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Identify the most important types of interparticle forces present in the solids of each of the following substances. a. \(\mathrm{BaSO}_{4}\) b. \(\mathrm{H}_{2} \mathrm{S}\) c. Xe d. \(C_{2} H_{6}\) $$\begin{array}{l} \text { e. } \mathrm{CsI} \\ \text { f. } \mathrm{P}_{4} \\ \text { g. } \mathrm{NH}_{3} \end{array}$$

Short Answer

Expert verified
a. Ionic bonds (Ba虏鈦 and SO鈧劼测伝) b. Dipole-dipole interactions (H2S) c. London dispersion forces (Xe) d. London dispersion forces (C2H6) e. Ionic bonds (Cs鈦 and I鈦) f. Van der Waals forces (P4) g. Hydrogen bonds (NH3)

Step by step solution

01

a. BaSO4

BaSO4 is an ionic compound, composed of the ions Ba虏鈦 and SO鈧劼测伝. The strongest interparticle force in this solid is the ionic bond between these ions.
02

b. H2S

H2S is a polar covalent molecule with hydrogen atoms covalently bonded to a sulfur atom. In its solid state, the most important interparticle force is the dipole-dipole interaction between the polar H2S molecules.
03

c. Xe

Xe is a noble gas, and its atoms interact through weak London dispersion forces (Van der Waals forces) in the solid state. These forces arise from temporary fluctuations in the electron distribution.
04

d. C2H6

C2H6 is a nonpolar covalent molecule known as ethane. In its solid state, the most important interparticle force is the London dispersion force due to temporary fluctuations in electron distribution.
05

e. CsI

CsI is an ionic compound composed of the ions Cs鈦 and I鈦. The strongest interparticle force in this solid is the ionic bond between these ions.
06

f. P4

P4 is a molecular solid, with covalent bonds between phosphorus atoms forming P4 molecules. In its solid state, the most important interparticle force is the Van der Waals force, as there are no hydrogen or dipole-dipole interactions present in the structure.
07

g. NH3

NH3, also known as ammonia, is a polar covalent molecule with nitrogen and hydrogen atoms covalently bonded. In its solid state, the most important interparticle force is the hydrogen bond between the nitrogen atom of one molecule and the hydrogen atom of another molecule.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ionic Bonds
Ionic bonds are one of the strongest types of interparticle forces. They occur when atoms of one element transfer electrons to atoms of another, forming ions. These ions, usually involving a metal and a nonmetal, are then attracted to each other by their opposite charges. For instance, in compounds like \(\text{BaSO}_4\) and \(\text{CsI}\), we see ionic bonds between \(\text{Ba}^{2+}\) and \(\text{SO}_4^{2-}\) ions, and between \(\text{Cs}^+\) and \(\text{I}^-\) ions, respectively.
The energy required to break these ionic bonds is significant due to the strong electrostatic attraction. This results in high melting and boiling points for ionic compounds. Generally, ionic compounds are hard and brittle in their solid form, and they conduct electricity when dissolved in water or melted because their ions are free to move.
Dipole-Dipole Interaction
Dipole-dipole interactions occur in polar molecules where there is an uneven distribution of electrons. This creates a dipole moment, where one end of the molecule is slightly negative and the other is slightly positive. These interactions aren't as strong as ionic bonds, but they still significantly influence the properties of substances.
In the example of \(\text{H}_2\text{S}\), molecules have a bent shape causing an uneven distribution of charges. The partially positive hydrogens are attracted to the partially negative sulfurs of neighboring molecules, creating dipole-dipole interactions. These forces affect the boiling and melting points, but they are generally lower compared to substances with stronger ionic bonds.
Hydrogen Bonds
Hydrogen bonds are a special type of dipole-dipole interaction that occurs when hydrogen is bonded to highly electronegative atoms like nitrogen, oxygen, or fluorine. This creates a strong dipole where the hydrogen atom becomes quite positive, allowing it to form a bond with an electronegative atom in another molecule.
In ammonia, \(\text{NH}_3\), hydrogen bonds are crucial for its properties. The nitrogen atom has a lone pair of electrons, making it very electronegative and prone to form hydrogen bonds with the hydrogen of another \(\text{NH}_3\) molecule. This results in relatively high boiling points for a molecular compound, as the energy needed to break these hydrogen bonds is quite substantial.
London Dispersion Forces
London dispersion forces are the weakest of all interparticle forces. They arise from temporary fluctuations in electron distribution that create instantaneous dipoles, which in turn induce dipoles in neighboring atoms or molecules.
These forces are present in all atoms and molecules, but they are the only type of interparticle force in nonpolar molecules. For example, in \(\text{Xe}\) and \(\text{C}_2\text{H}_6\), these fluctuations allow the atoms or molecules to be momentarily polar, leading to attraction. Generally, these forces are weaker than other interactions, leading to lower boiling and melting points.
Molecular Solids
Molecular solids are composed of molecules held together by various interparticle forces, including hydrogen bonds, dipole interactions, and London dispersion forces. These solids tend to have lower melting points than ionic or covalent solids because the forces holding the molecules together are weaker.
Take \(\text{P}_4\) for example, it's a molecular solid where covalent bonds hold phosphorus atoms together within each molecule, but these molecules are held in the solid by weaker Van der Waals forces. These types of solids often exhibit properties like softness and lower melting points, and they do not conduct electricity as they lack free ions or charge carriers.

