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Equal moles of sulfur dioxide gas and oxygen gas are mixed in a flexible reaction vessel and then sparked to initiate the formation of gaseous sulfur trioxide. Assuming that the reaction goes to completion, what is the ratio of the final volume of the gas mixture to the initial volume of the gas mixture if both volumes are measured at the same temperature and pressure?

Short Answer

Expert verified
The ratio of the final volume of the gas mixture to the initial volume of the gas mixture, when measured at the same temperature and pressure, is 3:4.

Step by step solution

01

Write the balanced chemical equation

Determine the balanced chemical equation for the reaction involving sulfur dioxide (SO2), oxygen (O2), and sulfur trioxide (SO3). The balanced chemical equation is: 2 SO2(g) + O2(g) -> 2 SO3(g)
02

Analyze the stoichiometry of the reaction

From the balanced chemical equation, we can see that 2 moles of SO2 react with 1 mole of O2 to produce 2 moles of SO3. Since equal moles of SO2 and O2 are involved initially, we can say that half of the moles of O2 react with SO2 to form SO3.
03

Calculate moles of each gas after the reaction

Let's assume that initially there are x moles of SO2 and x moles of O2 in the reaction vessel. After the reaction, SO2 consumption is x moles (as reaction goes to completion), and O2 consumption is (1/2)x moles (by stoichiometry of the balanced equation). Therefore, the moles of the remaining O2 will be [(x - (1/2)x] = (1/2)x moles. Since 2 moles of SO3 are produced for each 1 mole of O2 consumed, the moles of SO3 produced will be (2 * (1/2)x) = x moles.
04

Determine the initial and final volume ratio

According to the combined gas law, at constant temperature and pressure, the volume of a gas depends only on the number of moles. Since initially, there are x moles of SO2 and x moles of O2, the initial volume of the gas mixture will be proportional to a total of (x + x) = 2x moles. After the reaction, there are x moles of SO3 and (1/2)x moles remaining of O2, the final volume of the gas mixture will be proportional to (x + (1/2)x) = (3/2)x moles. The ratio of the final volume to the initial volume will be: \(\frac{Final\:Volume}{Initial\:Volume} = \frac{(3/2)x\:moles}{2x\:moles}\)
05

Simplify the ratio

Simplify the expression above to obtain the ratio of the final volume to the initial volume: \(\frac{Final\:Volume}{Initial\:Volume} = \frac{(3/2)x\:moles}{2x\:moles} = \frac{3}{4}\) So, the ratio of the final volume of the gas mixture to the initial volume of the gas mixture, when measured at the same temperature and pressure, is 3:4.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Balanced Chemical Equation
A balanced chemical equation is crucial in understanding chemical reactions because it shows how reactants transform into products while conserving matter. Each side of the equation has the same number of atoms for every element, ensuring mass conservation.
For the reaction under consideration, sulfur dioxide ( \( \text{SO}_2 \) ) reacts with oxygen ( \( \text{O}_2 \) ) to form sulfur trioxide ( \( \text{SO}_3 \) ). The balanced equation for this is: \[ 2 \text{SO}_2(g) + \text{O}_2(g) \rightarrow 2 \text{SO}_3(g) \]
This equation tells us that 2 moles of \( \text{SO}_2 \) react with 1 mole of \( \text{O}_2 \) to produce 2 moles of \( \text{SO}_3 \).
  • The subscripts next to the chemical formulas indicate the number of moles for each substance.
  • The coefficients ensure that the number of atoms for each element is equal on both sides of the equation. For instance, there are 2 sulfur atoms and 6 oxygen atoms on each side.
Understanding balanced equations helps predict how much product will form and what quantities of reactants are required.
Gas Laws
Gas laws, such as the ideal gas law, can help in relating the volumes, pressures, and temperatures of gases in chemical reactions. At constant temperature and pressure, the volume of a gas is directly proportional to the number of moles ( \( V \propto n \) ). This relationship simplifies comparing volumes of gas before and after a reaction, as in this problem.
By understanding that volume changes are due to changes in the number of moles, we can derive valuable insights. The combined gas law helps us state that: \[ \frac{P_1 V_1}{T_1} = \frac{P_2 V_2}{T_2} \]
In this equation:
  • P stands for pressure
  • V stands for volume
  • T stands for temperature
When temperature and pressure are constant, we find that \( V_1/V_2 = n_1/n_2 \) , meaning the volume ratio equals the mole ratio. This knowledge simplifies predicting how gas mixtures change in reactions, like the formation of sulfur trioxide.
Reaction Completion
In chemical reactions, the term 'reaction completion' indicates that the reaction proceeds until one of the reactants is entirely consumed, and no further reaction occurs. This is vital to know how the moles of substances change during a reaction.
In the reaction between \( \text{SO}_2 \) and \( \text{O}_2 \) , we're assuming it goes to completion, meaning all of one reactant is used up. For this reaction:
  • All initial moles of \( \text{SO}_2 \) are totally consumed.
  • Half the initial moles of \( \text{O}_2 \) are consumed.
  • The reaction produces moles of \( \text{SO}_3 \) according to the stoichiometry.
By understanding the concept of completion, we see how moles and thus volumes change, affecting calculations for volume ratios. Reaction completion allows us to analyze changes effectively and predict the quantities of remaining substances.
Mole Ratio
The mole ratio in a balanced chemical equation tells us the proportions of reactants and products involved in the reaction. It forms a fundamental part of stoichiometry, which ensures that chemical equations are balanced.
In the balanced equation: \( 2 \text{SO}_2(g) + \text{O}_2(g) \rightarrow 2 \text{SO}_3(g) \), the mole ratio between \( \text{SO}_2, \text{O}_2, \text{and}\, \text{SO}_3 \) are 2 : 1 : 2 respectively.
This means:
  • 2 moles of sulfur dioxide react with 1 mole of oxygen.
  • This ratio dictates how much \( \text{SO}_3 \) is formed from specific amounts of \( \text{SO}_2 \) and \( \text{O}_2 \).
By using the mole ratio, we can calculate the exact amounts of products formed or reactants required. This also helps derive the initial and final volume ratios in the exercise, as the mole ratio directly affects these calculations, determining how reactions proceed.

