/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 166 A \(9.780-\mathrm{g}\) gaseous m... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

A \(9.780-\mathrm{g}\) gaseous mixture contains ethane \(\left(\mathrm{C}_{2} \mathrm{H}_{6}\right)\) and propane \(\left(\mathrm{C}_{3} \mathrm{H}_{8}\right) .\) Complete combustion to form carbon dioxide and water requires 1.120 mole of oxygen gas. Calculate the mass percent of ethane in the original mixture.

Short Answer

Expert verified
The mass percent of ethane in the original gaseous mixture is approximately 21.14%.

Step by step solution

01

Write the balanced combustion equations for ethane and propane

The balanced combustion equations for ethane and propane are \(C_2H_6 + \dfrac{7}{2} O_2 \rightarrow 2 CO_2 + 3 H_2O\) \(C_3H_8 + 5 O_2 \rightarrow 3 CO_2 + 4 H_2O\) These equations tell us that 1 mole of ethane requires \(\dfrac{7}{2}\) moles of oxygen for combustion, while 1 mole of propane requires 5 moles of oxygen.
02

Set up a system of equations to find the moles of ethane and propane

Let x represent the moles of ethane and y represent the moles of propane. Then, we have the following system of equations: \(x\left(\dfrac{7}{2}\right) + 5y = 1.120\) moles of oxygen (from the balanced equations) \(30x + 44y = 9.780\) g (total mass of the ethane and propane mixture)
03

Solve the system of equations

To solve the system of equations, we can multiply the first equation by -30 and then add the two equations to eliminate x: \(-15x - 30y = -3.360\) \(-30x - 14y = -9.780\) Now, add the equations: \(-44y = -13.140\) Divide by -44 to solve for y: \(y = 0.29886\) moles of propane Now, substitute y back into the first equation to solve for x: \(x\left(\dfrac{7}{2}\right) + 5(0.29886) = 1.120\) \(x = 0.11762\) moles of ethane
04

Convert moles to mass and find the mass percent of ethane

Now that we have the moles of ethane and propane, we can convert them to mass and find the mass percent of ethane. Mass of ethane = moles of ethane × molar mass of ethane \(Mass_{ethane} = 0.11762 \times 30 = 3.5286\;\mathrm{g}\) Mass of propane = moles of propane × molar mass of propane \(Mass_{propane} = 0.29886 \times 44 = 13.14984\;\mathrm{g}\) Now, we can find the mass percent of ethane: Mass percent of ethane = \(\dfrac{Mass_{ethane}}{Mass_{ethane} + Mass_{propane}} \times 100\) Mass percent of ethane = \(\dfrac{3.5286}{3.5286 + 13.14984} \times 100 \approx 21.14\%\) Therefore, the mass percent of ethane in the original mixture is approximately 21.14%.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Combustion Reactions
Combustion reactions are a type of chemical reaction where a substance combines with oxygen and releases energy in the form of heat and light. This process is fundamental in stoichiometry, as it helps determine the reactants and products involved in burning substances like hydrocarbons. For hydrocarbons such as ethane - (\(C_2H_6\)) and propane - (\(C_3H_8\)), the products of complete combustion are carbon dioxide (\(CO_2\)) and water (\(H_2O\)).

In the given problem, ethane and propane react with oxygen. The balanced equations are:
  • For ethane: \(C_2H_6 + \dfrac{7}{2} O_2 \rightarrow 2 CO_2 + 3 H_2O\)
  • For propane: \(C_3H_8 + 5 O_2 \rightarrow 3 CO_2 + 4 H_2O\)


These equations indicate that combustion processes are consistent in their stoichiometry, utilizing specific ratios of reactants and products.
Mass Percent
Mass percent is a way of expressing the concentration of a component in a mixture by comparing the mass of the component to the total mass of the mixture. It is a common technique in chemistry for expressing the composition of mixtures.

To find the mass percent of ethane in a mixture, you first need the mass of ethane and the total mass of the mixture. In the exercise provided, mass calculations for each gas were performed after determining the moles:
  • Mass of ethane: calculated using \(0.11762\) moles, the molar mass (\(30\) g/mol), resulting in \(3.5286\) g.
  • Mass of propane is \(13.14984\) g, calculated similarly from \(0.29886\) moles and molar mass \(44\) g/mol.


