8}(g) + 5 \text{O}_{2}(g) \rightarrow 3 \text{CO}_{2}(g) + 4 \text{H}_{2} \text{O}(g) + 2220 \text{ kJ}\)
The 2220 kJ of heat is on the product side, meaning the reaction releases heat. This is an exothermic reaction.

Similarly, in the reaction:
\(\text{2 Na}(s) + \text{Cl}_{2}(g) \rightarrow 2 \text{NaCl}(s) + 819 \text{ kJ}\)
The 819 kJ of heat is on the product side, indicating that the reaction also releases heat, and is therefore exothermic.
Endothermic Reactions
Endothermic reactions are the opposite of exothermic reactions. They absorb heat from their surroundings. You can identify an endothermic reaction by finding the heat term among the reactants of the chemical equation.

For instance, in the reaction:
\(\text{PCl}_{5}(g) + 67 \text{ kJ} \rightarrow \text{PCl}_{3}(g) + \text{Cl}_{2}(g)\)
The 67 kJ of energy is on the reactant side, meaning that the reaction absorbs heat. This is an endothermic reaction.

In summary, if you see that heat is required for the reaction to occur and it appears on the reactants' side, you are dealing with an endothermic process.
Heat in Chemical Reactions
Heat plays a crucial role in chemical reactions. Whether a reaction releases or absorbs heat can help understand the nature and behavior of the reaction.

In exothermic reactions:
  • Heat is released to the surroundings.
  • The temperature of the surroundings increases.
  • Common examples include combustion reactions and many oxidation processes.

In endothermic reactions:
  • Heat is absorbed from the surroundings.
  • The temperature of the surroundings decreases.
  • Common examples include photosynthesis and the melting of ice.

Understanding the heat dynamics in these reactions is essential for applications in everyday life, such as chemical manufacturing, energy production, and biological processes.

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Most popular questions from this chapter

At a winery, glucose \(\left(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\right)\) in grapes undergoes fermentation to produce ethanol \(\left(\mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O}\right)\) and carbon dioxide. (7.8) $$ \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(a q) \longrightarrow 2 \mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O}(a q)+2 \mathrm{CO}_{2}(g) $$ a. How many grams of glucose are required to form \(124 \mathrm{~g}\) of ethanol? b. How many grams of ethanol would be formed from the reaction of \(0.240 \mathrm{~kg}\) of glucose?

Calculate each of the following: a. number of \(\mathrm{O}\) atoms in 0.0180 moles of dry ice b. number of \(\mathrm{K}\) atoms in \(14.5 \mathrm{moles}\) of \(\mathrm{K}_{2} \mathrm{CO}_{3}\) c. moles of \(\mathrm{O}\) in \(8.60 \times 10^{21}\) molecules of \(\mathrm{H}_{2} \mathrm{SO}_{4}\) d. moles of \(\mathrm{C}_{6} \mathrm{H}_{6}\) in \(6.90 \times 10^{23}\) molecules of \(\mathrm{C}_{6} \mathrm{H}_{6}\)

When nitrogen dioxide \(\left(\mathrm{NO}_{2}\right)\) gas from car exhaust combines with water vapor in the air, it forms aqueous nitric acid (HNO \(_{3}\) ), which causes acid rain, and nitrogen oxide gas. (7.4,7.7,7.8) a. Write the balanced chemical equation. b. How many moles of each product are produced from 0.250 mole of \(\mathrm{H}_{2} \mathrm{O} ?\) c. How many grams of \(\mathrm{HNO}_{3}\) are produced when \(60.0 \mathrm{~g}\) of \(\mathrm{NO}_{2}\) completely reacts? d. How many grams of \(\mathrm{NO}_{2}\) are needed to form \(75.0 \mathrm{~g}\) of \(\mathrm{HNO}_{3}\) ?

Classify each of the following as exothermic or endothermic: a. The energy level of the products is lower than that of the reactants. b. In the body, the synthesis of proteins requires energy. c. A reaction absorbs \(125 \mathrm{~kJ}\).

During heavy exercise and workouts, lactic acid, \(\mathrm{C}_{3} \mathrm{H}_{6} \mathrm{O}_{3}\), accumulates in the muscles where it can cause pain and soreness. (7.1,7.2) a. How many molecules are in 0.500 mole of lactic acid? b. How many atoms of \(\mathrm{C}\) are in 1.50 moles of lactic acid? c. How many moles of lactic acid contain \(4.5 \times 10^{24}\) atoms of \(\mathrm{O} ?\) d. What is the molar mass of lactic acid?

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