Chapter 13: Problem 94
Calculate the concentration of an aqueous \(\operatorname{Sr}(\mathrm{OH})_{2}\) that has \(\mathrm{pH}=10.50\)
Short Answer
Expert verified
The concentration of the aqueous Sr(OH)鈧 solution with a pH of 10.50 is approximately \(1.59 \times 10^{-4}\) mol/L.
Step by step solution
01
Find the hydrogen ion concentration
We are given the pH value of the solution, which is 10.50. To find the H鈦 concentration, we can use the equation:
pH = -log[H鈦篯
where pH is the pH value and [H鈦篯 is the H鈦 concentration. We can solve for [H鈦篯 using the following formula:
[H鈦篯 = 10^(-pH)
So, for our case:
[H鈦篯 = 10^(-10.50)
Calculating this, we get:
[H鈦篯 鈮 3.16 脳 10鈦宦孤 mol/L
02
Find the hydroxide ion concentration
Now that we have the H鈦 concentration, we can find the OH鈦 concentration using the relationship between H鈦 and OH鈦 concentration:
[H鈦篯 脳 [OH鈦籡 = Kw
where [OH鈦籡 is the OH鈦 concentration, and Kw is the ion product of water, which is constant and equals 1 脳 10鈦宦光伌 at 25掳C. We can use this equation to solve for [OH鈦籡:
[OH鈦籡 = Kw / [H鈦篯
For our case:
[OH鈦籡 = 1 脳 10鈦宦光伌 / 3.16 脳 10鈦宦孤
Calculating this, we get:
[OH鈦籡 鈮 3.17 脳 10鈦烩伌 mol/L
03
Find the concentration of Sr(OH)鈧
In an aqueous solution, strontium hydroxide (Sr(OH)鈧) dissociates into its ions as follows:
Sr(OH)鈧 鈫 Sr虏鈦 + 2OH鈦
From the stoichiometry of the reaction, we know that one molecule of Sr(OH)鈧 dissociates to produce two OH鈦 ions. Therefore, the concentration of Sr(OH)鈧 is half the concentration of OH鈦:
[Sr(OH)鈧俔 = [OH鈦籡 / 2
For our case:
[Sr(OH)鈧俔 = 3.17 脳 10鈦烩伌 mol/L / 2
Calculating this, we get:
[Sr(OH)鈧俔 鈮 1.59 脳 10鈦烩伌 mol/L
So, the concentration of the aqueous Sr(OH)鈧 solution with a pH of 10.50 is approximately 1.59 脳 10鈦烩伌 mol/L.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Hydrogen Ion Concentration
When solving for the concentration of hydrogen ions in a solution, understanding how it relates to pH is essential. The pH of a solution is a measure of its acidity, and it is based on the concentration of hydrogen ions (\([H^+]\)). A lower pH indicates a higher concentration of hydrogen ions, meaning the solution is more acidic. Conversely, a higher pH means the solution is more basic, possessing fewer hydrogen ions.
To find the \([H^+]\) concentration from a given pH, we use the formula:
To find the \([H^+]\) concentration from a given pH, we use the formula:
- \([H^+] = 10^{-pH}\)
Hydroxide Ion Concentration
Understanding the concentration of hydroxide ions (\([OH^-]\)) is crucial in determining the basic nature of a solution. The relationship between hydrogen ions and hydroxide ions comes from the ion product constant of water (\(K_w\)), which at 25掳C is \(1 \times 10^{-14} \text{ mol}^2/\text{L}^2\). This implies that the multiplication of \([H^+]\)and \([OH^-]\) in any aqueous solution at this temperature equals this constant. Thus, if one ion concentration is known, the other can be easily calculated.
For hydroxide ions, we have:
For hydroxide ions, we have:
- \([OH^-] = \frac{K_w}{[H^+]} \)
Strontium Hydroxide Concentration
To find the concentration of strontium hydroxide (\( \text{Sr(OH)}_2\)) in a solution, we must consider its dissociation in water. Strontium hydroxide is a strong base and completely dissociates into strontium ions (\( \text{Sr}^{2+}\)) and hydroxide ions (\( \text{OH}^-\)) when dissolved. The chemical equation for this dissociation is:
- \( \text{Sr(OH)}_2 \rightarrow \text{Sr}^{2+} + 2\text{OH}^- \)
- \([\text{Sr(OH)}_2] = \frac{[OH^-]}{2} \)