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Are the following processes exothermic or endothermic? a. When solid \(\mathrm{KBr}\) is dissolved in water, the solution gets colder. b. Natural gas \(\left(\mathrm{CH}_{4}\right)\) is burned in a furnace. c. When concentrated \(\mathrm{H}_{2} \mathrm{SO}_{4}\) is added to water, the solution gets very hot. d. Water is boiled in a teakettle.

Short Answer

Expert verified
a. Endothermic b. Exothermic c. Exothermic d. Endothermic

Step by step solution

01

a. Dissolving \(\mathrm{KBr}\) in Water

The statement says that when solid \(\mathrm{KBr}\) is dissolved in water, the solution gets colder. This indicates that heat is being absorbed by the solution from the surroundings. Since heat is being absorbed, this process is endothermic.
02

b. Burning Natural Gas (\(\mathrm{CH}_{4}\))

Burning natural gas (\(\mathrm{CH}_{4}\)) in a furnace is a combustion reaction. Combustion reactions are typically exothermic, as they release heat to the surroundings. Therefore, this process is exothermic.
03

c. Adding Concentrated \(\mathrm{H}_{2}\mathrm{SO}_{4}\) to Water

When concentrated \(\mathrm{H}_{2}\mathrm{SO}_{4}\) is added to water, the solution gets very hot. This means that heat is being released by the solution to the surroundings. Since heat is being released, this process is exothermic.
04

d. Boiling Water in a Teakettle

Boiling water in a teakettle requires heat to be absorbed from the surroundings (i.e., from the heat source) to break the hydrogen bonds and initiate phase transition from liquid to gas. Since heat is being absorbed, this process is endothermic. In summary: a. Dissolving \(\mathrm{KBr}\) in water: Endothermic b. Burning natural gas (\(\mathrm{CH}_{4}\)): Exothermic c. Adding concentrated \(\mathrm{H}_{2}\mathrm{SO}_{4}\) to water: Exothermic d. Boiling water in a teakettle: Endothermic

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Endothermic Processes
In thermochemistry, an endothermic process is a reaction or physical change that absorbs heat energy from the surrounding environment. Such a process results in a change where the system gains energy, causing a decrease in the temperature of its surroundings.
For example, when solid potassium bromide (\( \mathrm{KBr} \)) is dissolved in water, the solution becomes colder. This indicates that the dissolution process is absorbing heat from the surroundings, thus making it an endothermic process.
Another common example is the boiling of water. When water is boiled in a kettle, energy from the heat source is used to break the hydrogen bonds between water molecules, turning them into steam. This absorption of energy signifies another classic endothermic reaction, emphasizing the dependence on external heat sources for the process to occur.
Exothermic Processes
Exothermic processes are chemical reactions or physical changes that release heat energy into their surroundings. These processes often result in an increase in temperature of the surrounding area as energy is expelled.
A typical example is the combustion of natural gas (\( \mathrm{CH}_{4} \)) in a furnace. This exothermic process releases significant amounts of heat, which is often used for heating purposes in homes and industries.
Another example is the addition of concentrated sulfuric acid (\( \mathrm{H}_2\mathrm{SO}_4 \)) to water, which results in a noticeable temperature rise due to the heat released during the mixing process. Both examples demonstrate how exothermic reactions can significantly impact their environment by releasing stored energy.
Chemical Reactions
Chemical reactions are processes where substances, known as reactants, transform into new substances, called products. These reactions can involve the breaking and forming of bonds between atoms.
Chemistry broadly categorizes reactions into many types, including combustion, synthesis, decomposition, and neutralization, among others. For instance, burning natural gas (\( \mathrm{CH}_{4} \)) is a combustion reaction, characterized by the reaction of a fuel with oxygen, producing carbon dioxide and water, and releasing heat in an exothermic process.
Understanding chemical reactions requires a look at the energy changes involved, typically in terms of heat absorption or release, which dictates whether a process is endothermic or exothermic. This energy aspect is vital in determining the behavior and practicality of chemical processes in applications like energy production or material synthesis.
Heat Absorption
Heat absorption is a critical aspect of endothermic processes, where energy from the surroundings is taken in by the system or process. This can lead to a cooling effect in the environment, as seen when \( \mathrm{KBr} \) is dissolved in water.
During such a reaction or change, bonds may be broken, or new structures formed, absorbing a significant amount of heat energy. This is crucial in processes like evaporation and boiling, where heat absorption is necessary for overcoming intermolecular forces.
In real-world applications, endothermic reactions that involve heat absorption can be seen in everyday phenomena such as the melting of ice or photosynthesis in plants, where energy from sunlight is absorbed to produce glucose.
Heat Release
Heat release is a hallmark of exothermic processes, where energy is expelled from the system into the surrounding environment, often resulting in a temperature increase. This is evident in the burning of natural gas (\( \mathrm{CH}_{4} \)) and the addition of concentrated \( \mathrm{H}_2\mathrm{SO}_4 \) to water.
In these exothermic reactions, the energy released is typically due to bond formation, as new, stable bonds often form in the product molecules, releasing excess energy that manifests as heat.
Such heat-releasing processes are incredibly useful in applications like cooking, where energy release from fuel combustion is harnessed to warm food, or in industrial processes that utilize heat to drive mechanical systems. Understanding how and why heat is released helps in controlling and optimizing these reactions for desired outcomes.

