Chapter 19: Problem 91
What is the hybridization of the underlined nitrogen atom in each of the following molecules or ions? a. \(\underline{N O}^{+}\) b. \(\mathrm{N}_{2} \mathrm{O}_{3}\left(\mathrm{O}_{2} \mathrm{N} \underline{\mathrm{NO}}\right)\) c. \(\underline{N O}_{2}^{-}\) d. \(\underline{N}_{2}\)
Short Answer
Expert verified
The hybridization states of the underlined nitrogen atoms in the given molecules or ions are:
a. \(NO^{+}\): sp
b. \(O_2NNO (N_2O_3)\): sp虏
c. \(NO_2^{-}\): sp虏
d. \(N_2\): sp虏
Step by step solution
01
Finding Steric Number
Determine the steric number for each nitrogen atom (defined as the number of bond pairs and lone pairs around it):
a. NO鈦
b. O鈧侼NO (N鈧侽鈧)
c. NO鈧傗伝
d. N鈧
02
Determining Hybridization
Find the hybridization state of the underlined nitrogen atom in each molecule/ion using the steric number calculated from Step 1.
a. NO鈦
03
Step 2a: Steric Number for NO鈦
In the case of NO鈦, there are two atoms bonded to the nitrogen (O and N鈦) and no lone pairs. So the steric number of the nitrogen is 2.
04
Step 2b: Hybridization of NO鈦
If the steric number is 2, the hybridization will be sp. Therefore, the hybridization of the underlined nitrogen atom in NO鈦 is sp.
b. O鈧侼NO (N鈧侽鈧)
05
Step 2c: Steric Number for N鈧侽鈧
In the case of N鈧侽鈧, there are three atoms bonded to the nitrogen atom (2 O atoms and 1 N atom) and no lone pairs. So the steric number of the nitrogen is 3.
06
Step 2d: Hybridization of N鈧侽鈧
If the steric number is 3, the hybridization will be sp虏. Therefore, the hybridization of the underlined nitrogen atom in N鈧侽鈧 (O鈧侼NO) is sp虏.
c. NO鈧傗伝
07
Step 2e: Steric Number for NO鈧傗伝
In the case of NO鈧傗伝, there are two atoms bonded to the nitrogen atom (2 O atoms) and one lone pair. So the steric number of the nitrogen is 3.
08
Step 2f: Hybridization of NO鈧傗伝
If the steric number is 3, the hybridization will be sp虏. Therefore, the hybridization of the underlined nitrogen atom in NO鈧傗伝 is sp虏.
d. N鈧
09
Step 2g: Steric Number for N鈧
In the case of N鈧, there is one atom bonded to the nitrogen atom (another N atom) and two lone pairs. So the steric number of the nitrogen is 3.
10
Step 2h: Hybridization of N鈧
If the steric number is 3, the hybridization will be sp虏. Therefore, the hybridization of the underlined nitrogen atom in N鈧 is sp虏.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Steric Number
The concept of the "Steric Number" is crucial in understanding the hybridization of atoms in molecules. It tells us how crowded an atom is with bonds and lone pairs. To calculate it, you add up all the atoms directly bonded to the atom in question and also include any lone pairs of electrons.
For example:
For example:
- If an atom has 2 atoms bonded to it and no lone pairs, the steric number is 2.
- If it has 2 atoms bonded and 1 lone pair, the steric number becomes 3.
Nitrogen Compounds
Nitrogen compounds are a diverse group of chemical substances where nitrogen atoms are bonded to various other elements. Nitrogen can form compounds by sharing its electrons to bond with other atoms, such as oxygen or carbon.
Some common nitrogen compounds are nitrates, ammonium, and oxides of nitrogen, each showing different chemical properties due to their unique structures.
Understanding nitrogen compounds' structuring helps predict their behaviors in chemical reactions and their physical properties. The hybridization state of nitrogen in a compound noticeably affects the geometry and type of bonds formed, influencing the overall stability and reactivity of the compound.
Some common nitrogen compounds are nitrates, ammonium, and oxides of nitrogen, each showing different chemical properties due to their unique structures.
Understanding nitrogen compounds' structuring helps predict their behaviors in chemical reactions and their physical properties. The hybridization state of nitrogen in a compound noticeably affects the geometry and type of bonds formed, influencing the overall stability and reactivity of the compound.
Chemical Bonding
Chemical bonding involves the joining of atoms to form molecules. This occurs when atoms share or transfer electrons to achieve stable electron arrangements. Nitrogen atoms can form single, double, or triple bonds, depending on the compound:
- Single bonds occur when only one pair of electrons is shared between two atoms.
- Double bonds involve two pairs of shared electrons.
- Triple bonds, seen in nitrogen gas ( 鈧), involve three pairs of electrons and are very strong.
SP Hybridization
SP hybridization happens when one s orbital mixes with one p orbital to form two equivalent sp orbitals. This type of hybridization is associated with a linear geometry around the central atom and a steric number of 2.
For instance, in nitric oxide cation ( 鈦), the nitrogen shows sp hybridization due to bonding with one oxygen and holding a positive charge without lone pairs. This configuration can result in molecules that are very reactive due to their highly directed orbitals, influencing their participation in chemical reactions.
It鈥檚 an important concept to grasp as it sets the foundation for understanding how molecular shape and bond angles arise from atomic orbitals.
For instance, in nitric oxide cation ( 鈦), the nitrogen shows sp hybridization due to bonding with one oxygen and holding a positive charge without lone pairs. This configuration can result in molecules that are very reactive due to their highly directed orbitals, influencing their participation in chemical reactions.
It鈥檚 an important concept to grasp as it sets the foundation for understanding how molecular shape and bond angles arise from atomic orbitals.
SP虏 Hybridization
SP虏 hybridization, or 'sp squared' hybridization, occurs when one s orbital and two p orbitals mix to create three equivalent sp虏 orbitals. This usually results in a trigonal planar shape around the central atom and a steric number of 3.
In molecules like dinitrogen trioxide (N鈧侽鈧), the nitrogen can achieve sp虏 hybridization, allowing it to form bonds with three neighboring atoms. This hybridization often results in planar molecules with bond angles of about 120 degrees, which can influence things like reactivity and molecular polarity.
Understanding sp虏 hybridization helps predict the molecular geometry and how compounds interact, especially for reactions that depend on the geometry of molecules.
In molecules like dinitrogen trioxide (N鈧侽鈧), the nitrogen can achieve sp虏 hybridization, allowing it to form bonds with three neighboring atoms. This hybridization often results in planar molecules with bond angles of about 120 degrees, which can influence things like reactivity and molecular polarity.
Understanding sp虏 hybridization helps predict the molecular geometry and how compounds interact, especially for reactions that depend on the geometry of molecules.