Chapter 15: Problem 20
What is a catalyst? How does a catalyst increase the rate of a chemical reaction?
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Chapter 15: Problem 20
What is a catalyst? How does a catalyst increase the rate of a chemical reaction?
These are the key concepts you need to understand to accurately answer the question.
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Consider the tabulated data showing the initial rate of a reaction (A \(\longrightarrow\) products) at several different concentrations of A. What is the order of the reaction? Write a rate law for the reac- tion, including the value of the rate constant, \(k\). $$ \begin{array}{cc} {[\mathrm{A}](\mathrm{M})} & \text { Initial Rate }(\mathrm{M} / \mathrm{s}) \\\ 0.12 & 0.0078 \\ \hline 0.16 & 0.0104 \\ \hline 0.20 & 0.0130 \\ \hline \end{array} $$
The evaporation of a 120 -nm film of \(n\) -pentane from a single crystal of aluminum oxide is zero order with a rate constant of \(1.92 \times 10^{13} \mathrm{molecules} / \mathrm{cm}^{2} \cdot \mathrm{s}\) at \(120 \mathrm{~K}\) a. If the initial surface coverage is \(8.9 \times 10^{16}\) molecules \(/ \mathrm{cm}^{2}\), how long will it take for one-half of the film to evaporate? b. What fraction of the film is left after 10 s? Assume the same initial coverage as in part a.
Why is the reaction rate for reactants defined as the negative of the change in reactant concentration with respect to time, whereas for products it is defined as the change in reactant concentration with respect to time (with a positive sign)?
The tabulated data show the rate constant of a reaction mea- sured at several different temperatures. Use an Arrhenius plot to determine the activation barrier and frequency factor for the reaction. $$ \begin{array}{cl} \text { Temperature (K) } & \text { Rate Constant (1/s) } \\ \hline 310 & 0.00434 \\ \hline 320 & 0.0140 \\ \hline 330 & 0.0421 \\ \hline 340 & 0.118 \\ \hline 350 & 0.316 \\ \hline \end{array} $$
Iodine atoms combine to form \(\mathrm{I}_{2}\) in liquid hexane solvent with a rate constant of \(1.5 \times 10^{10} \mathrm{~L} / \mathrm{mol} \cdot \mathrm{s}\). The reaction is second order in I. since the reaction occurs so quickly, the only way to study the reaction is to create iodine atoms almost instanta- neously, usually by photochemical decomposition of \(\mathrm{I}_{2} .\) Suppose a flash of light creates an initial [I] concentration of \(0.0100 \mathrm{M} .\) How long will it take for \(95 \%\) of the newly created iodine atoms to recombine to form \(\mathrm{I}_{2} ?\)
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