Chapter 7: Problem 88
Write the expected electron configurations for each of the following atoms: Cl, Sb, Sr, W, Pb, Cf.
Short Answer
Expert verified
The electron configurations for the given atoms are:
- Cl: \(1s^2 2s^2 2p^6 3s^2 3p^5\)
- Sb: \(1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^{10} 4p^6 5s^2 4d^{10} 5p^3\)
- Sr: \(1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^{10} 4p^6 5s^2\)
- W: \(1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^{10} 4p^6 5s^2 4d^{10} 5p^6 6s^2 4f^{14} 5d^4\)
- Pb: \(1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^{10} 4p^6 5s^2 4d^{10} 5p^6 6s^2 4f^{14} 5d^{10} 6p^2\)
- Cf: \(1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^{10} 4p^6 5s^2 4d^{10} 5p^6 6s^2 4f^{14} 5d^{10} 6p^6 7s^2 5f^{10}\)
Step by step solution
01
Electron configuration of Chlorine (Cl)
Chlorine has 17 electrons. Start filling the orbitals in the order mentioned above:
1s虏 2s虏 2p鈦 3s虏 3p鈦
So, the electron configuration of Cl is: 1s虏 2s虏 2p鈦 3s虏 3p鈦
02
Electron configuration of Antimony (Sb)
Antimony has 51 electrons. Start filling the orbitals in the order mentioned above:
1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦 5s虏 4d鹿鈦 5p鲁
So, the electron configuration of Sb is: 1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦 5s虏 4d鹿鈦 5p鲁
03
Electron configuration of Strontium (Sr)
Strontium has 38 electrons. Start filling the orbitals in the order mentioned above:
1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦 5s虏
So, the electron configuration of Sr is: 1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦 5s虏
04
Electron configuration of Tungsten (W)
Tungsten has 74 electrons. Start filling the orbitals in the order mentioned above:
1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦 5s虏 4d鹿鈦 5p鈦 6s虏 4f鹿鈦 5d鈦
So, the electron configuration of W is: 1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦 5s虏 4d鹿鈦 5p鈦 6s虏 4f鹿鈦 5d鈦
05
Electron configuration of Lead (Pb)
Lead has 82 electrons. Start filling the orbitals in the order mentioned above:
1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦 5s虏 4d鹿鈦 5p鈦 6s虏 4f鹿鈦 5d鹿鈦 6p虏
So, the electron configuration of Pb is: 1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦 5s虏 4d鹿鈦 5p鈦 6s虏 4f鹿鈦 5d鹿鈦 6p虏
06
Electron configuration of Californium (Cf)
Californium has 98 electrons. Start filling the orbitals in the order mentioned above:
1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦 5s虏 4d鹿鈦 5p鈦 6s虏 4f鹿鈦 5d鹿鈦 6p鈦 7s虏 5f鹿鈦
So, the electron configuration of Cf is: 1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦 5s虏 4d鹿鈦 5p鈦 6s虏 4f鹿鈦 5d鹿鈦 6p鈦 7s虏 5f鹿鈦
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chlorine
Chlorine is an element represented by the symbol Cl with atomic number 17. This means it has 17 electrons when it's neutral. Electrons are distributed in various atomic orbitals according to specific rules, commonly referred to as the electron configuration. For chlorine, its configuration becomes:
- 1s虏 2s虏 2p鈦 3s虏 3p鈦
Antimony
Antimony, with the chemical symbol Sb, holds an atomic number of 51. Thus, it possesses 51 electrons arranged in its ground state configuration, which is:
- 1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦 5s虏 4d鹿鈦 5p鲁
Californium
Californium, a synthetic element denoted as Cf, with atomic number 98, is one of the actinides. It is not naturally found and is produced in nuclear reactors or particle accelerators. Californium's electron configuration is a highly complex setup due to its position in the periodic table:
- 1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦 5s虏 4d鹿鈦 5p鈦 6s虏 4f鹿鈦 5d鹿鈦 6p鈦 7s虏 5f鹿鈦
Atomic Orbitals
Atomic orbitals are regions in an atom where electrons are likely to be found, serving as the building blocks for electron configurations. Different types of orbitals鈥攕, p, d, and f鈥攅ach have distinct shapes and capacities:
- s orbitals are spherical and hold up to 2 electrons.
- p orbitals have a dumbbell shape, holding a max of 6 electrons across three sub-orbitals.
- d orbitals are more complex with five sub-orbitals carrying up to 10 electrons.
- f orbitals have even more complex shapes and can hold 14 electrons.
Electron Filling Order
Understanding the electron filling order is crucial to mastering electron configurations. Electrons fill orbitals in a defined sequence dictated by increasing energy levels. The order is arranged as: 1s, 2s, 2p, 3s, 3p, 4s,
3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d. This sequence is derived from the Aufbau principle, which states electrons occupy the lowest energy orbitals available. Additionally:
- Each orbital can only hold a certain number of electrons, with s orbitals holding 2, p holding 6, d holding 10, and f holding 14.
- Hund's Rule suggests that half-filled orbitals increase stability, influencing order within a subshell.
- The Pauli Exclusion Principle asserts that no two electrons can have identical quantum numbers.