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Complete the following table: $$ \begin{array}{|l|l|} \hline \text { Acid } & \text { Conjugate Base } \\ \hline \mathrm{H}_{2} \mathrm{O} & \\ \hline & \mathrm{CN}^{-} \\ \hline \mathrm{HNO}_{2} & \\ \hline & \mathrm{H}_{2} \mathrm{PO}_{4}^{-} \\ \hline \end{array} $$

Short Answer

Expert verified
H2O - OH-, HCN - CN-, HNO2 - NO2-, H3PO4 - H2PO4-

Step by step solution

01

Identify the Conjugate Base of H2O

The conjugate base of water (H2O) is obtained by removing one hydrogen ion (H+). This results in hydroxide ion (OH-). Hence, the conjugate base of H2O is OH-.
02

Identify the Acid for CN-

The conjugate acid of CN- is obtained by adding one hydrogen ion (H+) to it. This results in hydrogen cyanide (HCN). Hence, the acid that forms CN- as a conjugate base is HCN.
03

Identify the Conjugate Base of HNO2

The conjugate base of nitrous acid (HNO2) is obtained by removing one hydrogen ion (H+). This results in nitrite ion (NO2-). Hence, the conjugate base of HNO2 is NO2-.
04

Identify the Acid for H2PO4-

The conjugate acid of H2PO4- is obtained by adding one hydrogen ion (H+) to it. This results in phosphoric acid (H3PO4). Hence, the acid that forms H2PO4- as a conjugate base is H3PO4.
05

Complete the Table

Fill in the missing entries using the information obtained in the previous steps. The completed table is: | Acid | Conjugate Base ||--------|-----------------|| H2O | OH- || HCN | CN- || HNO2 | NO2- || H3PO4 | H2PO4- |

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Conjugate Acid-Base Pairs
In acid-base chemistry, acids and bases exist in pairs known as conjugate acid-base pairs. These pairs are related by the loss or gain of a hydrogen ion (H+). When an acid donates a hydrogen ion, it becomes its conjugate base. Conversely, when a base accepts a hydrogen ion, it becomes its conjugate acid.

For example:
  • Water (H鈧侽) acts as an acid when it donates a hydrogen ion to form its conjugate base, hydroxide ion (OH鈦).
  • Cyanide ion (CN鈦) acts as a base when it accepts a hydrogen ion to form its conjugate acid, hydrogen cyanide (HCN).
Understanding these pairs is essential for predicting the outcome of acid-base reactions.
Hydrogen Ion (H+)
The hydrogen ion, often represented as H鈦, plays a crucial role in acid-base reactions. It is essentially a proton, and its presence or absence determines whether a molecule behaves as an acid or a base.

When an acid dissociates in water, it releases hydrogen ions into the solution. These H鈦 ions can then be accepted by a base, which explains why acids are described as proton donors and bases as proton acceptors.

For instance:
  • H鈧侽 loses an H鈦 to become OH鈦, showing its role as an acid.
  • CN鈦 gains an H鈦 to become HCN, showing its role as a base.
This simple transfer of H鈦 is the basis for defining the properties of acids and bases.
Acid Dissociation
Acid dissociation refers to the process by which an acid releases a hydrogen ion (H鈦) when it dissolves in water. This is often represented by the equation:

HA <=> H鈦 + A鈦

Here, HA represents the acid and A鈦 is its conjugate base.

For example:
  • When HNO鈧 (nitrous acid) dissociates, it releases an H鈦, forming its conjugate base, NO鈧傗伝 (nitrite ion).
  • Similarly, water (H鈧侽) can dissociate to release an H鈦, forming OH鈦 (hydroxide ion).
  • Acid dissociation is a fundamental concept for understanding acid strength and the behavior of acids in different environments.

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    Most popular questions from this chapter

    Write a balanced equation for the neutralization of each of the following: a. \(\mathrm{H}_{2} \mathrm{SO}_{4}(a q)\) and \(\mathrm{NaOH}(a q)\) b. \(\mathrm{HCl}(a q)\) and \(\mathrm{Fe}(\mathrm{OH})_{3}(s)\) c. \(\mathrm{H}_{2} \mathrm{CO}_{3}(a q)\) and \(\mathrm{Mg}(\mathrm{OH})_{2}(s)\)

    State whether each of the following solutions is acidic, basic, or neutral: a. soda, \(\mathrm{pH} 3.22\) b. shampoo, \(\mathrm{pH} 5.7\) c. laundry detergent, \(\mathrm{pH} 9.4\) d. rain, \(\mathrm{pH} 5.83\) e. honey, \(\mathrm{pH} 3.9\) f. cheese, \(\mathrm{pH} 5.2\)

    Calculate the \(\mathrm{pH}\) of each solution given the following \(\left[\mathrm{H}_{3} \mathrm{O}^{+}\right]\) or \(\left[\mathrm{OH}^{-}\right]\) values: a. \(\left[\mathrm{H}_{3} \mathrm{O}^{+}\right]=1 \times 10^{-8} \mathrm{M}\) b. \(\left[\mathrm{H}_{3} \mathrm{O}^{+}\right]=5 \times 10^{-6} \mathrm{M}\) c. \(\left[\mathrm{OH}^{-}\right]=4 \times 10^{-2} \mathrm{M}\) d. \(\left[\mathrm{OH}^{-}\right]=8 \times 10^{-3} \mathrm{M}\) e. \(\left[\mathrm{H}_{3} \mathrm{O}^{+}\right]=4.7 \times 10^{-2} \mathrm{M}\) f. \(\left[\mathrm{OH}^{-}\right]=3.9 \times 10^{-6} \mathrm{M}\)

    Identify the Br酶nsted-Lowry acid-base pairs in each of the following equations: a. \(\mathrm{H}_{3} \mathrm{PO}_{4}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftarrows \mathrm{H}_{3} \mathrm{O}^{+}(a q)+\mathrm{H}_{2} \mathrm{PO}_{4}^{-}(a q)\) b. \(\mathrm{CO}_{3}{ }^{2-}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftarrows \mathrm{OH}^{-}(a q)+\mathrm{HCO}_{3}^{-}(a q)\) c. \(\mathrm{H}_{3} \mathrm{PO}_{4}(a q)+\mathrm{NH}_{3}(a q) \rightleftarrows \mathrm{NH}_{4}{ }^{+}(a q)+\mathrm{H}_{2} \mathrm{PO}_{4}^{-}(a q)\)

    Calculate the \(\left[\mathrm{OH}^{-}\right]\) of each aqueous solution with the following \(\left[\mathrm{H}_{3} \mathrm{O}^{+}\right]:\) a. coffee, \(1.0 \times 10^{-5} \mathrm{M}\) b. soap, \(1.0 \times 10^{-8} \mathrm{M}\) c. cleanser, \(5.0 \times 10^{-10} \mathrm{M}\) d. lemon juice, \(2.5 \times 10^{-2} \mathrm{M}\)

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