Chapter 15: Problem 15
List some ways one can increase the solubility of a salt in water.
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Chapter 15: Problem 15
List some ways one can increase the solubility of a salt in water.
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The \(K_{\mathrm{sp}}\) of \(\mathrm{Al}(\mathrm{OH})_{3}\) is \(2 \times 10^{-32} .\) At what \(\mathrm{pH}\) will a \(0.2-M\) \(\mathrm{Al}^{3+}\) solution begin to show precipitation of \(\mathrm{Al}(\mathrm{OH})_{3} ?\)
The \(K_{\mathrm{sp}}\) for silver sulfate \(\left(\mathrm{Ag}_{2} \mathrm{SO}_{4}\right)\) is \(1.2 \times 10^{-5} .\) Calculate the solubility of silver sulfate in each of the following. a. water b. \(0.10 M\) AgNO \(_{3}\) c. \(0.20 M \mathrm{K}_{2} \mathrm{SO}_{4}\)
Calculate the solubility of solid \(\mathrm{Pb}_{3}\left(\mathrm{PO}_{4}\right)_{2}\left(K_{\mathrm{sp}}=1 \times 10^{-54}\right)\) in a \(0.10-M \mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}\) solution.
What is the maximum possible concentration of \(\mathrm{Ni}^{2+}\) ion in water at \(25^{\circ} \mathrm{C}\) that is saturated with \(0.10 \mathrm{M} \mathrm{H}_{2} \mathrm{S}\) and maintained at \(\mathrm{pH} 3.0\) with HCl?What is the maximum possible concentration of \(\mathrm{Ni}^{2+}\) ion in water at \(25^{\circ} \mathrm{C}\) that is saturated with \(0.10\) \(M\) \(\mathrm{H}_{2} \mathrm{S}\) and maintained at \(\mathrm{pH} 3.0\) with \(\mathrm{HCl}\)?
\(\mathrm{Ag}_{2} \mathrm{S}(s)\) has a larger molar solubility than CuS even though \(\mathrm{Ag}_{2} \mathrm{S}\) has the smaller \(K_{\mathrm{sp}}\) value. Explain how this is possible.
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