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A reaction in which \(\mathrm{A}, \mathrm{B},\) and \(\mathrm{C}\) react to form products is first order in A, second order in B, and zero order in C. a. Write a rate law for the reaction. b. What is the overall order of the reaction? c. By what factor does the reaction rate change if [A] is doubled (and the other reactant concentrations are held constant)? d. By what factor does the reaction rate change if [B] is doubled (and the other reactant concentrations are held constant)? e. By what factor does the reaction rate change if [C] is doubled (and the other reactant concentrations are held constant)? f. By what factor does the reaction rate change if the concentrations of all three reactants are doubled?

Short Answer

Expert verified
Rate law: Rate = k[A][B]^2; Overall order: 3; Factor change if [A] is doubled: 2; Factor change if [B] is doubled: 4; Factor change if [C] is doubled: 1; Factor change if all reactants are doubled: 8.

Step by step solution

01

- Writing the Rate Law

The rate law is based on the order of reaction with respect to each reactant. Given the reaction is first order in A, second order in B, and zero order in C, the rate law can be written as: Rate = k[A]^[1][B]^[2][C]^[0], where k is the rate constant, [A], [B], and [C] are the concentrations of reactants A, B, and C respectively, and the exponents represent the reaction order with respect to each reactant.
02

- Determining the Overall Order

The overall order of a reaction is the sum of the orders with respect to each reactant. For this reaction, the overall order is: 1(order in A) + 2(order in B) + 0(order in C) = 1 + 2 + 0 = 3. Therefore, the overall order of the reaction is 3.
03

- Reaction Rate Change with Doubling [A]

If [A] is doubled and the other reactants are held constant, the reaction rate will change by a factor of 2^[1] = 2, since the reaction is first order with respect to A.
04

- Reaction Rate Change with Doubling [B]

If [B] is doubled and the other reactants are held constant, the reaction rate will change by a factor of 2^[2] = 4, because the reaction is second order with respect to B.
05

- Reaction Rate Change with Doubling [C]

If [C] is doubled and the other reactants are held constant, the rate of reaction will not change because the reaction is zero order with respect to C. Doubling the concentration of a reactant that the reaction is zero order in does not affect the rate of the reaction.
06

- Reaction Rate Change with Doubling All Reactants

If the concentrations of all three reactants are doubled, the rate will change by a factor of: 2^[1](effect of doubling [A]) * 2^[2](effect of doubling [B]) * 2^[0](effect of doubling [C]) = 2 * 4 * 1 = 8. Thus, the reaction rate is increased by a factor of 8.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Rate Law
Understanding the rate law is a cornerstone in chemical kinetics, which deals with the speed or rate at which a chemical reaction occurs. The rate law reflects how the rate is affected by the concentration of reactants in a reaction. It is generally represented by the expression 'Rate = k[A]^m[B]^n...', where 'k' is the rate constant, while 'm' and 'n' are the orders of the reaction with respect to each reactant 'A' and 'B'.

The orders, as indicated by the exponents, dictate how the rate will change as the concentration of each reactant changes. In a concrete example, for a reaction that is first order in A, second order in B, and zero order in C, we write the rate law as 'Rate = k[A][B]^2[C]^0'.

In simple terms, this tells us that the rate directly depends on the concentration of A, is quadratically dependent on the concentration of B, and is independent of the concentration of C. These relationships are essential for predicting how a change in concentration affects the reaction rate, making the rate law a powerful tool for chemists.
Reaction Kinetics
Reaction kinetics refers to the study of the rates of chemical processes and the factors that influence these rates. It involves the use of mathematical equations and models to describe and predict how quickly reactants are transformed into products.

Within the context of kinetics, we often evaluate how various factors such as temperature, pressure, reactant concentration, and the presence of catalysts affect the speed of a reaction. In our exercise we look at the correlation between reactant concentration and the rate of reaction.

To deepen this understanding, consider our previous example where the rate of reaction increases eightfold when concentrations of all reactants are doubled. This insight validates the practical impact of kinetics in industrial processes where control over the reaction speed can lead to more efficient production and safer operations.
Chemical Concentration
Chemical concentration, typically expressed in units like moles per liter (Molarity), provides information about the amount of a substance within a certain volume. It's a fundamental concept in chemistry, especially when examining reaction rates.

The concentration of reactants is directly involved in determining how fast a reaction will proceed according to the rate law. For instance, doubling the concentration of reactant A in our specific reaction, which is first order in A, will double the reaction rate. However, when a reactant is zero order, such as reactant C in our scenario, changing its concentration has no effect on the reaction rate.

Keeping a tab on concentrations allows chemists to manipulate rates purposefully to align with their desired outcomes, thereby highlighting the importance of precision when measuring chemical concentrations in both laboratory and industrial settings.

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Most popular questions from this chapter

The half-life for the radioactive decay of \(\mathrm{C}-14\) is 5730 years and is independent of the initial concentration. How long does it take for \(25 \%\) of the \(\mathrm{C}-14\) atoms in a sample of \(\mathrm{C}-14\) to decay? If a sample of C-14 initially contains 1.5 mmol of C-14, how many millimoles are left after 2255 years?

For the reaction \(2 \mathrm{~A}(g)+\mathrm{B}(g) \longrightarrow 3 \mathrm{C}(g),\) a. determine the expression for the rate of the reaction in terms of the change in concentration of each of the reactants and products. b. when \(A\) is decreasing at a rate of \(0.100 \mathrm{M} / \mathrm{s},\) how fast is \(\mathrm{B}\) decreasing? How fast is C increasing?

Explain the difference between the rate law for a reaction and the integrated rate law for a reaction. What relationship does each kind of rate law express?

The tabulated data show the rate constant of a reaction mea- sured at several different temperatures. Use an Arrhenius plot to determine the activation barrier and frequency factor for the reaction. $$ \begin{array}{cl} \text { Temperature (K) } & \text { Rate Constant (1/s) } \\ \hline 310 & 0.00434 \\ \hline 320 & 0.0140 \\ \hline 330 & 0.0421 \\ \hline 340 & 0.118 \\ \hline 350 & 0.316 \\ \hline \end{array} $$

The tabulated data were collected for this reaction at \(500^{\circ} \mathrm{C}\) : $$ \mathrm{CH}_{3} \mathrm{CN}(g) \longrightarrow \mathrm{CH}_{3} \mathrm{NC}(g) $$ $$ \begin{array}{cc} \text { Time (h) } & {\left[\mathrm{CH}_{3} \mathrm{CN]}\right. \text { (M) }} \\\ 0.0 & 1.000 \\ \hline 5.0 & 0.794 \\ \hline 10.0 & 0.631 \\ \hline 15.0 & 0.501 \\ \hline 20.0 & 0.398 \\ \hline 25.0 & 0.316 \\ \hline \end{array} $$ a. Determine the order of the reaction and the value of the rate constant at this temperature. b. What is the half-life for this reaction (at the initial concentration)? c. How long will it take for \(90 \%\) of the \(\mathrm{CH}_{3} \mathrm{CN}\) to convert to \(\mathrm{CH}_{3} \mathrm{NC} ?\)

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