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A mixture of \(8.0 \mathrm{~g} \mathrm{CH}_{4}\) and \(8.0 \mathrm{~g}\) Xe is placed in a container, and the total pressure is found to be 0.44 atm. Determine the partial pressure of \(\mathrm{CH}_{4}\)

Short Answer

Expert verified
Partial pressure of CHâ‚„ is 0.20 atm.

Step by step solution

01

Calculate Moles of CHâ‚„ and Xe

Use the molar mass of CHâ‚„ (16.04 g/mol) and Xe (131.3 g/mol) to determine moles. For CHâ‚„: moles = 8.0 g / 16.04 g/mol. For Xe: moles = 8.0 g / 131.3 g/mol.
02

Calculate Total Moles

Add the moles of CHâ‚„ and Xe to get the total moles of the gas mixture.
03

Use Dalton's Law of Partial Pressures

According to Dalton's Law, the total pressure is the sum of partial pressures. Use the mole fraction of CHâ‚„ (moles of CHâ‚„ / total moles) to find its partial pressure: Partial pressure of CHâ‚„ = mole fraction of CHâ‚„ * total pressure.
04

Calculate Partial Pressure of CHâ‚„

Multiply the mole fraction of CHâ‚„ obtained in Step 3 by the total pressure to find the partial pressure of CHâ‚„.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Partial Pressure Calculation
Understanding how to calculate partial pressure is essential when dealing with mixtures of gases. Partial pressure is the pressure that a gas in a mixture would exert if it occupied the entire volume alone at the same temperature. To calculate the partial pressure of a specific gas, like methane (CHâ‚„) in our exercise, we use Dalton's Law of Partial Pressures.

For example, if you have a mixture of CHâ‚„ and xenon (Xe) with a total pressure of 0.44 atm and you need to find the partial pressure of CHâ‚„, you first need to calculate the number of moles of each gas. Once you have the moles, determine the mole fraction of CHâ‚„, which is the ratio of moles of CHâ‚„ to the total moles in the mixture. Finally, the partial pressure of CHâ‚„ can be found by multiplying its mole fraction by the total pressure. This approach is particularly helpful when dealing with gas mixtures in closed containers, as it allows you to understand the contribution of each component to the overall pressure.
Mole Fraction
The mole fraction is a dimensionless quantity that represents the proportion of moles of a particular component to the total moles in a mixture. It is an important concept when dealing with mixtures in chemistry, especially gases.

To calculate the mole fraction, you divide the number of moles of the component of interest by the total number of moles in the mixture. For instance, if you have a mixture containing CHâ‚„ and Xe, calculate the moles of each gas separately and then divide the moles of CHâ‚„ by the total moles of both CHâ‚„ and Xe to find the mole fraction of CHâ‚„. This value is crucial for subsequent calculations, such as determining partial pressures using Dalton's Law. Mole fractions are also very useful in physical chemistry for predicting the behavior of gas mixtures under various conditions.
Gas Laws
Gas laws are mathematical relationships that describe how the physical properties of gases such as pressure, volume, temperature, and quantity of gas are related. Some well-known gas laws include Boyle's Law, which holds the temperature constant and shows the inverse relationship between pressure and volume, and Charles's Law, which keeps the pressure fixed and demonstrates the direct relationship between volume and temperature.

In our exercise involving Dalton's Law, we're also applying a fundamental principle from the ideal gas law. Dalton's Law ties together the concept of partial pressures in a mixture of non-reacting gases, which is a practical application of the ideal gas law in a mixture context. Understanding these gas laws allows for accurate predictions about the behavior of gases under different conditions, and they're the basis for many calculations in chemistry and physics.
Molecular Mass
The molecular mass (or molar mass) of a substance is the mass of one mole of that substance, and it is an essential parameter for converting between the mass of a substance and the amount of substance (moles). The unit of molecular mass is grams per mole (g/mol).

When calculating partial pressures, as we did with CHâ‚„ and Xe, knowing the molecular mass is vital for calculating the number of moles of each gas. To determine the molecular mass, you would sum the atomic masses of all the atoms in the molecule. In our example, the molecular mass of CHâ‚„ is 16.04 g/mol and that of Xe is 131.3 g/mol. Accurately determining the molecular mass is critical for all subsequent calculations involving the amount of substance, especially when dealing with gaseous reactions and the use of gas laws in quantitative chemistry.

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