Chapter 10: Problem 23
For an acid or a base, when is the normality of a solution equal to the molarity of the solution and when are the two concentration units different?
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Chapter 10: Problem 23
For an acid or a base, when is the normality of a solution equal to the molarity of the solution and when are the two concentration units different?
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Calculate the normality of each of the following solutions. a. \(0.250 M\space \mathrm {HCl}\) b. \(0.105 M\space \mathrm{H}_{2} \mathrm{SO}_{4}\) c. \(5.3 \times 10^{-2} M \space \mathrm{H}_{3} \mathrm{PO}_{4}\) d. \(0.134 M\space \mathrm{NaOH}\) e. \(0.00521 M \space \mathrm{Ca}(\mathrm{OH})_{2}\) What is the equivalent mass for each of the acids or bases listed above?
What volume of \(0.25 \mathrm{M}\) HCl solution must be diluted to prepare 1.00 L of \(0.040 M\) HCl?
A solution is made by mixing \(50.0 \mathrm{g}\) acetone \(\left(\mathrm{CH}_{3} \mathrm{COCH}_{3}\right)\) and 50.0 g methanol (CH_OH). What is the vapor pressure of this solution at \(25^{\circ} \mathrm{C} ?\) What is the composition of the vapor expressed as a mole fraction? Assume ideal solution and gas behavior. (At \(25^{\circ} \mathrm{C}\) the vapor pressures of pure acetone and pure methanol are 271 and 143 torr, respectively.) The actual vapor pressure of this solution is 161 torr. Explain any discrepancies.
An aqueous solution of 10.00 g of catalase, an enzyme found in the liver, has a volume of \(1.00 \mathrm{L}\) at \(27^{\circ} \mathrm{C}\). The solution's osmotic pressure at \(27^{\circ} \mathrm{C}\) is found to be 0.745 torr. Calculate the molar mass of catalase.
A solution is made by dissolving \(25.8 \mathrm{g}\) urea \(\left(\mathrm{CH}_{4} \mathrm{N}_{2} \mathrm{O}\right),\) a nonelectrolyte, in \(275 \mathrm{g}\) water. Calculate the vapor pressures of this solution at \(25^{\circ} \mathrm{C}\) and \(45^{\circ} \mathrm{C}\). (The vapor pressure of pure water is \(\left.23.8 \text { torr at } 25^{\circ} \mathrm{C} \text { and } 71.9 \text { torr at } 45^{\circ} \mathrm{C} .\right)\)
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