Chapter 9: Problem 21
How does each of the following affect the rate of evaporation of a liquid in an open dish? a. intermolecular forces b. temperature c. surface area
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Chapter 9: Problem 21
How does each of the following affect the rate of evaporation of a liquid in an open dish? a. intermolecular forces b. temperature c. surface area
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Consider two different organic compounds, each with the formula \(\mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O}\). One of these compounds is a liquid at room conditions and the other is a gas. Write Lewis structures consistent with this observation, and explain your answer. (Hint: The oxygen atom in both structures satisfies the octet rule with two bonds and two lone pairs.)
Predict which substance in each of the following pairs would have the greater intermolecular forces. a. \(\mathrm{CO}_{2}\) or \(\mathrm{OCS}\) b. \(\operatorname{SeO}_{2}\) or \(\mathrm{SO}_{2}\) \(\mathbf{c .} \cdot \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\) or \(\mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\) d. \(\mathrm{CH}_{3} \mathrm{CH}_{3}\) or \(\mathrm{H}_{2} \mathrm{CO}\) e. \(\mathrm{CH}_{3} \mathrm{OH}\) or \(\mathrm{H}_{2} \mathrm{CO}\)
Nickel has a face-centered cubic unit cell. The density of nickel is \(6.84 \mathrm{g} / \mathrm{cm}^{3} .\) Calculate a value for the atomic radius of nickel.
Iron has a density of \(7.86 \mathrm{g} / \mathrm{cm}^{3}\) and crystallizes in a bodycentered cubic lattice. Show that only \(68 \%\) of a body-centered lattice is actually occupied by atoms, and determine the atomic radius of iron.
Use the kinetic molecular theory to explain why a liquid gets cooler as it evaporates from an insulated container.
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