Chapter 9: Problem 48
The second-order diffraction \((n=2)\) for a gold crystal is at an angle of \(22.20^{\circ}\) for \(\mathrm{X}\) rays of \(154 \mathrm{pm}\). What is the spacing between these crystal planes?
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Chapter 9: Problem 48
The second-order diffraction \((n=2)\) for a gold crystal is at an angle of \(22.20^{\circ}\) for \(\mathrm{X}\) rays of \(154 \mathrm{pm}\). What is the spacing between these crystal planes?
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Which are stronger, intermolecular or intramolecular forces for a given molecule? What observation(s) have you made that support this? Explain.
General Zod has sold Lex Luthor what Zod claims to be a new copper-colored form of kryptonite, the only substance that can harm Superman. Lex, not believing in honor among thieves, decided to carry out some tests on the supposed kryptonite. From previous tests, Lex knew that kryptonite is a metal having a specific heat capacity of \(0.082 \mathrm{J} / \mathrm{g} \cdot^{\circ} \mathrm{C}\) and a density of \(9.2 \mathrm{g} / \mathrm{cm}^{3}.\) Lex Luthor's first experiment was an attempt to find the specific heat capacity of kryptonite. He dropped a \(10 \mathrm{g} \pm 3 \mathrm{g}\) sample of the metal into a boiling water bath at a temperature of \(100.0^{\circ} \mathrm{C} \pm 0.2^{\circ} \mathrm{C} .\) He waited until the metal had reached the bath temperature and then quickly transferred it to \(100 \mathrm{g} \pm 3 \mathrm{g}\) of water that was contained in a calorimeter at an initial temperature of \(25.0^{\circ} \mathrm{C} \pm 0.2^{\circ} \mathrm{C} .\) The final temperature of the metal and water was \(25.2^{\circ} \mathrm{C} .\) Based on these results, is it possible to distinguish between copper and kryptonite? Explain. When Lex found that his results from the first experiment were inconclusive, he decided to determine the density of the sample. He managed to steal a better balance and determined the mass of another portion of the purported kryptonite to be \(4 \mathrm{g} \pm 1\) g. He dropped this sample into water contained in a 25-mL graduated cylinder and found that it displaced a volume of \(0.42 \mathrm{mL} \pm 0.02 \mathrm{mL} .\) Is the metal copper or kryptonite? Explain. Lex was finally forced to determine the crystal structure of the metal General Zod had given him. He found that the cubic unit cell contained four atoms and had an edge length of \(600 . \mathrm{pm} .\) Explain how this information enabled Lex to identify the metal as copper or kryptonite. Will Lex be going after Superman with the kryptonite or seeking revenge on General Zod? What improvements could he have made in his experimental techniques to avoid performing the crystal structure determination?
The memory metal, nitinol, is an alloy of nickel and titanium. It is called a memory metal because after being deformed, a piece of nitinol wire will return to its original shape. The structure of nitinol consists of a simple cubic array of Ni atoms and an inner penetrating simple cubic array of Ti atoms. In the extended lattice, a Ti atom is found at the center of a cube of Ni atoms; the reverse is also true. a. Describe the unit cell for nitinol. b. What is the empirical formula of nitinol? c. What are the coordination numbers (number of nearest neighbors) of Ni and Ti in nitinol?
Predict which substance in each of the following pairs would have the greater intermolecular forces. a. \(\mathrm{CO}_{2}\) or \(\mathrm{OCS}\) b. \(\operatorname{SeO}_{2}\) or \(\mathrm{SO}_{2}\) \(\mathbf{c .} \cdot \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\) or \(\mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\) d. \(\mathrm{CH}_{3} \mathrm{CH}_{3}\) or \(\mathrm{H}_{2} \mathrm{CO}\) e. \(\mathrm{CH}_{3} \mathrm{OH}\) or \(\mathrm{H}_{2} \mathrm{CO}\)
Rationalize why chalk (calcium carbonate) has a higher melting point than motor oil (large compound made from carbon and hydrogen), which has a higher melting point than water and engages in relatively strong hydrogen bonding interactions.
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