Finally, the mass percent of ethane is determined by dividing the mass of ethane by the total mass of the mixture. Multiplication by 100 converts it to a percentage:
\[ Mass \; percent \; of \; ethane = \dfrac{3.5286}{3.5286 + 13.14984} \times 100 \approx 21.14\% \]

This showed ethane made up approximately \(21.14\%\) of the original mixture.
Balanced Chemical Equations
Balanced chemical equations are crucial in tracking the quantities of reactants and products in a chemical reaction. They ensure that the law of conservation of mass is adhered to, meaning the number of atoms of each element is the same on both sides of the equation.

In the problem of burning ethane and propane, each component's combustion reaction must be balanced. This involves:
  • Assigning correct stoichiometric coefficients to each reactant and product.
  • Ensuring that both moles and types of atoms are the same on both sides.


For ethane, the balanced equation is: \[C_2H_6 + \frac{7}{2} O_2 \rightarrow 2 CO_2 + 3 H_2O\]And for propane: \[C_3H_8 + 5 O_2 \rightarrow 3 CO_2 + 4 H_2O\]

This guarantees that the correct amount of oxygen is used and carbon dioxide with water is formed at precise amounts. Balanced reactions are the foundation for stoichiometric calculations that follow, ensuring accurate quantification of substances involved.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Consider the following unbalanced reaction: $$\mathrm{P}_{4}(s)+\mathrm{F}_{2}(g) \longrightarrow \mathrm{PF}_{3}(g)$$ What mass of \(\mathrm{F}_{2}\) is needed to produce \(120 . \mathrm{g}\) of \(\mathrm{PF}_{3}\) if the reaction has a \(78.1 \%\) yield?

In the production of printed circuit boards for the electronics industry, a 0.60-mm layer of copper is laminated onto an insulating plastic board. Next, a circuit pattern made of a chemically resistant polymer is printed on the board. The unwanted copper is removed by chemical etching, and the protective polymer is finally removed by solvents. One etching reaction is $$\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}(a q)+4 \mathrm{NH}_{3}(a q)+\mathrm{Cu}(s) \longrightarrow 2 \mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}(a q)$$ A plant needs to manufacture 10,000 printed circuit boards, each \(8.0 \times 16.0 \mathrm{cm}\) in area. An average of \(80 . \%\) of the copper is removed from each board (density of copper \(=8.96 \mathrm{g} / \mathrm{cm}^{3}\)). What masses of \(\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\) and \(\mathrm{NH}_{3}\) are needed to do this? Assume \(100 \%\) yield.

Balance the following equations: a. \(\operatorname{Cr}(s)+\mathrm{S}_{8}(s) \rightarrow \mathrm{Cr}_{2} \mathrm{S}_{3}(s)\) b. \(\mathrm{NaHCO}_{3}(s) \stackrel{\text { Heat }}{\longrightarrow} \mathrm{Na}_{2} \mathrm{CO}_{3}(s)+\mathrm{CO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(g)\) c. \(\mathrm{KClO}_{3}(s) \stackrel{\text { Heat }}{\longrightarrow} \mathrm{KCl}(s)+\mathrm{O}_{2}(g)\) d. \(\mathrm{Eu}(s)+\mathrm{HF}(g) \rightarrow \mathrm{EuF}_{3}(s)+\mathrm{H}_{2}(g)\)

Some bismuth tablets, a medication used to treat upset stomachs, contain \(262 \mathrm{mg}\) of bismuth subsalicylate, \(\mathrm{C}_{7} \mathrm{H}_{5} \mathrm{BiO}_{4},\) per tablet. Assuming two tablets are digested, calculate the mass of bismuth consumed.

Para-cresol, a substance used as a disinfectant and in the manufacture of several herbicides, is a molecule that contains the elements carbon, hydrogen, and oxygen. Complete combustion of a 0.345-g sample of \(p\)-cresol produced 0.983 g carbon dioxide and \(0.230 \mathrm{g}\) water. Determine the empirical formula for \(p\)-cresol.

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.