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Most popular questions from this chapter

Which of the following statements is(are) true? For the false statements, correct them. a. At constant temperature, the lighter the gas molecules, the faster the average velocity of the gas molecules. b. At constant temperature, the heavier the gas molecules, the larger the average kinetic energy of the gas molecules. c. A real gas behaves most ideally when the container volume is relatively large and the gas molecules are moving relatively quickly. d. As temperature increases, the effect of interparticle interactions on gas behavior is increased. e. At constant \(V\) and \(T\), as gas molecules are added into a container, the number of collisions per unit area increases resulting in a higher pressure. f. The kinetic molecular theory predicts that pressure is inversely proportional to temperature at constant volume and moles of gas.

Atmospheric scientists often use mixing ratios to express the concentrations of trace compounds in air. Mixing ratios are often expressed as ppmv (parts per million volume): ppmv of \(X=\frac{\text { vol of } X \text { at STP }}{\text { total vol of air at STP }} \times 10^{6}\) On a certain November day, the concentration of carbon monoxide in the air in downtown Denver, Colorado, reached \(3.0 \times 10^{2}\) ppmv. The atmospheric pressure at that time was 628 torr and the temperature was \(0^{\circ} \mathrm{C}\). a. What was the partial pressure of \(\mathrm{CO}\) ? b. What was the concentration of \(\mathrm{CO}\) in molecules per cubic meter? c. What was the concentration of \(\mathrm{CO}\) in molecules per cubic centimeter?

An organic compound containing only C, H, and N yields the following data. i. Complete combustion of \(35.0 \mathrm{mg}\) of the compound produced \(33.5 \mathrm{mg} \mathrm{CO}_{2}\) and \(41.1 \mathrm{mg} \mathrm{H}_{2} \mathrm{O}\). ii. A \(65.2\) -mg sample of the compound was analyzed for nitrogen by the Dumas method (see Exercise 129), giving \(35.6 \mathrm{~mL}\) of dry \(\mathrm{N}_{2}\) at 740 . torr and \(25^{\circ} \mathrm{C}\). iii. The effusion rate of the compound as a gas was measured and found to be \(24.6 \mathrm{~mL} / \mathrm{min}\). The effusion rate of argon gas, under identical conditions, is \(26.4 \mathrm{~mL} / \mathrm{min}\). What is the molecular formula of the compound?

The nitrogen content of organic compounds can be determined by the Dumas method. The compound in question is first reacted by passage over hot \(\mathrm{CuO}(s)\) : $$ \text { Compound } \stackrel{\mathrm{Hot}}{\longrightarrow} \mathrm{N}_{2}(g)+\mathrm{CO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(g) $$ The product gas is then passed through a concentrated solution of \(\mathrm{KOH}\) to remove the \(\mathrm{CO}_{2}\). After passage through the KOH solution, the gas contains \(\mathrm{N}_{2}\) and is saturated with water vapor. In a given experiment a \(0.253-\mathrm{g}\) sample of a compound produced \(31.8 \mathrm{~mL} \mathrm{~N}_{2}\) saturated with water vapor at \(25^{\circ} \mathrm{C}\) and 726 torr. What is the mass percent of nitrogen in the compound? (The vapor pressure of water at \(25^{\circ} \mathrm{C}\) is \(23.8\) torr.)

The average lung capacity of a human is \(6.0 \mathrm{~L}\). How many moles of air are in your lungs when you are in the following situations? a. At sea level \((T=298 \mathrm{~K}, P=1.00 \mathrm{~atm})\). b. \(10 . \mathrm{m}\) below water \((T=298 \mathrm{~K}, P=1.97 \mathrm{~atm})\). c. At the top of Mount Everest \((T=200 . \mathrm{K}, P=0.296 \mathrm{~atm})\).

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