Chapter 15: Problem 79
Many heterogeneous catalysts are deposited on high-surfacearea supports. Why?
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Chapter 15: Problem 79
Many heterogeneous catalysts are deposited on high-surfacearea supports. Why?
These are the key concepts you need to understand to accurately answer the question.
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Why is the reaction rate for reactants defined as the negative of the change in reactant concentration with respect to time, whereas for products it is defined as the change in reactant concentration with respect to time (with a positive sign)?
Suppose that the reaction \(\mathrm{A} \longrightarrow\) products is exothermic and has an activation barrier of \(75 \mathrm{~kJ} / \mathrm{mol} .\) Sketch an energy diagram showing the energy of the reaction as a function of the progress of the reaction. Draw a second energy curve showing the effect of a catalyst.
The energy of activation for the decomposition of \(2 \mathrm{~mol}\) of \(\mathrm{HI}\) to \(\mathrm{H}_{2}\) and \(\mathrm{I}_{2}\) in the gas phase is \(185 \mathrm{~kJ}\). The heat of formation of \(\mathrm{HI}(g)\) from \(\mathrm{H}_{2}(g)\) and \(\mathrm{I}_{2}(g)\) is \(-5.65 \mathrm{~kJ} / \mathrm{mol} .\) Find the energy of activation for the reaction of \(1 \mathrm{~mol}\) of \(\mathrm{H}_{2}\) and \(1 \mathrm{~mol}\) of \(\mathrm{I}_{2}\) to form 2 mol of HI in the gas phase.
The decomposition of \(\mathrm{XY}\) is second order in \(\mathrm{XY}\) and has a rate constant of \(7.02 \times 10^{-3} \mathrm{M}^{-1} \cdot \mathrm{s}^{-1}\) at a certain temperature. a. What is the half-life for this reaction at an initial concentra- tion of \(0.100 \mathrm{M} ?\) b. How long will it take for the concentration of XY to decrease to \(12.5 \%\) of its initial concentration when the ini- tial concentration is \(0.100 \mathrm{M}\) ? When the initial concentra- tion is \(0.200 \mathrm{M} ?\) c. If the initial concentration of \(\mathrm{XY}\) is \(0.150 \mathrm{M}\), how long will it take for the concentration to decrease to \(0.062 \mathrm{M} ?\) d. If the initial concentration of \(\mathrm{XY}\) is \(0.050 \mathrm{M},\) what is the concentration of XY after \(5.0 \times 10^{1}\) s? After \(5.50 \times 10^{2}\) s?
What are the four basic steps involved in heterogeneous catalysis?
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