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Acetylene gas, \(\mathrm{C}_{2} \mathrm{H}_{2}\), used in welders' torches, releases \(1300 \mathrm{~kJ}\) of heat when 1 mole of \(\mathrm{C}_{2} \mathrm{H}_{2}\) undergoes combustion. \((7.4,7.7,\) 7.8,7.9) a. Write a balanced equation for the reaction, including the heat of reaction. b. Is the reaction endothermic or exothermic? c. How many moles of \(\mathrm{H}_{2} \mathrm{O}\) are produced when 2.00 moles of \(\mathrm{O}_{2}\) reacts? d. How many grams of \(\mathrm{O}_{2}\) are needed to react with \(9.80 \mathrm{~g}\) of \(\mathrm{C}_{2} \mathrm{H}_{2} ?\)

Short Answer

Expert verified
(a) 2 \text{C}_2\text{H}_2 + 5 \text{O}_2 \rightarrow 4 \text{CO}_2 + 2 \text{H}_2\text{O} + 2600 kJ, (b) exothermic, (c) 0.8 moles of \text{H}_2\text{O}, (d) 30.08 grams of \text{O}_2.

Step by step solution

01

Write the balanced equation for the combustion of acetylene

Acetylene (\text{C}_2 \text{H}_2) combusts in the presence of oxygen (\text{O}_2) to form carbon dioxide (\text{CO}_2) and water (\text{H}_2 \text{O}). The balanced chemical equation for this reaction is: \[ \text{2 C}_2\text{H}_2 + \text{5 O}_2 \rightarrow \text{4 CO}_2 + \text{2 H}_2\text{O} \text{ with the release of 2600 kJ of heat} \]. Since 1300 kJ of heat is released per mole of \text{C}_2\text{H}_2}, for 2 moles, it would be 2600 kJ.
02

Determine if the reaction is endothermic or exothermic

This reaction releases heat energy, which means it is exothermic.
03

Calculate the moles of \text{H}_2\text{O} produced when 2.00 moles of \text{O}_2 reacts

From the balanced equation, \text{5 O}_2 produces \text{2 H}_2\text{O}. Thus, \( \frac{2 \text{ moles } \text{H}_2\text{O}}{5 \text{ moles } \text{O}_2} \times 2.00 \text{ moles } \text{O}_2 = 0.8 \text{ moles } \text{H}_2\text{O} \)
04

Calculate the grams of \text{O}_2 needed to react with 9.80 grams of \text{C}_2\text{H}_2}

First, calculate the moles of \text{C}_2\text{H}_2 using its molar mass (26.04 g/mol): \( \frac{9.80 \text{ g }}{26.04 \text{ g/mol }} = 0.376 \text{ moles of } \text{C}_2\text{H}_2 \). From the balanced equation, 2 moles of \text{C}_2\text{H}_2 react with 5 moles of \text{O}_2. Hence, \( \frac{5 \text{ moles } \text{O}_2}{2 \text{ moles } \text{C}_2\text{H}_2} \times 0.376 \text{ moles } \text{C}_2\text{H}_2 = 0.94 \text{ moles } \text{O}_2 \). Finally, calculate the mass of \text{O}_2 needed using its molar mass (32.00 g/mol): \( 0.94 \text{ moles } \text{O}_2 \times 32.00 \text{ g/mol } = 30.08 \text{ grams } \text{O}_2 \)