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Most popular questions from this chapter

The reaction $$ \mathrm{SO}_{3}(g)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{H}_{2} \mathrm{SO}_{4}(a q) $$ is the last step in the commercial production of sulfuric acid. The enthalpy change for this reaction is \(-227 \mathrm{~kJ}\). In designing a sulfuric acid plant, is it necessary to provide for heating or cooling of the reaction mixture? Explain.

Which of the following substances have an enthalpy of formation equal to zero? a. \(\mathrm{Cl}_{2}(g)\) b. \(\mathrm{H}_{2}(g)\) c. \(\mathrm{N}_{2}(l)\) d. \(\mathrm{Cl}(g)\)

The overall reaction in a commercial heat pack can be represented as $$ 4 \mathrm{Fe}(s)+3 \mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{Fe}_{2} \mathrm{O}_{3}(s) \quad \Delta H=-1652 \mathrm{~kJ} $$ a. How much heat is released when \(4.00\) moles of iron are reacted with excess \(\mathrm{O}_{2}\) ? b. How much heat is released when \(1.00\) mole of \(\mathrm{Fe}_{2} \mathrm{O}_{3}\) is produced? c. How much heat is released when \(1.00 \mathrm{~g}\) iron is reacted with excess \(\mathrm{O}_{2}\) ? d. How much heat is released when \(10.0 \mathrm{~g} \mathrm{Fe}\) and \(2.00 \mathrm{~g} \mathrm{O}_{2}\) are reacted?

The specific heat capacity of silver is \(0.24 \mathrm{~J} /{ }^{\circ} \mathrm{C} \cdot \mathrm{g}\). a. Calculate the energy required to raise the temperature of \(150.0 \mathrm{~g}\) Ag from \(273 \mathrm{~K}\) to \(298 \mathrm{~K}\). b. Calculate the energy required to raise the temperature of \(1.0\) mole of Ag by \(1.0^{\circ} \mathrm{C}\) (called the molar heat capacity of silver). c. It takes \(1.25 \mathrm{~kJ}\) of energy to heat a sample of pure silver from \(12.0^{\circ} \mathrm{C}\) to \(15.2^{\circ} \mathrm{C}\). Calculate the mass of the sample of silver.

A system undergoes a process consisting of the following two steps: Step \(1:\) The system absorbs \(72 \mathrm{~J}\) of heat while \(35 \mathrm{~J}\) of work is done on it. Step 2: The system absorbs \(35 \mathrm{~J}\) of heat while performing \(72 \mathrm{~J}\) of work. Calculate \(\Delta E\) for the overall process.

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