Chapter 8: Problem 25
Which noble gas has the smallest density at STP? Explain.
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Chapter 8: Problem 25
Which noble gas has the smallest density at STP? Explain.
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Calculate the pressure exerted by \(0.5000\) mole of \(\mathrm{N}_{2}\) in a \(10.000-\mathrm{L}\) container at \(25.0^{\circ} \mathrm{C}\). a. using the ideal gas law. b. using the van der Waals equation. c. Compare the results. d. Compare the results with those in Exercise 115.
Suppose two 200.0 - \(L\) tanks are to be filled separately with the gases helium and hydrogen. What mass of each gas is needed to produce a pressure of 2.70 atm in its respective tank at \(24^{\circ} \mathrm{C} ?\)
One of the chemical controversies of the nineteenth century concerned the element beryllium (Be). Berzelius originally claimed that beryllium was a trivalent element (forming \(\mathrm{Be}^{3+}\) ions) and that it gave an oxide with the formula \(\mathrm{Be}_{2} \mathrm{O}_{3}\). This resulted in a calculated atomic mass of \(13.5\) for beryllium. In formulating his periodic table, Mendeleev proposed that beryllium was divalent (forming \(\mathrm{Be}^{2+}\) ions) and that it gave an oxide with the formula BeO. This assumption gives an atomic mass of \(9.0 .\) In \(1894,\) A. Combes (Comptes Rendus 1894 p. 1221 ) reacted beryllium with the anion \(C_{5} \mathrm{H}_{7} \mathrm{O}_{2}^{-}\) and measured the density of the gaseous product. Combes's data for two different experiments are as follows:If beryllium is a divalent metal, the molecular formula of the product will be \(\mathrm{Be}\left(\mathrm{C}_{5} \mathrm{H}_{7} \mathrm{O}_{2}\right)_{2} ;\) if it is trivalent, the formula will be \(\mathrm{Be}\left(\mathrm{C}_{5} \mathrm{H}_{7} \mathrm{O}_{2}\right)_{3} .\) Show how Combes's data help to confirm that beryllium is a divalent metal.
Freon-12 \(\left(\mathrm{CF}_{2} \mathrm{Cl}_{2}\right)\) is commonly used as the refrigerant in central home air conditioners. The system is initially charged to a pressure of 4.8 atm. Express this pressure in each of the following units ( 1 atm \(=14.7\) psi). a. \(\mathrm{mm} \mathrm{Hg}\) b. \(torr\) c. \(Pa\) d. \(psi\)
Calculate the root mean square velocities of \(\mathrm{CH}_{4}(g)\) and \(\mathrm{N}_{2}(g)\) molecules at \(273 \mathrm{K}\) and \(546 \mathrm{K}\).
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