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Balanced Chemical Equation
In a chemical reaction, it's essential to maintain the same number of each type of atom on both sides of the equation. This is done by balancing the chemical equation. For the combustion of acetylene (Câ‚‚Hâ‚‚), the balanced equation is:
\[2 \text{C}_2\text{H}_2 + 5 \text{O}_2 \rightarrow 4 \text{CO}_2 + 2 \text{H}_2\text{O} \text{ with the release of 2600 kJ of heat}.\]
Each side of the equation has the same number of carbon, hydrogen, and oxygen atoms:
  • 4 Carbon atoms (2 molecules of Câ‚‚Hâ‚‚) → 4 Carbon atoms (4 molecules of COâ‚‚)
  • 4 Hydrogen atoms (2 molecules of Câ‚‚Hâ‚‚) → 4 Hydrogen atoms (2 molecules of Hâ‚‚O)
  • 10 Oxygen atoms (5 molecules of Oâ‚‚) → 10 Oxygen atoms (4 molecules of COâ‚‚ and 2 molecules of Hâ‚‚O)
This keeps the law of conservation of mass intact.
Exothermic Reaction
In an exothermic reaction, energy is released into the surroundings, usually in the form of heat. The combustion of acetylene (\text{C}_2\text{H}_2}) is an exothermic reaction because it releases 1300 kJ of heat per mole of acetylene. Since there are 2 moles of acetylene in the balanced equation, it releases 2600 kJ of heat:
\[2 \text{C}_2\text{H}_2 + 5 \text{O}_2 \rightarrow 4 \text{CO}_2 + 2 \text{H}_2\text{O} \text{ with the release of 2600 kJ of heat}.\]
Exothermic reactions are characterized by the release of heat, making the surrounding environment warmer. This type of reaction is the opposite of an endothermic reaction, which absorbs heat from the surroundings.
Stoichiometry
Stoichiometry is the branch of chemistry that deals with the quantitative relationships between the reactants and products in a chemical reaction. It allows us to calculate the amount of products formed in a reaction based on the quantities of reactants used.
In the acetylene combustion problem, we use stoichiometry to calculate the moles of water produced and the grams of oxygen needed. From the balanced equation, we see that 5 moles of Oâ‚‚ react with 2 moles of Câ‚‚Hâ‚‚ to produce 2 moles of Hâ‚‚O.
To find how many moles of Hâ‚‚O are produced with 2 moles of Oâ‚‚: \[ \frac{2 \text{ moles } \text{H}_2\text{O}}{5 \text{ moles } \text{O}_2} \times 2.00 \text{ moles } \text{O}_2 = 0.8 \text{ moles } \text{H}_2\text{O} \] For the grams of Oâ‚‚ needed to react with 9.80 grams of Câ‚‚Hâ‚‚:
  • Calculate moles of Câ‚‚Hâ‚‚: \[ \frac{9.80 \text{ g}}{26.04 \text{ g/mol}} = 0.376 \text{ moles of C}_2\text{H}_2 \]
  • Moles of Oâ‚‚ needed: \[ \frac{5 \text{ moles } \text{O}_2}{2 \text{ moles } \text{C}_2\text{H}_2} \times 0.376 \text{ moles } \text{C}_2\text{H}_2 = 0.94 \text{ moles } \text{O}_2 \]
  • Grams of Oâ‚‚ needed: \[ 0.94 \text{ moles } \text{O}_2 \times 32.00 \text{ g/mol} = 30.08 \text{ grams } \text{O}_2 \]
Molar Mass
Molar mass is the mass of one mole of a substance, usually expressed in grams per mole (g/mol). It is calculated by adding the atomic masses of all the atoms in a molecule. For instance, the molar mass of acetylene (Câ‚‚Hâ‚‚) is calculated as follows:
  • Carbon (C) has an atomic mass of approximately 12.01 g/mol.
  • Hydrogen (H) has an atomic mass of approximately 1.01 g/mol.
Each molecule of acetylene (Câ‚‚Hâ‚‚) has 2 carbon atoms and 2 hydrogen atoms:
\[ \text{Molar Mass of C}_2\text{H}_2 = 2 \times 12.01 \text{ g/mol} + 2 \times 1.01 \text{ g/mol} = 26.04 \text{ g/mol}. \] We use molar mass to convert between grams and moles. For example, to find the moles of acetylene in 9.80 grams:
\[ \frac{9.80 \text{ g}}{26.04 \text{ g/mol}} = 0.376 \text{ moles of C}_2\text{H}_2 \] Knowing molar mass helps in various calculations, letting us know the amount of substance present.

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Most popular questions from this chapter

At a winery, glucose \(\left(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\right)\) in grapes undergoes fermentation to produce ethanol \(\left(\mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O}\right)\) and carbon dioxide. (7.8) $$ \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(a q) \longrightarrow 2 \mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O}(a q)+2 \mathrm{CO}_{2}(g) $$ a. How many grams of glucose are required to form \(124 \mathrm{~g}\) of ethanol? b. How many grams of ethanol would be formed from the reaction of \(0.240 \mathrm{~kg}\) of glucose?

During heavy exercise and workouts, lactic acid, \(\mathrm{C}_{3} \mathrm{H}_{6} \mathrm{O}_{3}\), accumulates in the muscles where it can cause pain and soreness. (7.1,7.2) a. How many molecules are in 0.500 mole of lactic acid? b. How many atoms of \(\mathrm{C}\) are in 1.50 moles of lactic acid? c. How many moles of lactic acid contain \(4.5 \times 10^{24}\) atoms of \(\mathrm{O} ?\) d. What is the molar mass of lactic acid?

Naproxen, found in Aleve, is used to treat the pain and inflammation caused by arthritis. Naproxen has a formula of \(\mathrm{C}_{14} \mathrm{H}_{14} \mathrm{O}_{3}\). a. How many moles of \(\mathrm{C}\) are present in 2.30 moles of naproxen? b. How many moles of \(\mathrm{H}\) are present in 0.444 mole of naproxen? c. How many moles of \(\mathrm{O}\) are present in \(0.0765 \mathrm{~mole}\) of naproxen?

Nitrogen gas reacts with hydrogen gas to produce ammonia. $$ \mathrm{N}_{2}(g)+3 \mathrm{H}_{2}(g) \longrightarrow 2 \mathrm{NH}_{3}(g) $$ a. If you have \(3.64 \mathrm{~g}\) of \(\mathrm{H}_{2}\), how many grams of \(\mathrm{NH}_{3}\) can be produced? b. How many grams of \(\mathrm{H}_{2}\) are needed to react with \(2.80 \mathrm{~g}\) of \(\mathrm{N}_{2} ?\) c. How many grams of \(\mathrm{NH}_{3}\) can be produced from \(12.0 \mathrm{~g}\) of \(\mathrm{H}_{2} ?\)

Calculate the molar mass for each of the following: a. \(\mathrm{C}_{4} \mathrm{H}_{8} \mathrm{O}_{4}\) b. \(\mathrm{Ga}_{2}\left(\mathrm{CO}_{3}\right)_{3}\) c. \(\mathrm{KBrO}_{4}\)

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