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Most popular questions from this chapter

Some ionic compounds contain a mixture of different charged cations. For example, some titanium oxides contain a mixture of \(\mathrm{Ti}^{2+}\) and \(\mathrm{Ti}^{3+}\) ions. Consider a certain oxide of titanium that is \(28.31 \%\) oxygen by mass and contains a mixture of \(\mathrm{Ti}^{2+}\) and \(\mathrm{Ti}^{3+}\) ions. Determine the formula of the compound and the relative numbers of \(\mathrm{Ti}^{2+}\) and \(\mathrm{Ti}^{3+}\) ions.

Water in an open beaker evaporates over time. As the water is evaporating, is the vapor pressure increasing, decreasing, or staying the same? Why?

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General Zod has sold Lex Luthor what Zod claims to be a new copper-colored form of kryptonite, the only substance that can harm Superman. Lex, not believing in honor among thieves, decided to carry out some tests on the supposed kryptonite. From previous tests, Lex knew that kryptonite is a metal having a specific heat capacity of \(0.082 \mathrm{J} / \mathrm{g} \cdot^{\circ} \mathrm{C}\) and a density of \(9.2 \mathrm{g} / \mathrm{cm}^{3}.\) Lex Luthor's first experiment was an attempt to find the specific heat capacity of kryptonite. He dropped a \(10 \mathrm{g} \pm 3 \mathrm{g}\) sample of the metal into a boiling water bath at a temperature of \(100.0^{\circ} \mathrm{C} \pm 0.2^{\circ} \mathrm{C} .\) He waited until the metal had reached the bath temperature and then quickly transferred it to \(100 \mathrm{g} \pm 3 \mathrm{g}\) of water that was contained in a calorimeter at an initial temperature of \(25.0^{\circ} \mathrm{C} \pm 0.2^{\circ} \mathrm{C} .\) The final temperature of the metal and water was \(25.2^{\circ} \mathrm{C} .\) Based on these results, is it possible to distinguish between copper and kryptonite? Explain. When Lex found that his results from the first experiment were inconclusive, he decided to determine the density of the sample. He managed to steal a better balance and determined the mass of another portion of the purported kryptonite to be \(4 \mathrm{g} \pm 1\) g. He dropped this sample into water contained in a 25-mL graduated cylinder and found that it displaced a volume of \(0.42 \mathrm{mL} \pm 0.02 \mathrm{mL} .\) Is the metal copper or kryptonite? Explain. Lex was finally forced to determine the crystal structure of the metal General Zod had given him. He found that the cubic unit cell contained four atoms and had an edge length of \(600 . \mathrm{pm} .\) Explain how this information enabled Lex to identify the metal as copper or kryptonite. Will Lex be going after Superman with the kryptonite or seeking revenge on General Zod? What improvements could he have made in his experimental techniques to avoid performing the crystal structure determination?

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