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A buffer solution is made by dissolving \(\mathrm{HC}_{2} \mathrm{H}_{3} \mathrm{O}_{2}\) and \(\mathrm{NaC}_{2} \mathrm{H}_{3} \mathrm{O}_{2}\) in water. (10.8) a. Write an equation that shows how this buffer neutralizes added acid. b. Write an equation that shows how this buffer neutralizes added base.

Short Answer

Expert verified
a. \[\text{C}_{2} \text{H}_{3} \text{O}_{2}^{-} + \text{H}^{+} \rightarrow \text{HC}_{2} \text{H}_{3} \text{O}_{2}\] b. \[\text{HC}_{2} \text{H}_{3} \text{O}_{2} + \text{OH}^{-} \rightarrow \text{C}_{2} \text{H}_{3} \text{O}_{2}^{-} + \text{H}_{2} \text{O}\]

Step by step solution

01

Understanding the Components

Identify the components of the buffer solution. The buffer is made from acetic acid \(\text{HC}_{2} \text{H}_{3} \text{O}_{2}\) and sodium acetate \(\text{NaC}_{2} \text{H}_{3} \text{O}_{2}\).
02

Writing the Acid-Base Reaction for Added Acid

When an acid is added to the buffer, the acetate ion (\text{C}_{2} \text{H}_{3} \text{O}_{2}^{-}) will react with the added hydrogen ions (\text{H}^{+}). The equation is: \[\text{C}_{2} \text{H}_{3} \text{O}_{2}^{-} + \text{H}^{+} \rightarrow \text{HC}_{2} \text{H}_{3} \text{O}_{2}\]
03

Writing the Acid-Base Reaction for Added Base

When a base is added to the buffer, acetic acid (\text{HC}_{2} \text{H}_{3} \text{O}_{2}) will react with the added hydroxide ions (\text{OH}^{-}). The equation is: \[\text{HC}_{2} \text{H}_{3} \text{O}_{2} + \text{OH}^{-} \rightarrow \text{C}_{2} \text{H}_{3} \text{O}_{2}^{-} + \text{H}_{2} \text{O}\]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Acid-Base Reaction
An acid-base reaction involves the transfer of protons (H鈦) between reactants. Often, acids donate protons while bases accept them. In a buffer solution, there are two key reactions: one that neutralizes added acids and one that neutralizes added bases.
In our example, acetic acid (HC鈧侶鈧僌鈧) and sodium acetate (NaC鈧侶鈧僌鈧) create a buffer. When acid is added, the acetate ion (C鈧侶鈧僌鈧傗伝) reacts with the hydrogen ions (H鈦), neutralizing the acid. When a base is added, acetic acid (HC鈧侶鈧僌鈧) reacts with the hydroxide ions (OH鈦), neutralizing the base. This concept is crucial for understanding how buffer solutions maintain a relatively stable pH despite the addition of strong acids or bases.
Acetic Acid
Acetic acid (HC鈧侶鈧僌鈧) is an organic compound and a weak acid. It's commonly found in vinegar. The molecular formula is C鈧侶鈧凮鈧, but when it's in a buffer solution, it exists mainly in its ionic form. This weak acid partially dissociates in water, meaning it doesn't fully ionize. This partial dissociation is key to its role in a buffer solution. When a base such as OH鈦 is added to the solution, acetic acid reacts with it to form acetate ions (C鈧侶鈧僌鈧傗伝) and water (H鈧侽). This reaction helps to neutralize the added base, contributing to the maintenance of a stable pH in the buffer solution.
Sodium Acetate
Sodium acetate (NaC鈧侶鈧僌鈧) is a salt formed by the combination of sodium hydroxide (a strong base) and acetic acid (a weak acid). In a buffer solution, it dissociates completely in water to produce sodium ions (Na鈦) and acetate ions (C鈧侶鈧僌鈧傗伝). These acetate ions are crucial because they interact with hydrogen ions (H鈦) when an acid is introduced into the buffer solution. This interaction helps to neutralize the added acid, keeping the pH stable. In essence, sodium acetate provides the conjugate base (C鈧侶鈧僌鈧傗伝) that balances the acidic components of the buffer.
Neutralization
Neutralization is the process of counteracting an acid with a base, or vice versa. In the context of buffer solutions, this occurs when acetic acid neutralizes added bases, and acetate ions neutralize added acids. When an acid (like HCl) is introduced into the buffer, the acetate ion (C鈧侶鈧僌鈧傗伝) reacts with the hydrogen ions (H鈦) to create acetic acid (HC鈧侶鈧僌鈧). Conversely, when a base (like NaOH) is introduced, the acetic acid (HC鈧侶鈧僌鈧) reacts with hydroxide ions (OH鈦) to form water (H鈧侽) and acetate ions (C鈧侶鈧僌鈧傗伝). By continuously balancing these reactions, the buffer solution maintains a relatively stable pH, a critical function in many biological, chemical, and industrial processes.

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