Chapter 7: Problem 21
Why is it a good idea to rinse your thermos bottle with hot water before filling it with hot coffee?
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Chapter 7: Problem 21
Why is it a good idea to rinse your thermos bottle with hot water before filling it with hot coffee?
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Assuming gasoline is pure \(\mathrm{C}_{8} \mathrm{H}_{18}(l),\) predict the signs of \(q\) and \(w\) for the process of combusting gasoline into \(\mathrm{CO}_{2}(g)\) and \(\mathrm{H}_{2} \mathrm{O}(g)\).
The standard enthalpy of combustion of ethene gas, \(\mathrm{C}_{2} \mathrm{H}_{4}(g)\) is \(-1411.1 \mathrm{kJ} / \mathrm{mol}\) at \(298 \mathrm{K}\). Given the following enthalpies of formation, calculate \(\Delta H_{\mathrm{f}}^{\circ}\) for \(\mathrm{C}_{2} \mathrm{H}_{4}(g)\). $$\begin{array}{ll}\mathrm{CO}_{2}(g) & -393.5 \mathrm{kJ} / \mathrm{mol} \\\\\mathrm{H}_{2} \mathrm{O}(l) & -285.8 \mathrm{kJ} / \mathrm{mol}\end{array}$$
Consider 2.00 moles of an ideal gas that are taken from state \(A\) \(\left(P_{A}=2.00 \mathrm{atm}, V_{A}=10.0 \mathrm{L}\right)\) to state \(B\left(P_{B}=1.00 \mathrm{atm}, V_{B}=\right.\) \(30.0 \mathrm{L})\) by two different pathways: These pathways are summarized on the following graph of \(P\) versus \(V:\) Calculate the work (in units of J) associated with the two pathways. Is work a state function? Explain.
For the reaction \(\mathrm{HgO}(s) \rightarrow \mathrm{Hg}(l)+\frac{1}{2} \mathrm{O}_{2}(g), \Delta H=+90.7 \mathrm{kJ}\). a. What quantity of heat is required to produce 1 mole of mercury by this reaction? b. What quantity of heat is required to produce 1 mole of oxygen gas by this reaction? c. What quantity of heat would be released in the following reaction as written? $$2 \mathrm{Hg}(l)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{HgO}(s)$$
Given the following data $$\begin{array}{ll}\mathrm{Fe}_{2} \mathrm{O}_{3}(s)+3 \mathrm{CO}(g) \longrightarrow 2 \mathrm{Fe}(s)+3 \mathrm{CO}_{2}(g) & \Delta H^{\circ}=-23 \mathrm{kJ} \\ 3 \mathrm{Fe}_{2} \mathrm{O}_{3}(s)+\mathrm{CO}(g) \longrightarrow 2 \mathrm{Fe}_{3} \mathrm{O}_{4}(s)+\mathrm{CO}_{2}(g) & \Delta H^{\circ}=-39 \mathrm{kJ} \\ \mathrm{Fe}_{3} \mathrm{O}_{4}(s)+\mathrm{CO}(g) \longrightarrow 3 \mathrm{FeO}(s)+\mathrm{CO}_{2}(g) & \Delta H^{\circ}=18 \mathrm{kJ} \end{array}$$ calculate \(\Delta H^{\circ}\) for the reaction $$\mathrm{FeO}(s)+\mathrm{CO}(g) \longrightarrow \mathrm{Fe}(s)+\mathrm{CO}_{2}(g)$$
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